1-(1-Methyl-2-piperidinyl)acetone
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1-(1-Methyl-2-piperidinyl)acetone 속성
- 끓는 점
- 217℃
- 밀도
- 0.920
- 굴절률
- 1.4674
- 인화점
- 67℃
- 저장 조건
- Refrigerator
- 용해도
- 클로로포름 (약간 용해됨), DMSO (약간 용해됨), 에탄올 (약간 용해됨)
- 물리적 상태
- 기름
- 산도 계수 (pKa)
- 9.53±0.10(Predicted)
- 색상
- 주황색에서 매우 어두운 주황색까지
안전
1-(1-Methyl-2-piperidinyl)acetone C화학적 특성, 용도, 생산
개요
This alkaloid occurs in the bark of Punica Granatum L. and was first isolated by Piccinini under the name of isomethylpelletierine. The base is an oily liquid with an alkaline reaction, miscible with H20 and optically inactive. The hydrochloride has m.p. lS6°C; the hydrobromide, m.p. lSI-2°C; the aurichloride forms rosettes of orange-yellow needles, m.p. lIS-7°C and the picrate has m.p. lS7-8°C. The alkaloid may be resolved into its optically active components. (+)-methy1isopelletierine (+)-hydrogen tartrate has m.p. 133-4°C; [α]20D + 22.7°, the corresponding figures for the antipode being m.p. 132-40c;~aH)S - 20.83° while the two hydrochlorides have [α]18D + 11.08° and - 10.64° respectively.The base gives a semicarbazone as colourless crystals, m.p. 169°C; an oxime, b.p. 1600C/12 mm and a hydrazone, b.p. lS4-SoC/29 mm. The methiodide yields cubic crystals, m.p. lS6°C. Oxidation with chromic acid in H2S04 furnishes N-methylpiperidine-2-carboxylic acid.
참고 문헌
Piccinini., Gazzetta, 29, ii, 311 (1899)Hess et al., Ber., SO, 344, 1386 (1917)
Hess et al., ibid, 51,741 (1918)
Hess et al., ibid, 52, 964, 100S (1919)
1-(1-Methyl-2-piperidinyl)acetone 준비 용품 및 원자재
원자재
준비 용품
1-(1-Methyl-2-piperidinyl)acetone 공급 업체
글로벌( 59)공급 업체
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Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
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BOC Sciences | +1-631-485-4226 |
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CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
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TargetMol Chemicals Inc. | +1-781-999-5354 |
support@targetmol.com | United States | 19973 | 58 |
Chembest Research Laboratories Limited | 021-20908456 |
sales@BioChemBest.com | China | 6011 | 61 |
BioBioPha Co., Ltd. | 0871-65217109 13211707573; |
y.liu@mail.biobiopha.com | China | 5654 | 65 |
Shanghai Tauto Biotech Co., Ltd. | 021-51320588 |
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sales@reading-chemicals.com | China | 15185 | 58 |
Shanghai Yongye Biotechnology Co., Ltd. | 86-021-61559134 15921386130 |
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ALB Technology Limited | 702-983-3769 |
sales@albtechnology.com | United States | 2993 | 55 |