톨루엔-2,5-다이아민

톨루엔-2,5-다이아민
톨루엔-2,5-다이아민 구조식 이미지
카스 번호:
95-70-5
한글명:
톨루엔-2,5-다이아민
동의어(한글):
2-메틸-1,4-벤젠다이아민;톨루엔-2,5-다이아민;톨루엔-2,5-디아민;1,4-다이아미노-2-메틸벤젠;1-메틸-2,5-다이아미노벤젠;2,5-다이아미노톨루엔;2,5-디아미노톨루엔;2-메틸-1,4-벤젠디아민;2-메틸-P-페닐렌디아민;2-메틸벤젠-1,4-다이아민;2-메틸-파라-페닐렌다이아민;4-아미노-2-메틸아닐린;P,M-톨릴렌디아민;파라-톨루엔다이아민
상품명:
2,5-Diaminotoluene
동의어(영문):
ci76042;c.i.76042;C.I. 76042;DIAMINOTOLUENES;p-Toluenediamine;p-Toluylendiamine;2,5-Diaminotoluol;p-Toluilenediamine;4-TOLUYLENEDIAMINE;2,5-DIAMINOTOLUENE
CBNumber:
CB4228730
분자식:
C7H10N2
포뮬러 무게:
122.17
MOL 파일:
95-70-5.mol
MSDS 파일:
SDS

톨루엔-2,5-다이아민 속성

녹는점
64°C
끓는 점
273°C
밀도
1.0343 (rough estimate)
증기압
0.454Pa at 25℃
굴절률
1.5103 (estimate)
용해도
물에 용해됨
물리적 상태
powder to crystal
산도 계수 (pKa)
5.98±0.10(Predicted)
색상
흰색에서 갈색으로
수용성
500g/L at 20℃
안정성
흡습성
LogP
-0.321 at 25℃
CAS 데이터베이스
95-70-5(CAS DataBase Reference)
IARC
3 (Vol. 16, Sup 7) 1987
NIST
1,4-Benzenediamine, 2-methyl-(95-70-5)
EPA
Toluene-2,5-diamine (95-70-5)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T,N
위험 카페고리 넘버 20/21-25-43-51/53
안전지침서 24-37-45-61
유엔번호(UN No.) 2811
RTECS 번호 XS9700000
위험 등급 6.1(b)
포장분류 III
HS 번호 2921511990
유해 물질 데이터 95-70-5(Hazardous Substances Data)
기존화학 물질 KE-23453
유해화학물질 필터링 97-1-299
함량 및 규제정보 물질구분: 유독물질; 혼합물(제품)함량정보: 톨루엔디아민과 그 염류 및 그 중 하나를 25% 이상 함유한 혼합물. 다만, 톨루엔-2,4-디아민(Toluene-2,4-diamine)과 이것의 황산염(Toluene-2,4-diamine sulfate)의 경우 이를 0.1% 이상 함유한 혼합물
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.

톨루엔-2,5-다이아민 MSDS


2-Methyl-1,4-benzenediamine

톨루엔-2,5-다이아민 C화학적 특성, 용도, 생산

개요

p-Toluylenediamine is a hair dye associated with contact dermatitis in hairdressers. Cross reactivity is observed with PPD.

화학적 성질

Colorless plates. Soluble in water, ethanol, ether, and hot benzene 2,5-Toluenediamine is used in hair and fur dyes.

용도

2,5-Toluenediamine is used primarily in hair dye formulations as one of the major oxidation dye precursors. It is also used in the synthesis of saframine, a family of dyes used as biological stain, and may be present in indelible ink, antifreeze, and nail polish.
As may be expected from its use in hair dye formulations, hairdressers and barbers may be exposed to 2,5-TDA. Workers in the dye manufacturing industry may also be exposed.

정의

ChEBI: A diamine in which the two amino groups are substituted into toluene at the 2- and 5-positions.

색상 색인 번호

Toluene-2,5-diamine is a permanent hair dye involved in contact dermatitis in hairdressers and consumers. It does not cross-react with PPD, but cosensitization is frequent.

Safety Profile

Poison by ingestion and subcutaneous routes. A skin irritant. Mutation data reported. Questionable carcinogen. Has a toxic action upon the liver and can cause fatty degeneration of that organ. Its total effect upon the body seems to take place three chfferent ways. It is toxic to the central nervous system, producing jaundice by action on the liver and spleen, and anemia by destruction of the red blood cells. This action is quite similar to that of aniline, although by no means identical with it. Its high boiling point and the fact that the material is solid at room temperature make it somewhat less hazardous than aniline, particularly at ordinary working temperatures. The literature contains a reference to a permanent injury to an eye due to the use of this material as an eyelash dye. It is considered to be an irritating dye material. When heated to decomposition it emits toxic fumes of NOx. See also other toluene diamine entries and AROMATIC AMINES.

Carcinogenicity

The possible carcinogenicity of 2,5-TDA (as sulfate salt [6369-59-1]) was tested by the National Cancer Institute in a dietary feeding study. Groups of 50 male and female F344 rats (600 or 2000 ppm) and B6C3F1 mice (600 or 1000 ppm) were given diets containing 2,5-TDA for 78 weeks and then observed for an additional period of 28–31 weeks for rats and 16–19 weeks for mice. The only statistically significant increased incidence was in lung tumors in high-dose female mice, but the evidence was not convincing enough to be attributed to 2,5-TDA. Overall, the compound was considered noncarcinogenic.

톨루엔-2,5-다이아민 준비 용품 및 원자재

원자재

준비 용품


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