Octyltrichlorosilane

Octyltrichlorosilane 구조식 이미지
카스 번호:
5283-66-9
상품명:
Octyltrichlorosilane
동의어(영문):
OTCS;DK322;DK321;DK805;CO9830;LS 2190;P 09830;trichlorooctyl-silan;TRICHLOROOCTYLSILANE;OCTYLTRICHLOROSILANE
CBNumber:
CB4230621
분자식:
C8H17Cl3Si
포뮬러 무게:
247.66
MOL 파일:
5283-66-9.mol

Octyltrichlorosilane 속성

끓는 점
233 °C731 mm Hg(lit.)
밀도
1.07 g/mL at 25 °C(lit.)
증기 밀도
>1 (vs air)
증기압
0-3.5Pa at 25℃
굴절률
n20/D 1.447(lit.)
인화점
206 °F
물리적 상태
투명한 액체
색상
연기가 나는 액체
Specific Gravity
1.074
수용성
59g/L at 20℃
감도
Moisture Sensitive
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
BRN
1744230
InChIKey
RCHUVCPBWWSUMC-UHFFFAOYSA-N
LogP
1.1 at 20℃
CAS 데이터베이스
5283-66-9(CAS DataBase Reference)
EPA
Silane, trichlorooctyl- (5283-66-9)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 C
위험 카페고리 넘버 34-37
안전지침서 26-36/37/39-45
유엔번호(UN No.) UN 1801 8/PG 2
WGK 독일 1
RTECS 번호 VV4700000
F 고인화성물질 10-21
TSCA Yes
위험 등급 8
포장분류 II
HS 번호 29319090
유해 물질 데이터 5283-66-9(Hazardous Substances Data)
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H331 흡입하면 유독함 급성 독성 물질 흡입 구분 3 위험 GHS hazard pictograms P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P271 옥외 또는 환기가 잘 되는 곳에서만 취급하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
0
3 0
W

Octyltrichlorosilane C화학적 특성, 용도, 생산

화학적 성질

CLEAR COLOURLESS TO LIGHT YELLOW LIQUID

용도

OTS functionalized magnesium oxide (MnO2)/aluminium oxide (Al2O3) surface can be used as a catalyst in the decomposition of ozone (O3) and nitrogen dioxide (NO2). OTS can also be used for the surface modification of silicon oxide (SiO2), used in the fabrication of pentacene organic field effect transistors (OFETs). OTS functionalized wafers can be coated on enhanced green fluorescent protein (GFP) and anchor peptides based films to determine the thickness of the films.

일반 설명

N-Octyltrichlorosilane is a colorless liquid with a pungent odor. It is decomposed by water to hydrochloric acid with evolution of heat. Octyltrichlorosilane is corrosive to metals and tissue and used as an intermediate for silicones.

반응 프로필

Chlorosilanes, such as N-OCTYLTRICHLOROSILANE, are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases.

건강위험

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Contact with molten substance may cause severe burns to skin and eyes. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

화재위험

Combustible material: may burn but does not ignite readily. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

Safety Profile

A corrosive irritant to skin, eyes, and mucous membranes. Will react with water or steam to produce toxic and corrosive fumes. When heated to decomposition it emits toxic fumes of Cl-. See also CHLOROSILANES.

Purification Methods

Purify the silane by repeated fractionation using a 15-20 theoretical plate glass column packed with glass helices. This can be done more efficiently using a spinning band column. The purity can be checked by analysing for Cl (ca 0.5-1g of sample is dissolved in 25mL of MeOH, diluted with H2O and titrated with standard alkali). It is moisture sensitive. [Whitmore J Am Chem Soc 68 475 1946, El-Abbady & Anderson J Am Chem Soc 80 1737 1958, Beilstein 4 III 1907.]

Octyltrichlorosilane 준비 용품 및 원자재

원자재

준비 용품


Octyltrichlorosilane 공급 업체

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