트리알릴아민

트리알릴아민
트리알릴아민 구조식 이미지
카스 번호:
102-70-5
한글명:
트리알릴아민
동의어(한글):
트리-2-프로페닐아민;트리알릴아민
상품명:
Triallylamine
동의어(영문):
TAA;Trialkylamine;N,N-Diallyl-2-propen-1-amine;2-Propen-1-amine, N,N-di-2-propen-1-yl-;tertiaryamine;(CH2=CHCH2)3N;TRIALLYLAMINE;triallylaMate;TRIALLYAMINE HCL;Triallylamine 99%
CBNumber:
CB4359230
분자식:
C9H15N
포뮬러 무게:
137.22
MOL 파일:
102-70-5.mol
MSDS 파일:
SDS

트리알릴아민 속성

녹는점
-70°C
끓는 점
150-151 °C (lit.)
밀도
0.79 g/mL at 25 °C (lit.)
증기 밀도
4.73 (vs air)
증기압
90 mm Hg ( 80 °C)
굴절률
n20/D 1.451(lit.)
인화점
87 °F
저장 조건
2-8°C
물리적 상태
투명한 액체
산도 계수 (pKa)
pK1:8.31(+1) (25°C)
색상
무색~황색~주황색
수용성
250g/100mL
안정성
안정적인. 가연성. 강한 산화제와 호환되지 않습니다.
InChIKey
VPYJNCGUESNPMV-UHFFFAOYSA-N
CAS 데이터베이스
102-70-5(CAS DataBase Reference)
NIST
2-Propen-1-amine, N,N-di-2-propenyl-(102-70-5)
EPA
Triallylamine (102-70-5)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 C
위험 카페고리 넘버 10-20/21/22-34
안전지침서 16-26-36/37/39-45
유엔번호(UN No.) UN 2610 3/PG 3
WGK 독일 3
RTECS 번호 XX5950000
TSCA Yes
위험 등급 3
포장분류 III
HS 번호 29211990
유해 물질 데이터 102-70-5(Hazardous Substances Data)
기존화학 물질 KE-33958
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H226 인화성 액체 및 증기 인화성 액체 구분 3 경고
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H331 흡입하면 유독함 급성 독성 물질 흡입 구분 3 위험 GHS hazard pictograms P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
2
3 0

트리알릴아민 MSDS


Triallylamine

트리알릴아민 C화학적 특성, 용도, 생산

화학적 성질

Triallylamine is a flammble liquid. Triallylamine can be detected at 0.5 ppm and is severely irritating at 75 ppm.

용도

Triallylamine is used in organic synthesis.Triallylamine has been proposed as a catalyst for the production of polyesters and as an initiator for the polymerization of butadiene.

주요 응용

Triallylamine (TAA) reacts with primary aromatic amines in the presence of a ruthenium catalyst to form 2-ethyl-3-methylquinolines.
TAA undergoes hydrozirconation followed by transmetalation with germanium tetrachloride to form 1-aza-5-germa-5-chlorobicyclo[3.3.3]undecane. This compound can react with Grignard or lithium reagents to form the corresponding 5-organo compounds.
The cycloaddition of TAA to fluorinated 1,3,4-oxadiazoles affords octahydro-2,7-methanofuro[3,2-c]pyridines.

생산 방법

Triallylamine is manufactured using allyl chloride and ammonia under heat and pressure. It is used as a solvent and in organic syntheses.

일반 설명

A colorless liquid with a fishlike odor. Density 0.800 g / cm3 and insoluble in water. Hence floats on water. Flash point 103°F. Vapors heavier than air. May irritate skin and eyes. Used to make other chemicals.

공기와 물의 반응

Flammable. Insoluble in water.

반응 프로필

Triallylamine is a strong reducing agent that reacts violently with oxidizing agents. Corrosive towards Al and Zn [Handling Chemicals Safely 1980 p. 912] . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

건강위험

May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

화재위험

Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Safety Profile

Poison by skin contact and intraperitoneal routes. Moderately toxic by ingestion and inhalation. An eye and severe skin irritant. Human systemic effects by inhalation: structural or functional changes in trachea or bronchi. Flammable liquid when exposed to heat, flame or oxidlzers. To fight fire, use foam, alcohol foam, fog. When heated to decomposition it emits toxic fumes of NOx. See also AMINES and ALLYL COMPOUNDS.

트리알릴아민 준비 용품 및 원자재

원자재

준비 용품


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