테트라아세틸에틸렌다이아민

테트라아세틸에틸렌다이아민
테트라아세틸에틸렌다이아민 구조식 이미지
카스 번호:
10543-57-4
한글명:
테트라아세틸에틸렌다이아민
동의어(한글):
테트라아세틸에틸렌다이아민;티에이이디;N,N,N',N'-테트라아세틸에틸렌다이아민;N,N'-1,2-에테인다이일비스[N-아세틸아세트아마이드];N,N'-에틸렌비스[N-아세틸아세트아마이드];N,N'-에틸렌비스[다이아세트아마이드];아세트아마이드, N,N'-1,2-에테인다이일 비스(N-아세틸)-;아세트아마이드, N,N'-1,2-에테인다이일비스[N-아세틸-
상품명:
Tetraacetylethylenediamine
동의어(영문):
TAED;TEAD;TAEG;Nikon A;Mykon ATC;Mikon ATC;TETRAACETYLENEDIAMINE;TETRACETYLETHYLENEDIAMINE;TETRAACETYLETHYLENEDIAMINE;1,2-Bis(diacetylamino)ethane
CBNumber:
CB4401238
분자식:
C10H16N2O4
포뮬러 무게:
228.24
MOL 파일:
10543-57-4.mol
MSDS 파일:
SDS

테트라아세틸에틸렌다이아민 속성

녹는점
149-154 °C
끓는 점
140 °C (1.5002 mmHg)
밀도
0.9
굴절률
1.4550 (estimate)
인화점
140 °C
산도 계수 (pKa)
-1.23±0.70(Predicted)
물리적 상태
과립분말
색상
미색부터 베이지까지
수용성
약간 용해됨
Merck
14,9028
BRN
1795711
InChIKey
BGRWYDHXPHLNKA-UHFFFAOYSA-N
CAS 데이터베이스
10543-57-4(CAS DataBase Reference)
NIST
N,n,n',n'-tetraacetylethylenediamine(10543-57-4)
EPA
Tetraacetylethylenediamine (10543-57-4)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
안전지침서 22-24/25
WGK 독일 1
TSCA Yes
HS 번호 29241900
기존화학 물질 KE-13179
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
예방조치문구:
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P332+P313 피부 자극이 생기면 의학적인 조치· 조언을 구하시오.
P337+P313 눈에 대한 자극이 지속되면 의학적인 조치· 조언를 구하시오.
NFPA 704
1
0 0

테트라아세틸에틸렌다이아민 MSDS


T.A.E.D.

테트라아세틸에틸렌다이아민 C화학적 특성, 용도, 생산

화학적 성질

Tetraacetylethylenediamine is off-white to beige granular powder

용도

Tetraacetylethylenediamine (TAED) is a bleaching activator which is mainly used in detergents and additives for laundry washing and dishwashing. Typical concentrations of TAED range between 1.4% and 13% in these products. A small amount of the produced TAED is also used in bleaching of paper, textiles and for the generation of Peracetic acid.
Peroxide bleach activator for household detergents, paper pulp.

제조 방법

Tetraacetylethylenediamine (TAED) is produced in a two stage process from ethylenediamine (ED) and acetic anhydride (Ac2O). ED is first diacetylated to DAED. In the second step DAED is subsequently converted with Ac2O via TriAED into TAED (Clariant, 1999). TAED is crystallized out of the reaction mixture, filtered, washed and dried, and if necessary also granulated. The raw materials used occur almost quantitatively in the product. Byproducts are not formed.
TAED was prepared by acetylation of diacetylethylenediamine (DAED) with acetic anhydride in a 5 L reactor coupled with a packed distillation column, 2.5 cm in inside diameter and 1 m in length. The reaction temperature was set at 135 °C and the reflux ratio at 6. The molar ratio of acetic anhydride to DAED was varied from 3 to 5. A TAED yield as high as 80% was obtained, higher by 15% than in the absence of distillation.

건강위험

TAED is of very low toxicity by all exposure routes examined. Up to 2 g/kg BW there is no acute toxicity. TAED is practically non-irritating to skin and eyes and there is no evidence of a sensitizing potential by skin contact. The only effect after repeated oral and dermal dosing was reversible centrilobular hypertrophy in the liver at high doses due to the induction of metabolizing enzymes. In a 90-day whole body inhalation study no adverse effects in the rat lung, respiratory tract or nasal mucosa were observed. Biokinetic data showed that TAED is rapidly absorbed from the rat intestine and largely metabolized via diacetylation to TriAED and DAED which are excreted in the urine.

테트라아세틸에틸렌다이아민 준비 용품 및 원자재

원자재

준비 용품


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