2,4-디클로로페놀

2,4-디클로로페놀
2,4-디클로로페놀 구조식 이미지
카스 번호:
120-83-2
한글명:
2,4-디클로로페놀
동의어(한글):
2,4-다이클로로페놀;2,4-디클로로페놀;2,4-다이클로로하이드록시벤젠;4,6-다이클로로페놀;다이클로로페놀;페놀, 2,4-다이클로로-
상품명:
2,4-Dichlorophenol
동의어(영문):
2,4-DCP;Isobac;a13-00078;NCI-C55345;2,4-Phenol;2,4-Dichlorphenol;2,4-dichloro-pheno;2,4-dlchlorophenol;2,4-DICHLOROPHENOL;4,6-dichlorophenol
CBNumber:
CB4458696
분자식:
C6H4Cl2O
포뮬러 무게:
163
MOL 파일:
120-83-2.mol
MSDS 파일:
SDS

2,4-디클로로페놀 속성

녹는점
42-43 °C(lit.)
끓는 점
209-210 °C(lit.)
밀도
1.383
증기압
1.3 hPa (50 °C)
굴절률
1.4430 (estimate)
인화점
237 °F
저장 조건
2-8°C
용해도
메탄올: 10ml에 1g이 녹습니다.
산도 계수 (pKa)
pK1:7.85 (25°C)
색상
흰색에서 베이지색
수용성
4.5g/L(20℃)
Merck
14,3072
BRN
742467
Henry's Law Constant
2.88 x 10-6 atm?m3/mol at 20 °C (Sheikheldin et al., 2001) 3.23 x 10-6 atm?m3/mol at 25 °C (estimated, Leuenberger et al., 1985a)
InChIKey
HFZWRUODUSTPEG-UHFFFAOYSA-N
LogP
3.25 at 20℃
CAS 데이터베이스
120-83-2(CAS DataBase Reference)
NIST
Phenol, 2,4-dichloro-(120-83-2)
EPA
2,4-Dichlorophenol (120-83-2)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T,N,F
위험 카페고리 넘버 22-24-34-51/53-39/23/24/25-23/24/25-11-25
안전지침서 26-36/37/39-45-61-36/37-16-7
유엔번호(UN No.) UN 2928 6.1/PG 2
WGK 독일 3
RTECS 번호 SK8575000
TSCA Yes
위험 등급 6.1
포장분류 III
HS 번호 29081000
유해 물질 데이터 120-83-2(Hazardous Substances Data)
독성 Acute oral LD50 for mice 1,276 mg/kg, rats 580 mg/kg (quoted, RTECS, 1985).
기존화학 물질 KE-10167
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H311 피부와 접촉하면 유독함 급성 독성 물질 - 경피 구분 3 위험 GHS hazard pictograms P280, P302+P352, P312, P322, P361,P363, P405, P501
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H411 장기적 영향에 의해 수생생물에 유독함 수생 환경유해성 물질 - 만성 구분 2
예방조치문구:
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
1
3 0

2,4-디클로로페놀 MSDS


4,6-Dichlorophenol

2,4-디클로로페놀 C화학적 특성, 용도, 생산

화학적 성질

white to beige crystalline solid

물리적 성질

Colorless to yellow crystals with a sweet, musty, or medicinal odor. At 40 °C, the average odor threshold concentration and the lowest concentration at which an odor was detected were 29 and 5.4 μg/L, respectively. Similarly, at 25 °C, the average taste threshold concentration and the lowest concentration at which a taste was detected were 2.5 and 0.98 μg/L, respectively (Young et al., 1996).

용도

2,4-Dichlorophenol is a chlorinated derivative of phenol and is used as an intermediate for the preparation of herbicide 2,4-dichlorophenoxyacetic acid (D435680).

정의

ChEBI: A dichlorophenol that is phenol carrying chloro substituents at positions 2 and 4.

일반 설명

Colorless crystalline solid with a medicinal odor. Melting point 45°C. Sinks in water. Strong irritant to tissues; toxic by ingestion.

공기와 물의 반응

Insoluble in water.

반응 프로필

2,4-Dichlorophenol can react vigorously with oxidizing agents. Can also react with acids or acid fumes. Incompatible with acid chlorides and acid anhydrides.

건강위험

Tremors, convulsions, shortness of breath, inhibition of respiratory system.

Safety Profile

Suspected carcinogen with experimental carcinogenic and teratogenic data. Poison by intraperitoneal route. Moderately toxic by ingestion and subcutaneous routes. An experimental teratogen. Mutation data reported. Combustible when exposed to heat or flame. Can react vigorously with oxidizing materials. To fight fre, use alcohol foam, foam, CO2, dry chemical. When heated to decomposition, or on contact with acid or acid fumes, it emits hghly toxic fumes of Cl-. See also CHLOROPHENOLS.

잠재적 노출

2,4-Dichlorophenol is a commercially produced substituted phenol used in the manufacture of industrial and agricultural products; in synthesis of pharmaceuticals. As an intermediate in the chemical industry, 2,4-DCP is utilized as the feedstock for the manufacture of 2,4-dichlorophenoxyacetic acid (2,4-D), and 2,4-D derivatives (germicides, soil sterilants, etc.); certain methyl compounds used in mothproofing, antiseptics and seed disinfectants. 2,4-DCP is also reacted with benzene sulfonyl chloride to produce miticides or further chlorinated to pentachlorophenol, a wood preservative. It is thus a widely used pesticide intermediate. The only group expected to be at risk for high exposure to 2,4-DCP is industrial workers involved in the manufacturing or handling of 2,4-DCP and 2,4-D

Carcinogenicity

In mammalian cells in vitro 2,4-DCP produced chromosomal aberrations and induced unscheduled DNA synthesis; it was negative for sister chromatid exchange in vivo and was mostly negative in bacterial assays.
Oral exposure of pregnant rats to 750mg/kg/day for 10 gestational days induced slightly decreased fetal weight, delayed ossification of sternal and vertebral arches, and some early embryonic deaths.10 Maternal deaths also occurred at this dose, indicating that 2,4-DCP was not selectively toxic to embryos or fetuses. No effects were noted in dams or offspring exposed at 375mg/kg/day.
A threshold limit value (TLV) has not been established for 2,4-dichlorophenol.

운송 방법

UN2020 Chlorophenols, solid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials

Purification Methods

Crystallise it from pet ether (b 30-40o). Purify it also by repeated zone melting, using a P2O5 guard tube to exclude moisture. It is very hygroscopic when dry. [Beilstein 6 IV 885.]

비 호환성

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. Contact with acids or acid fumes causes decomposition releasing poisonous chlorine gas. Incompatible with caustics, acid anhydrides; acid chlorides. Quickly corrodes aluminum; slowly corrodes zinc, tin, brass, bronze, copper and its alloys. May accumulate static electrical charges, and may cause ignition of its vapors.

폐기물 처리

Dissolve in a combustible solvent and incinerate in a furnace equipped with afterburner and scrubber. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≧100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal

2,4-디클로로페놀 준비 용품 및 원자재

원자재

준비 용품


2,4-디클로로페놀 공급 업체

글로벌( 438)공급 업체
공급자 전화 이메일 국가 제품 수 이점
Hebei Mojin Biotechnology Co., Ltd
+8613288715578
sales@hbmojin.com China 12457 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652
info@fdachem.com China 7613 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806
sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886
info@dakenam.com China 15928 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21695 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555 +8617317452075
jack.li@time-chemicals.com China 1807 55
career henan chemical co
+86-0371-86658258
sales@coreychem.com China 29914 58
Shenzhen Nexconn Pharmatechs Ltd
+86-755-89396905 +86-15013857715
admin@nexconn.com China 10248 58
Hubei Jusheng Technology Co.,Ltd.
18871490254
linda@hubeijusheng.com CHINA 28180 58
Jinan Finer Chemical Co., Ltd
+86-531-88989536 +86-15508631887
sales@finerchem.com China 2967 58

2,4-디클로로페놀 관련 검색:

Copyright 2019 © ChemicalBook. All rights reserved