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트리클로피어

트리클로피어
트리클로피어 구조식 이미지
카스 번호:
55335-06-3
한글명:
트리클로피어
동의어(한글):
트라이클로피르;트리클로피어;트리클로피어(TRICLOPYR)
상품명:
Triclopyr
동의어(영문):
Rely;Mutan;Remedy;Redeem;Garlon;Exetor;M 3724;Curtail;Timbrel;Turflon
CBNumber:
CB4666264
분자식:
C7H4Cl3NO3
포뮬러 무게:
256.47
MOL 파일:
55335-06-3.mol

트리클로피어 속성

녹는점
148-150°C
끓는 점
290°C
밀도
1.7626 (rough estimate)
굴절률
1.6200 (estimate)
저장 조건
0-6°C
물리적 상태
Liquid
산도 계수 (pKa)
2.68(at 25℃)
Merck
13,9730
BRN
225301
CAS 데이터베이스
55335-06-3(CAS DataBase Reference)
NIST
Acetic acid, [(3,5,6-trichloro-2-pyridinyl)oxy]-(55335-06-3)
EPA
Acetic acid, [(3,5,6-trichloro-2-pyridinyl) oxy]-(55335-06-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn
위험 카페고리 넘버 22
안전지침서 22-24/25
유엔번호(UN No.) UN3082 (liquid)
WGK 독일 3
RTECS 번호 AJ9000000
유해 물질 데이터 55335-06-3(Hazardous Substances Data)
독성 LD50 orally in rats: 713 mg/kg (Kenaga)
그림문자(GHS):
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 P264, P270, P301+P312, P330, P501
예방조치문구:

트리클로피어 C화학적 특성, 용도, 생산

화학적 성질

White to Off-White Solid

용도

Selective postemergence herbicide to control many woody and broad-leaved weeds.

용도

Triclopyr is a selective post-emergence herbicide.

정의

ChEBI: A monocarboxylic acid that is (pyridin-2-yloxy)acetic acid substituted by chloro groups at positions 3, 5 and 6. It is an agrochemical used as a herbicide.

농업용

Herbicide: Triclopry is a systemic herbicide used on rice, range land and pasture, rights-of-way, forestry and grasslands, including home lawns, for control of broadleaf weeds and woody plants. Triclopry is usually available as a triclopyr butoxyethyl ester (BEE) or as a triclopry triethylamine salt (TEA). Registered for use in the U.S. Some products may be classified as Restricted Use Pesticides (RUP). Registered for use in EU countries . U.S. Maximum Allowable Residue Levels for Triclopyr and its metabolites 3,5,6,-trichloro-2-pyridinol and 2-methoxy-3,5,6-trichloropyridine [40 CFR 180.417 (a)(1)]: for the combined residues of the herbicide in or on the following raw agricultural commodities: fish 3.0 ppm; grass, forage 500 ppm; grass, forage, hay 500 ppm;shellfish3.5 ppm.[40 CFR 180.417 (a)(2)]: in or on the following agricultural commodities: egg 0.05 ppm; meat, fat, and meat byproducts, except kidney and liver, of cattle, goat, hog, horse and sheep 0.05 ppm; meat, fat, and meat byproducts, except kidney, of poultry 0.1 ppm; milk 0.01 ppm; liver and kidney of cattle, goat, hog, horse and sheep 0.5 ppm; rice, grain 0.3 ppm; rice, straw10.0 ppm.

상품명

[Note: See the following record, Triclopyr, triethylamine salt, for trade names containing the salt of triclopry] ACCESS®; CROSSBOW®, (triclopyr + 2,4-D ester); ET®; GARLON®; GRAZON® Triclopyr; PATHFINDER®; REDEEM®; RELY®; REMEDY®; RIVERDALE TAHOE® Nufarm (Australia); TURFLON®

환경귀착

Soil. In soil, triclopyr degraded to 3,5,6-trichloro-2-pyridinol and 2-methoxy-3,5,6- trichloropyridine (Norris et al., 1987). The major route of dissipation from soil is likely due to microbial degradation (Newton et al., 1990).
Fifty-four days after triclopyr was applied to soil at a rate of 5.6 kg/ha, the majority (65%) remained in the top 10 cm of soil (Lee et al., 1986a).
Ashton and Monaco (1991) reported triclopyr had an average half-life of 46 days and is in?uenced by soil type and climatic conditions.
Plant. Lewer and Owen (1989) found 3,5,6-trichloro-2-pyridinol as the major metab- olite in plants. Cultured soybean cells metabolized triclopyr to dimethyl triclopyr-aspartate and dimethyl triclopyr-glutamate which can be rehydrolyzed to form the parent compound.
At an application rate of 3.4 kg/ha, the dissipation half-life was 3.7 days. At an application rate of 3.3 kg/ka, the dissipation half-lives of triclopyr in brown, browse and litter samples were 73.5, 202.3 and 31 days, respectively (Norris et al., 1987).

신진 대사 경로

After 7 days in a soybean cell suspension culture, the major metabolites of trichlopyr are formed and identified as the aspartate (major) and glutamate (minor) amide conjugates.

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