t-부틸 퍼옥시벤조에이트
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t-부틸 퍼옥시벤조에이트 속성
- 녹는점
- 8 °C
- 끓는 점
- 75-76 °C/0.2 mmHg (lit.)
- 밀도
- 1.021 g/mL at 25 °C (lit.)
- 증기 밀도
- 6.7 (vs air)
- 증기압
- 3.36 mm Hg ( 50 °C)
- 굴절률
- n
20/D 1.499(lit.)
- 인화점
- 200 °F
- 저장 조건
- 2-8°C
- 용해도
- 물: 가용성1.18g/L
- 물리적 상태
- 액체
- 색상
- 맑은 노란색
- 냄새
- 온화한 향기로운 냄새
- 수용성
- 섞일 수 없음
- BRN
- 1342734
- 안정성
- 안정적인. 타기 쉬운. 광범위한 유기 물질(산화제)과 호환되지 않습니다. 유기 화합물과 격렬하게 반응할 수 있음.
- InChIKey
- GJBRNHKUVLOCEB-UHFFFAOYSA-N
- LogP
- 3 at 25℃
- CAS 데이터베이스
- 614-45-9(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | O,Xi,E,N | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 7-38-2-50-43 | ||
| 안전지침서 | 7-14-36/37/39-47-37-17-61-39-35-26 | ||
| 유엔번호(UN No.) | UN 3103 5.2 | ||
| WGK 독일 | 2 | ||
| RTECS 번호 | SD9450000 | ||
| TSCA | Yes | ||
| 위험 등급 | 5.2 | ||
| 포장분류 | II | ||
| HS 번호 | 29163900 | ||
| 유해 물질 데이터 | 614-45-9(Hazardous Substances Data) | ||
| 독성 | LD50 orally in Rabbit: > 2000 mg/kg LD50 dermal Rabbit > 2000 mg/kg | ||
| 기존화학 물질 | KE-02166 |
t-부틸 퍼옥시벤조에이트 C화학적 특성, 용도, 생산
물성
명확한 노란 액체，알코올, 에스테 르, 에테르, 다양 한 종류의 용 매에 용 해. 물, 글 리세 린에서에서 불 용해성입니다. 에틸렌 글리콜에 약간 용 해.포장, 보관 및 운송
그것은 25kg 그물 PE 취소 입증 드럼에서 포장 된다. 유기 과산화물 저장 한다 점화 및 열 소스에서 닫힌된 컨테이너에서 그리고 직접적인 햇빛에 충분히 멋진. 별도, 잘 통풍 창 필수적 이며 대량에 대 한 별도 저장 건물을 사용 해야 합니다. 이 자료에 대 한 권장된 보관 온도 30 ℃ 아래 이다.화학적 성질
colourless or slightly yellow liquid. At 124 ℃ (temperature), the half-life of tert-butyl peroxybenzoate is 10 hours.용도
tert-Butyl peroxybenzoate was employed as polymerization and cross-linking catalyst. It was also was employed as initiator during ?grafting of 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO)-4-oxyacetamido-(3 propyltriethoxysilane) to poly(ethylene co-octene and in preparation of conformal poly(cyclohexyl methacrylate) thin films via initiated chemical vapor deposition.일반 설명
Clear, colorless to slightly yellow liquid with a mild, aromatic odor. tert-Butyl peroxybenzoate also is stored and transported as a mixture with inert solids and as a solvent slurry, to mitigate the explosion hazard.공기와 물의 반응
Insoluble in water.반응 프로필
TERT-BUTYL PEROXYBENZOATE explodes with great violence when rapidly heated to a critical temperature; pure form is shock sensitive and detonable [Bretherick 1979 p. 602]. Upon contact with organic matter, t-butyl peroxybenzoate can ignite or give rise to an explosion [Haz. Chem. Data 1973 p. 77].위험도
Oxidizing material; do not store near com- bustible materials.건강위험
t-Butyl peroxybenzoate is a mild skin andeye irritant. Exposure to 500 mg/day causedmild irritation in rabbit eyes and skin. Toxicitydata on animals show a low order oftoxicity.LD50 value, oral (mice): 914 mg/kg
It has been reported to cause tumors(blood) in mice. Its carcinogenic actions onhumans are unknown.
화재위험
Highly reactive and oxidizing compound with moderate flammability; flash point (open cup) 107–110°C (224.6–230°F); autoignition temperature not reported.It forms an explosive mixture with air; the explosive range not reported. It is not sensitive to shock but is heat sensitive. It explodes on heating; self-accelerating decomposition temperature 60°C (140°F).
It may react explosively when mixed with readily oxidizable, organic, and flammable substances. Fire-extinguishing agent: water from a sprinkler; use water to keep the containers cool.
Safety Profile
Moderately toxic by ingestion. A skin and eye irritant. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. See also PEROXIDES, ORGANIC. Potentially explosive when heated above 11 5'C. Explosive reaction on contact with organic matter or copperQ) bromide + limonene. When heated to decomposition it emits acrid smoke and fumes.Carcinogenicity
Other studies have determined the possibility that t-butyl peroxybenzoate can be metabolized to free radicals by human carcinoma skin keratinocytes. Free radicals are suggested to be involved in the cascade of events occurring during tumor promotion .저장
It should be stored in a well-ventilatedplace at a temperature between 10 and27°C (50–80°F), isolated from oxidizable,flammable, organic materials and accelerators.It should be shipped in glass, polyethylene,and earthenware containers of up to5-gallon capacity placed inside wooden orfiberboard boxes.t-부틸 퍼옥시벤조에이트 준비 용품 및 원자재
원자재
준비 용품
3-(4-Methylpiperazin-1-ylmethyl)benzoic acid
dimethyl ocatadecyl aminoium hydroxy propylsulfonate
3-(BROMOMETHYL)BENZOIC ACID
안트론
tert-butyl 4-methylphenyl ether
2-Methyl-1,3-cyclopentanedione
ACETIC ACID 3-BUTEN-2-YL ESTER
N-Boc-N-methyl glycine methyl ester
클로로(3-)피리딘
1-(1,1-Dimethylethoxy)-2,2-dimethylpropane
2-methyl-1,3-bis(p-methoxyphenyl)propane-1,3-diketone
2-t-Butoxythiophene
t-부틸 퍼옥시벤조에이트 공급 업체
글로벌( 254)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Taizhou Suze Chemical Materials Co.,Ltd. | +86-0523-86392777 +86-19825580222 |
nick.miao@suzechem.com | China | 23 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 |
sales@hbmojin.com | China | 12456 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
info@dakenam.com | China | 15933 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21691 | 55 |
| Tianjin Zhongxin Chemtech Co., Ltd. | +86-022-66880623 +8618622897568 |
sales@tjzxchem.com | China | 559 | 58 |
| career henan chemical co | +86-0371-86658258 |
sales@coreychem.com | China | 29914 | 58 |
| SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 |
sales@sdzschem.com | China | 2931 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28180 | 58 |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 |
alice@crovellbio.com | China | 8823 | 58 |