L-리모넨

L-리모넨
L-리모넨 구조식 이미지
카스 번호:
5989-54-8
한글명:
L-리모넨
동의어(한글):
L-리모넨;과산화물가가20mmol/L을초과하는ℓ-리모넨
상품명:
(S)-(-)-LIMONENE
동의어(영문):
L-LIMONENE;(-)-Limonene;(S)-1-Methyl-4-(prop-1-en-2-yl)cyclohex-1-ene;beta-limonene;(s)-(-)-p-mentha-8-diene;(-)-1,8-p-menthadiene,(S)-(-)-limonene;(S)-(-)-4-ISOPROPENYL-1-METHYL-1-CYCLOHEXENE;1-methyl-4-(1-methylethenyl)-,(S)-Cyclohexene;cyclohexene,1-methyl-4-(1-methylethenyl)-,(S)-;LIMONENER
CBNumber:
CB5178359
분자식:
C10H16
포뮬러 무게:
136.23
MOL 파일:
5989-54-8.mol
MSDS 파일:
SDS

L-리모넨 속성

녹는점
-74°C
끓는 점
175-177 °C(lit.)
알파
-99.5 º (C=NEAT)
밀도
0.844 g/mL at 25 °C(lit.)
증기 밀도
4.7 (vs air)
증기압
<3 mm Hg ( 14.4 °C)
굴절률
n20/D 1.471(lit.)
인화점
119 °F
저장 조건
Sealed in dry,Store in freezer, under -20°C
용해도
클로로포름(적게), 에탄올(약간), 메탄올(약간)에 용해됨
물리적 상태
액체
색상
무색~담황색 투명
냄새
100.00%에서. 테르펜 파인 허브 페퍼리
?? ??
테르펜
폭발한계
0.7-6.1%(V)
optical activity
[α]20/D 94±4°, c = 10% in ethanol
수용성
불용성
Merck
14,5493
BRN
2323991
안정성
안정적인. 강한 산화제와 호환되지 않습니다. 가연성.
LogP
4.38 at 37℃
CAS 데이터베이스
5989-54-8(CAS DataBase Reference)
NIST
Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (S)-(5989-54-8)
EPA
Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (4S)- (5989-54-8)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi,N
위험 카페고리 넘버 10-38-43-50/53
안전지침서 24-37-60-61
유엔번호(UN No.) UN 2052 3/PG 3
WGK 독일 2
RTECS 번호 OS8350000
F 고인화성물질 8-10-23
TSCA Yes
위험 등급 3
포장분류 III
HS 번호 29029090
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H226 인화성 액체 및 증기 인화성 액체 구분 3 경고
H304 삼켜서 기도로 유입되면 치명적일 수 있음 흡인 유해성물질 구분 1 위험 GHS hazard pictograms
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H400 수생생물에 매우 유독함 수생 환경유해성 물질 - 급성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
NFPA 704
2
2 0

L-리모넨 C화학적 특성, 용도, 생산

개요

ι-Limonene has a pleasant, lemon-like odor free from camphora ceous and turpentine-like notes. The most important and wide spread terpene; it is known in the d- and ι- optically active forms and in the optically inactive dl-form (known as dipentene); it has been reported found in more than 300 essential oils in amounts ranging from 90 - 95% (lemon, orange, mandarin) to as low as 1% (palmarosa);1 the most widespread form is the d-limonene, followed by the racemic form, and then ι-limonene.

화학적 성질

colourless liquid with lemon odour

출처

It has been reported found in more than 300 essential oils in amounts ranging from 90 to 95% (lemon, orange, mandarin) to as low as 1% (palmarosa); the most widespread form is the d-limonene, followed by the racemic form and then l-limo nene. Also reported found in ginger, nutmeg, pepper, mace, hop oil, coriander seed, calamus, dill herb, caraway seed and rosemary.

용도

(S)-(-)-Limonene is used to inhibit the proliferation of colon cancer cells. It is also used in artificial essential oils in order to produce (+)-carvone. It is an active component of turpentine. Further, it is used in flavorings, fragrances, and cosmetics. It finds application as a solvent and wetting agent. In addition to this it is used to produce resins.

제조 방법

d-Limonene may be obtained by steam distillation of citrus peels and pulp resulting from the production of juice and cold pressed oils, or from deterpenation of citrus oils; it is sometimes redistilled.

정의

ChEBI: An optically active form of limonene having (4S)-configuration.

일반 설명

(S)-(-)-Limonene, a monoterpenoid compound, is mostly used in perfumery and in flavoring. On irradiation, it undergoes radiolysis, which leads to a reduction in the optical purity. (S)-(-)-Limonene also shows potent antimicrobial activity.

색상 색인 번호

Limonene is a racemic form of dand l-limonene. d-Limonene is contained in Citrus species such as citrus, orange, mandarin, and bergamot. l-Limonene is contained in Pinus pinea.

Safety Profile

A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.

L-리모넨 준비 용품 및 원자재

원자재

준비 용품


L-리모넨 공급 업체

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