N-Phenyl-bis(trifluoromethanesulfonimide)
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N-Phenyl-bis(trifluoromethanesulfonimide) 속성
- 녹는점
- 100-102 °C(lit.)
- 끓는 점
- 305.3±52.0 °C(Predicted)
- 밀도
- 1.766±0.06 g/cm3(Predicted)
- 저장 조건
- Keep in dark place,Sealed in dry,Room Temperature
- 용해도
- 메탄올에 용해됩니다. 클로로포름과 에틸 아세테이트에 약간 용해됩니다.
- 산도 계수 (pKa)
- -13.12±0.50(Predicted)
- 물리적 상태
- 결정 또는 결정성 분말
- 색상
- 흰색 또는 무색
- 감도
- Moisture Sensitive
- BRN
- 1269141
- 안정성
- 수분에 민감한
- InChI
- InChI=1S/C8H5F6NO4S2/c9-7(10,11)20(16,17)15(6-4-2-1-3-5-6)21(18,19)8(12,13)14/h1-5H
- InChIKey
- DIOHEXPTUTVCNX-UHFFFAOYSA-N
- SMILES
- C(F)(F)(F)S(N(C1=CC=CC=C1)S(C(F)(F)F)(=O)=O)(=O)=O
- CAS 데이터베이스
- 37595-74-7(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | Xi | ||
---|---|---|---|
위험 카페고리 넘버 | 36/37/38 | ||
안전지침서 | 26-36 | ||
WGK 독일 | 3 | ||
F 고인화성물질 | 21 | ||
TSCA | No | ||
위험 등급 | IRRITANT | ||
HS 번호 | 29242100 |
N-Phenyl-bis(trifluoromethanesulfonimide) C화학적 특성, 용도, 생산
용도
제약 중간체개요
N-Phenylbis(trifluoromethanesulfonimide) acts as a mild triflating reagent as well as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes. It is also employed as a reactant for the preparation of amphoteric alfa-boryl aldehydes. It plays an important role in the enantioselective synthesis of the core ring skeleton of leucosceptroids A-D and in steroselective sulfoxidation.화학적 성질
white to off-white crystalline powderSynthesis
Add methylene chloride, aniline, 4-dimethylaminopyridine (DMAP), and triethylamine to a reactor equipped with a thermometer, distillation device, and mechanical stirring. When the vacuum of the reactor is evacuated to -0.095MPa and cooled to -40°C, trifluoromethanesulfonyl fluoride gas is introduced and then stirred at -20°C ~ 0°C and 0.02MPa ~ 0.1MPa reaction pressure, and react for 6 hours Finally, the excess trifluoromethanesulfonyl fluoride gas in the reactor is released and collected by cooling. After the inside of the reactor is brought to normal pressure, 500 mL of water is added, and the liquid is separated. A light yellow solid is obtained after the organic phase is heated to 40°C and methylene chloride is distilled. The light yellow solid is recrystallized with toluene to obtain 650g of white crystal N-Phenyl-bis(trifluoromethanesulfonimide).N-Phenyl-bis(trifluoromethanesulfonimide) 준비 용품 및 원자재
원자재
수소화나트륨
에틸알코올
염화나트륨
Trifluoromethanesulfonyl chloride
탄산 칼륨
트리플루오로메탄술폰산무수물
트리에틸아민
테트라하이드로푸란
아닐린
디클로로메탄
수산화나트륨
황산마그네슘
준비 용품
N-Phenyl-bis(trifluoromethanesulfonimide) 공급 업체
글로벌( 495)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Jiangxi Time Chemical CO Ltd | +86-0794-7183888 +86-13155888520 |
sales@groupchem.com | China | 27 | 58 |
Fluoropharm Co., Ltd. | +86-0571-85586753; +8613336034509 |
sales@fluoropharm.com | China | 1290 | 60 |
SHANGHAI T&W PHARMACEUTICAL CO., LTD. | +86-021-61551413 +8618813727289 |
contact@trustwe.com | China | 5738 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 |
sales@hbmojin.com | China | 12456 | 58 |
Zibo Hangyu Biotechnology Development Co., Ltd | +86-0533-2185556 +8617865335152 |
Mandy@hangyubiotech.com | China | 11013 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29797 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
info@dakenam.com | China | 15928 | 58 |
Beijing Cooperate Pharmaceutical Co.,Ltd | 010-60279497 |
sales01@cooperate-pharm.com | CHINA | 1811 | 55 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21691 | 55 |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 |
fandachem@gmail.com | China | 9348 | 55 |