2,3,5,6-테트라클로로페놀

2,3,5,6-테트라클로로페놀
2,3,5,6-테트라클로로페놀 구조식 이미지
카스 번호:
935-95-5
한글명:
2,3,5,6-테트라클로로페놀
동의어(한글):
2,3,5,6-테트라클로로페놀
상품명:
2,3,5,6-TETRACHLOROPHENOL
동의어(영문):
NSC 407823;2,3,5,6-TCP;2,3,5,6-TECP;2.3.5.6-Tetr;Fourchlorophenol;2,3,5,6-tetrachloro-pheno;2,3,5,6-Tetrachloropheno1;2,3,5,6-TETRACHLOROPHENOL;2,3,5,6-tetrachlorophenate;phenol,2,3,5,6-tetrachloro
CBNumber:
CB5311769
분자식:
C6H2Cl4O
포뮬러 무게:
231.89
MOL 파일:
935-95-5.mol

2,3,5,6-테트라클로로페놀 속성

녹는점
115-116℃ (isooctane )
끓는 점
331.59°C (rough estimate)
밀도
1.6 g/cm3 (60℃)
굴절률
1.5133 (estimate)
인화점
11 °C
저장 조건
APPROX 4°C
용해도
클로로포름(약간 용해됨), DMSO(약간 용해됨), 메탄올(약간 용해됨)
산도 계수 (pKa)
5.09±0.20(Predicted)
수용성
0.1g/L(25 ºC)
BRN
2049586
CAS 데이터베이스
935-95-5(CAS DataBase Reference)
EPA
2,3,5,6-Tetrachlorophenol (935-95-5)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T,F
위험 카페고리 넘버 25-37/38-41-39/23/24/25-23/24/25-11
안전지침서 26-39-45-36/37-16
유엔번호(UN No.) UN 2020 6.1/PG 3
WGK 독일 3
RTECS 번호 SM9450000
유해 물질 데이터 935-95-5(Hazardous Substances Data)
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H301 삼키면 유독함 급성 독성 물질 - 경구 구분 3 위험 GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P273 환경으로 배출하지 마시오.

2,3,5,6-테트라클로로페놀 C화학적 특성, 용도, 생산

화학적 성질

Brown solid; phenol odor. Soluble in sodium hydroxide solutions and most organic solvents; insoluble in water.

용도

Fungicide, wood preservative.

생산 방법

Chlorophenols are generally prepared by the chlorination of phenol. There are other routes of synthesis as through diazotizing p-chloroaniline or dechlorinating (by alkaline hydrolysis) 1,2,4,5-tetrachlorobenzene to yield 2,4,5-trichlorophenol (TCP). Polychlorinated dibenzo-p-dioxins can be formedduringthemanufacturingprocess of the chlorophenols. The amount formed depends on temperature and pressure process variability during production. The more notable toxic dioxin, 2,3,7,8-tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD), is formed during the production of 2,4,5- TCP. Laboratory reference standards of 2,3,7,8-TCDD are prepared by heating 2,4,5-TCP under alkaline conditions. All technical and formulated products containing 2,4,5-TCP are expected to be contaminated to varying degrees by this 2,3,7,8-TCDD by-product of the manufacturing process.

정의

ChEBI: The 2,3,5,6-isomer of tetrachlorophenol

일반 설명

Leaflets (from ligroin) or light beige powder.

공기와 물의 반응

Insoluble in water.

반응 프로필

2,3,5,6-TETRACHLOROPHENOL is incompatible with acid chlorides, acid anhydrides and oxidizing agents. .

위험도

Toxic by ingestion and inhalation, strong irritant.

화재위험

Flash point data for 2,3,5,6-TETRACHLOROPHENOL are not available. 2,3,5,6-TETRACHLOROPHENOL is probably combustible.

Carcinogenicity

There was no evidence of carcinogenic activity of 2,4-dichlorophenol in F344/N rats or B6C3F1 mice from the NTP bioassay program, but 2,4,6-trichlorophenol was reported to be carcinogenic in both species.

Purification Methods

Crystallise the phenol from pet ethers. The benzoate has m 136o (from EtOH). [Beilstein 6 II 182, 6 III 730, 6 IV 1025.]

2,3,5,6-테트라클로로페놀 준비 용품 및 원자재

원자재

준비 용품


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