헥실렌글리콜

헥실렌글리콜
헥실렌글리콜 구조식 이미지
카스 번호:
107-41-5
한글명:
헥실렌글리콜
동의어(한글):
헥실렌글리콜;헥실렌글라이콜;2-메틸-2,4-펜탄디올;2,4-디하이드록시-2-메틸펜탄;1,2-헥산디올;2-메틸-2,4-펜탄다이올;2-메틸-2,4-펜타네다이올
상품명:
2-Methyl-2,4-pentanediol
동의어(영문):
HEXYLENE GLYCOL;MPD;2-METHYLPENTANE-2,4-DIOL;3-METHYL-2,4-PENTANEDIOL;4-MPD;Hexalene glycol;Isol;HEXASOL;Diolane;Pinadon
CBNumber:
CB5353705
분자식:
C6H14O2
포뮬러 무게:
118.17
MOL 파일:
107-41-5.mol
MSDS 파일:
SDS

헥실렌글리콜 속성

녹는점
-40 °C (lit.)
끓는 점
197 °C (lit.)
밀도
0.925 g/mL at 25 °C (lit.)
증기 밀도
4.1 (vs air)
증기압
0.02 mm Hg ( 20 °C)
굴절률
n20/D 1.427(lit.)
인화점
201 °F
저장 조건
Store below +30°C.
용해도
H2O: 1 M at 20 °C, 투명, 무색
산도 계수 (pKa)
15.10±0.29(Predicted)
물리적 상태
약간 점성이 있는 액체
색상
투명한
냄새
암모니아와 비슷합니다.
수소이온지수(pH)
6-8 (25℃, 1M in H2O)
폭발한계
1-9.9%(V)
수용성
녹는
감도
Hygroscopic
최대 파장(λmax)
λ: 260 nm Amax: 0.01
λ: 280 nm Amax: 0.01
Merck
14,4710
BRN
1098298
노출 한도
ACGIH: TWA 25 ppm; STEL 50 ppm(10 mg/m3)
NIOSH: Ceiling 25 ppm(125 mg/m3)
Dielectric constant
24.399999999999999
안정성
안정적인. 강한 산화제, 강산, 강한 환원제와 호환되지 않습니다.
InChIKey
SVTBMSDMJJWYQN-UHFFFAOYSA-N
LogP
0 at 20℃
CAS 데이터베이스
107-41-5(CAS DataBase Reference)
NIST
2,4-Pentanediol, 2-methyl-(107-41-5)
EPA
Hexylene glycol (107-41-5)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 36/38
안전지침서 26-36
WGK 독일 1
RTECS 번호 SA0810000
F 고인화성물질 3-23
자연 발화 온도 425 °C DIN 51794
TSCA Yes
HS 번호 29053910
유해 물질 데이터 107-41-5(Hazardous Substances Data)
독성 LD50 orally in rats: 4.70 g/kg (Smyth, Carpenter)
기존화학 물질 KE-24702
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
예방조치문구:
P202 모든 안전 조치 문구를 읽고 이해하기 전에는 취급하지 마시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P308+P313 노출 또는 접촉이 우려되면 의학적인 조치· 조언를 구하시오.
NFPA 704
1
2 0

헥실렌글리콜 MSDS


2-Methylpentan-2,4-diol

헥실렌글리콜 C화학적 특성, 용도, 생산

화학적 성질

Hexylene Glycol is an oily colorless liquid with a mild sweet odor. It is an oxygenated solvent derived from acetone which has two alcohol functions. It has a low evaporation rate and it is completely miscible with water.

용도

(^+)-2-Methyl-2,4-pentanediol is used to control the flow properties of industrial products such as paints, coatings, cleansers, solvents, and hydraulic fluids. It acts as a thickening agent in cosmetic products. It serves as a coupling agent and an additive to hydraulic fluids, inks and cement. It is also employed as a blood volume expander. Further, it is used as a solvent for cleaning and colorant products. In addition to this, it is used in laboratory studies as a precipitant and cryoprotectant in protein crystallography.

생산 방법

2-Methyl-2,4-pentanediol is prepared commercially by the catalytic hydrogenation of diacetone alcohol . It is used as a chemical intermediate, a selective solvent in petroleum refining, a component of hydraulic fluids, a solvent for inks, and as an additive for cement . Industrial exposure is likely to be from direct contact or from inhalation, particularly if the material is heated.

정의

ChEBI: A glycol in which the two hydroxy groups are at positions 2 and 4 of 2-methylpentane (isopentane).

일반 설명

Oily colorless liquid with a mild sweet odor. Floats and mixes slowly with water.

공기와 물의 반응

Hygroscopic. Water soluble [Hawley]

반응 프로필

2-Methyl-2,4-pentanediol is incompatible with the following: Strong oxidizers, strong acids [Note: Hygroscopic (i.e., absorbs moisture from the air).] .

위험도

Toxic by ingestion and inhalation; irritant to skin, eyes, and mucous membranes. Combustible.

건강위험

Irritation of eyes, nose and throat; headache, dizziness, and nausea.

화학 반응

Reactivity with Water No reaction; Reactivity with Common Materials: Can catch fire when in contact with porous materials such as wood, asbestos, cloth, soil, or rusty metals; Stability During Transport: Stable at ordinary temperatures, however when heated this material can decompose to nitrogen and ammonia gases. The decomposition is not generally hazardous unless it occurs in confined spaces; Neutralizing Agents for Acids and Caustics: Flush with water and neutralize the resulting solution with calcium hypochlorite; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Purification Methods

Dry the diol with Na2SO4, then CaH2 and fractionally distil it under reduced pressure through a packed column, taking precautions to avoid absorption of water. [Beilstein 1 IV 2565.]

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