눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P310
즉시 의료기관(의사)의 진찰을 받으시오.
삼켰다면 즉시 의료기관(의사)의 도움을 받으시오.
NFPA 704
3
3
2
W
클로로디메틸비닐실란 C화학적 특성, 용도, 생산
화학적 성질
clear light beige to amber liquid
물리적 성질
bp 82–83°C; d 0.874 gmL?1 at 25°C.
용도
Metallacycloalkanones have been prepared
by the cyclic hydroboration of dialkenyl silanes. In order to obtain
one such dialkenyl silane, chlorodimethylvinylsilane was allylated
with allyl magnesium bromide (eq 4).The dialkenyl silane
was then hydroborated sequentially with thexylborane, followed
by treatment with potassium cyanide, trifluoroacetic anhydride,
and finally hydrogen peroxide in sodium hydroxide to produce
the silacycloheptanone (eq 4).Cyclic silylketones were then
further reacted to form acyclic compounds with chiral centers that
are difficult to introduce without the use of the silicon tether.
일반 설명
Chloro(dimethyl)vinylsilane (Dimethylvinylchlorosilane, Vinyldimethylchlorosilane, C4H9ClSi) is an organosilicon compound. It participates in the preparation of 1,1,2,2-tetramethyl-1,2-divinyldisilane. It undergoes [2+4] cycloaddition reaction with t-butyllithium in the presence of 2,3-dimethyl-1,3-butadiene to afford cycloadducts.