ChemicalBook
Chinese English Japanese Germany Korea

트리메틸알루미늄

트리메틸알루미늄
트리메틸알루미늄 구조식 이미지
카스 번호:
75-24-1
한글명:
트리메틸알루미늄
동의어(한글):
트리메틸알루미늄;트라이메틸 알루미늄
상품명:
Trimethylaluminium
동의어(영문):
TMA;ATM;(CH3)3Al;A-T mutated;Trimethylalane;trimethyl-alane;Trimethylalumine;trimethyl-aluminu;TRIMETHYLALUMINUM;TRIMETHYLALUMINIUM
CBNumber:
CB5374238
분자식:
C3H9Al
포뮬러 무게:
72.09
MOL 파일:
75-24-1.mol

트리메틸알루미늄 속성

녹는점
15 °C
끓는 점
126 °C
밀도
0.81 g/mL at 25 °C
증기압
69.3 mmHg ( 60 °C)
인화점
40 °F
저장 조건
0-6°C
용해도
Soluble in aromatic, saturated aliphatic and cycloaliphatic hydrocarbons.
물리적 상태
Liquid
색상
Clear colorless
Specific Gravity
0.688
Specific Gravity
0.81
냄새
Corrosive odor and "taste" may be detectable from trimethylaluminum fires
수용성
REACTS
감도
Air & Moisture Sensitive
Hydrolytic Sensitivity
9: reacts extremely rapidly with atmospheric moisture - may be pyrophoric - glove box or sealed system required
BRN
3587197
InChIKey
JLTRXTDYQLMHGR-UHFFFAOYSA-N
CAS 데이터베이스
75-24-1(CAS DataBase Reference)
NIST
Trimethylaluminum(75-24-1)
EPA
Aluminum, trimethyl- (75-24-1)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 F,C,N
위험 카페고리 넘버 11-14-17-34-50/53-65-67-14/15-63-48/20-51/53-20-62
안전지침서 26-36/37/39-45-61-62-6A-43A-24/25-16-43-60-33-25-24
유엔번호(UN No.) UN 3399 4.3/PG 1
WGK 독일 3
RTECS 번호 BD2204000
F 고인화성물질 1-10
자연 발화 온도 Spontaneously ignites in air (even as a frozen solid)
TSCA Yes
위험 등급 4.3
포장분류 I
HS 번호 29319090
독성 TLV-TWA (ACGIH) 2 mg (Al)/m3
기존화학 물질 KE-05-1326
그림문자(GHS):
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H225 고인화성 액체 및 증기 인화성 액체 구분 2 위험 P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H250 공기에 노출되면 스스로 발화함 자연발화성 액체;자연발화성 고체 구분 1 위험 P210, P222, P280, P302+P334,P370+P378, P422
H260 물과 접촉시 자연 발화성 인화성 가스를 발생시킴 물반응성 물질 및 혼합물 구분 1 위험 P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H304 삼켜서 기도로 유입되면 치명적일 수 있음 흡인 유해성물질 구분 1 위험
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 눈에 심한 손상을 일으킴 심한 눈 손상 또는 자극성 물질 구분 1 위험 P280, P305+P351+P338, P310
H336 졸음 또는 현기증을 일으킬 수 있음 특정표적장기 독성 물질(1회 노출);마취작용 구분 3 경고 P261, P271, P304+P340, P312,P403+P233, P405, P501
H361 태아 또는 생식능력에 손상을 일으킬 것으로 의심됨 생식독성 물질 구분 2 경고 P201, P202, P281, P308+P313, P405,P501
H373 장기간 또는 반복 노출되면 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킬 수 있음 특정 표적장기 독성 - 반복 노출 구분 2 경고 P260, P314, P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 P273, P391, P501
H411 장기적 영향에 의해 수생생물에 유독함 수생 환경유해성 물질 - 만성 구분 2
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P223 물과 접촉하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P231+P232 불활성 기체 하에서 취급하고, 습기를 방지하시오.
P331 토하게 하지 마시오.
P301+P310 삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
P302+P334 피부에 묻은 경우,냉수에 담그기/젖은 붕대로 감싸기
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P370+P378 화재 시 불을 끄기 위해 (Section 5. 폭발, 화재시 대처방법의 적절한 소화제)을(를) 사용하시오.
P405 밀봉하여 저장하시오.
P422 적절한 물질을(를) 충진하여 보관하시오.
NFPA 704
3
3

트리메틸알루미늄 MSDS


Aluminumtrimethanide

트리메틸알루미늄 C화학적 특성, 용도, 생산

화학적 성질

The aluminum alkyls are highly flammable and reactive, colorless to yellow liquids at room temperature. The lighter trialkylaluminums ignite spontaneously in air. They are normally supplied and used in a 20% solution with a hydrocarbon solvent, such as hexane, heptane, benzene, toluene. Properties may depend on solvent. Reacts violently with water.

용도

Trimethylaluminium can be used as catalyst for olefin polymerization, pyrophoric fuel, manufacture of straight-chain primary alcohols and olefins, to produce luminous trails in upper atmosphere to track rockets.

용도

Trimethyl aluminum is a highly reactivereducing and alkylating agent. It is used in aZiegler-Natta catalyst for polymerization andhydrogenation.

용도

Trimethylaluminum can be used in the pretreatment of Al2O3/p-type GaSb capacitors.

정의

A colorless liquid produced by the sodium reduction of dimethyl aluminum chloride. It ignites spontaneously on contact with air and reacts violently with water, acids, halogens, alcohols, and amines. Aluminum alkyls are used in the Ziegler process for the manufacture of high-density polyethene.

건강위험

As it is pyrophoric and reacts explosivelywith moisture, skin contact can cause a dangerousburn. Contact with eyes can causeblindness. Because of its significant volatility,the risk of inhalation of this compoundis higher than with most other alkyls. Inhalationof its vapors can severely damage therespiratory tract.
TLV-TWA: 2 mg(Al)/m3 (ACGIH).

건강위험

Trimethylaluminum and related alkylaluminum reagents are pyrophoric materials that can react explosively with the moisture in tissues, causing severe burns. The heat of reaction can also ignite the methane gas generated, resulting in thermal burns. Alkylaluminum reagents are corrosive substances, and contact is extremely destructive to the eyes, skin, and mucous membranes. Inhalation of trimethylaluminum and other volatile alkylaluminum compounds may cause severe damage to the respiratory tract and can lead to fatal pulmonary edema.

인화성 및 폭발성

Trimethylaluminum is pyrophoric and burns violently on contact with air or water. Other alkylaluminum reagents show similar behavior, although most are not as volatile as trimethylaluminum. Water or CO2 fire extinguishers must not be used to put out fires involving trialkylaluminum reagents. Instead, dry chemical powders such as bicarbonate, Met-L-X?, or inert smothering agents such as sand or graphite should be used to extinguish fires involving trialkylaluminum compounds.

잠재적 노출

Alkyl aluminum compounds are used as components of olefin polymerization catalysts. They are also used in the synthesis of higher primary alcohols and in pyrophoric fuels, as a catalyst in making ethylene gas; and in plating aluminum.

저장

Safety glasses, impermeable gloves, and a fire-retardant laboratory coat should be worn at all times when working with these compounds. Trialkylaluminum reagents should be handled only under an inert atmosphere.

운송 방법

ntial fire or explosion hazard. Shipping: UN3399 Organometallic substance, liquid, water-reactive, flammable, Hazard Class: 4.3; Labels: 4.3 Dangerous Dangerous when wet material, 3-Flammable liquid, technical name Required. UN3051-Spontaneously combustible. Also, this material is dangerous when wet. (Note: this number does not appear in the 49/CFR HazMat tables).

비 호환성

The lighter trialkylaluminums ignite spontaneously in air; can self-heat in the air at room temperature without any added energy and may ignite. These compounds are strong reducing agents. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Incompatible with water, oxygen (air), acids, alcohols, phenols, amines, carbon dioxide; sulfur oxides; halogenated compounds, and many other substances

폐기물 처리

Careful incineration

트리메틸알루미늄 준비 용품 및 원자재

원자재

준비 용품


트리메틸알루미늄 공급 업체

글로벌( 159)공급 업체
공급자 전화 팩스 이메일 국가 제품 수 이점
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com China 22607 55
career henan chemical co
+86-0371-55982848
sales@coreychem.com China 29953 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 linda@hubeijusheng.com CHINA 23035 58
Chongqing Chemdad Co., Ltd
+86-13650506873
sales@chemdad.com CHINA 37282 58
CONIER CHEM AND PHARMA LIMITED
86-18523575427
sales@conier.com China 47498 58
Zhuozhou Wenxi import and Export Co., Ltd
+8613111626072 (WhatsApp)
Wechat: +8613111626072 Wickr me: waynehu zzwenxi@126.com CHINA 13187 58
Fuxin Pharmaceutical
021-50872116
contact@fuxinpharm.com CHINA 10305 58
Antai Fine Chemical Technology Co.,Limited
18503026267
info@antaichem.com CHINA 9664 58
Hunan russell chemicals technology co ltd
13739093081 +86-182-2994-0868
sales01@russellchem.com CHINA 291 58
Shaanxi Dideu Medichem Co. Ltd
18192503167 +86-29-89586680
+86-29-88380327 1005@dideu.com CHINA 9938 58

트리메틸알루미늄 관련 검색:

Copyright 2019 © ChemicalBook. All rights reserved