초산 제2아밀

초산 제2아밀
초산 제2아밀 구조식 이미지
카스 번호:
626-38-0
한글명:
초산 제2아밀
동의어(한글):
초산이차-아밀;초산제2아밀;초산이차-아밀;2-페닐 아세테이트
상품명:
1-METHYLBUTYL ACETATE
동의어(영문):
2-Acetoxypentane;sec-Amyl acetate;SEC-PENTYL ACETATE;pentan-2-yl acetate;2-Pentanol, acetate;1-Methylbutylacetat;1-METHYLBUTYL ACETATE;pentan-2-yl ethanoate;2-Pentanol, 2-acetate;ACETIC ACID-2-PENTYL ESTER
CBNumber:
CB5451876
분자식:
C7H14O2
포뮬러 무게:
130.18
MOL 파일:
626-38-0.mol
MSDS 파일:
SDS

초산 제2아밀 속성

녹는점
-74.65°C (estimate)
끓는 점
134.85°C
밀도
0.8628
증기압
10 at 35.2 °C (estimated, Weast, 1986)
굴절률
1.3969
FEMA
4012 | 2-PENTYL ACETATE
용해도
Soluble in alcohol, ether (Weast, 1986), and many other organic solvents including esters and glycols.
물리적 상태
액체
냄새
100.00%에서. 풀 풀 잡초 곰팡내 나는 녹색 야채 너트 피부 콩 같은 케톤체 동물
?? ??
약초
수용성
25°C에서 2.2g/L(몽고메리, 1989)
JECFA Number
1146
Henry's Law Constant
(x 10-4 atm?m3/mol): 7.7 at 25 °C (approximate - calculated from water solubility and vapor pressure)
노출 한도
NIOSH REL: TWA 125 ppm (650 mg/m3), IDLH 1,000 ppm; OSHA PEL: TWA 125 ppm; ACGIH TLV: TWA 125 ppm with intended TWA and STEL values of 50 and 100 ppm, respectively.
안정성
휘발성 물질
LogP
2.12
EPA
sec-Amyl acetate (626-38-0)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험 카페고리 넘버 10
안전지침서 16
유엔번호(UN No.) UN 1104 3/PG 3
위험 등급 3.2
포장분류 III
유해 물질 데이터 626-38-0(Hazardous Substances Data)
IDLA 1,000 ppm
기존화학 물질 KE-23642
그림문자(GHS): GHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H225 고인화성 액체 및 증기 인화성 액체 구분 2 위험 GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P233 용기를 단단히 밀폐하시오. 용기는 환기가 잘 되는 곳에 단단히 밀폐하여 보관하시오.
P240 용기와 수용설비를 접지 및 접합시키시오.
P241 폭발 방지용 장비[전기적/환기/조명/...]을(를) 사용하시오.
P242 스파크가 발생하지 않는 도구를 사용하시오
P243 정전기 방지 조치를 취하시오.
NFPA 704
3
1 0

초산 제2아밀 C화학적 특성, 용도, 생산

화학적 성질

All isomers of amyl acetate are highly flammable, colorless to yellow, watery liquids.

물리적 성질

Clear, colorless liquid with a fruity odor. Odor threshold concentration is 2.0 ppb (quoted, Amoore and Hautala, 1983).

출처

Reportedly present in over 50 products including apple, apple juice, grape (muscat), apricot, banana, cherry, guava, melon, peach, blackberry, pear, strawberry, nectarine, potato, tomato, cocoa liquor, and vinegar.

용도

Solvent for nitrocellulose and ethyl cellulose, cements, coated paper, lacquers, leather finishes, nail enamels, plastic wood, textile sizing, and print- ing compounds.

제조 방법

Prepared from alcohols using acetic acid as an acetylating agent and clays as catalysts (patented process).

일반 설명

Colorless to yellow watery liquid with a weak odor of bananas. Floats on water. Produces irritating vapor.

공기와 물의 반응

Highly flammable. Slightly water soluble.

반응 프로필

1-METHYLBUTYL ACETATE is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. 1-METHYLBUTYL ACETATE is incompatible with the following: Nitrates; strong oxidizers, alkalis & acids .

위험도

Flammable, moderate fire risk. Toxic. Upper respiratory tract irritant.

건강위험

INHALATION AND INGESTION: Irritates the mucous membrane, depresses the central nervous system, and is a narcotic. Damage to kidney, liver, and lung can occur. Ingestion may irritate gastro-intestinal tract. EYES: Irritation. Skin: Irritation.

Safety Profile

Mildly toxic by inhalation. Human systemic effects by inhalation: conjunctiva irritation. Dangerous fire hazard when exposed to heat or flame; can react with oxidizing materials. Moderately explosive in the form of vapor when exposed to heat or flame. To fight fire, use alcohol foam, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.

잠재적 노출

(n-isomer): Primary irritant (w/o allergic reaction), (sec-isomer) Human Data. Amyl acetates are used as industrial solvents and in the manufacturing and dry-cleaning industry; making artificial fruit-flavoring agents; cements, coated papers, lacquers; in medications as an inflammatory agent; pet repellents, insecticides and miticide. Many other uses.

환경귀착

Chemical/Physical. Slowly hydrolyzes in water forming acetic acid and 2-pentanol.

운송 방법

UN1993 Flammable liquids, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, Technical Name Required.

비 호환성

Vapors may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, nitrates. May soften certain plastics.

폐기물 처리

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

초산 제2아밀 준비 용품 및 원자재

원자재

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