페노티오캅

페노티오캅
페노티오캅 구조식 이미지
카스 번호:
62850-32-2
한글명:
페노티오캅
동의어(한글):
페노티오캅;(S)-4-펜옥시뷰틸 다이메틸티오카바메이트, 펜노티오캅;파노콘
상품명:
FENOTHIOCARB
동의어(영문):
bi-5452;PANOCON;kco-3001;PANOCON(R);FENOTHIOCARB;Fenothiocard;phenothiocarb;FENOTHIOCARB-D6;FENOTHIOCARB STANDARD;Fenothiocarb solution
CBNumber:
CB5753004
분자식:
C13H19NO2S
포뮬러 무게:
253.36
MOL 파일:
62850-32-2.mol
MSDS 파일:
SDS

페노티오캅 속성

녹는점
40.5℃
끓는 점
155 °C
밀도
1.1414 (rough estimate)
증기압
1.6 x l0-5 Pa (23 °C)
굴절률
1.6800 (estimate)
저장 조건
0-6°C
수용성
30mg l-1(20°C)
산도 계수 (pKa)
-1.21±0.70(Predicted)
BRN
2125738
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,N
위험 카페고리 넘버 22-50
안전지침서 61
유엔번호(UN No.) UN 3077 9 / PGIII
WGK 독일 3
RTECS 번호 FD3825000
HS 번호 29309090
기존화학 물질 KE-05-0990
유해화학물질 필터링 97-1-330
함량 및 규제정보 물질구분: 유독물질; 혼합물(제품)함량정보: 페노티오캅 및 이를 25% 이상 함유한 혼합물
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H400 수생생물에 매우 유독함 수생 환경유해성 물질 - 급성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P273 환경으로 배출하지 마시오.

페노티오캅 C화학적 특성, 용도, 생산

용도

Fenothiocarb is an acaricide used to control the eggs and young stages of Panonychus citri, Panonychus ulmi and other Panonychus spp.

신진 대사 경로

When the red mite, applied with 14C-fenothiocarb by the contact method, metabolizes fenothiocarb, resulting in several metabolites via the primary oxidation of the N-methyl moiety. The photodegradation of fenothiocarb on silica gel plate exposed to sunlight gives rise to several degradation products. A primary photochemical reaction seems to be the oxidation of the sulfur atom to form its sulfoxide. Under greenhouse conditions, when fenothiocarb is applied to the citrus trees, the major metabolites identified in the leaves, rinds, and edible fruit are 6-O-malonyl-b-D-glucosode of N- hydroxymethyl fenothiocarb, N-formylfenothiocarb, and glucoside conjugate of phenol (not shown in the map), respectively. In soils, fenothiocarb is more rapidly degraded under upland conditions than under flooded conditions. Main degradation pathways include oxidation of the sulfur atom which results in the formation of methyl-4-phenoxybutylsulfoxide, its sulfone, and 4-phenoxybutylsulfonic acid.

Degradation

Fenothiocarb has long residual activity. It is stable to hydrolysis for 5 days (pH 5-9, 40 °C) but it is decomposed slowly by sunlight (PM). [U-14C-phenyl]Fenothiocarb was applied to the origin of silica gel TLC plates and exposed to sunlight in September or October. The plates were developed, with authentic standard compounds also applied, in two dimensions using different solvent systems. After 72 hours exposure to sunlight, 34% of parent fenothiocarb remained (DT50 45 hours). Twelve photoproducts were detected. Products that were identified are illustrated in Scheme 1 and were N-formyl-fenothiocarb (2), desmethyl-fenothiocarb (3) the bis(4-phenoxybutyl) thiolsulfinate (4), the bis(4-phenoxybutyl) thiolsulfonate (5), the sulfoxide derivative (6) and 4-phenoxybutanesulfonic acid (7). The latter two compounds were major products. The primary photochemical reaction was oxidation of sulfur to form fenothiocarb sulfoxide (6) followed by cleavage of the ester linkage and the oxidation or dimerisation of the 4-phenoxybutanesulfenic acid intermediate. The second main route of photodegradation was oxidation of the N-methyl moiety of fenothiocarb (Unai and Tomiwaza, 1986b).

페노티오캅 준비 용품 및 원자재

원자재

준비 용품


페노티오캅 공급 업체

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