피로갈롤

피로갈롤
피로갈롤 구조식 이미지
카스 번호:
87-66-1
한글명:
피로갈롤
동의어(한글):
피로갈롤;1,2,3-벤젠트리올;1,2,3-벤젠트리올;C.I.산화염기32;2,3-디하이드록시페놀;피로갈륨산
상품명:
Pyrogallol
동의어(영문):
benzene-1,2,3-triol;1,2,3-Benzenetriol;1,2,3-Trihydroxybenzene;Pyrogallo;Piral;pyrogallic;1,2,3-Trihydroxybenzen;PyrogaL;PYROGALL;fourrine85
CBNumber:
CB6107909
분자식:
C6H6O3
포뮬러 무게:
126.11
MOL 파일:
87-66-1.mol
MSDS 파일:
SDS

피로갈롤 속성

녹는점
43-47 °C(lit.)
끓는 점
309 °C
밀도
1.112 g/mL at 25 °C(lit.)
증기 밀도
4.4 (vs air)
증기압
10 mm Hg ( 167.7 °C)
굴절률
n20/D 1.387
인화점
>230 °F
저장 조건
Store below +30°C.
용해도
물에 용해
물리적 상태
매우 미세한 결정성 분말
산도 계수 (pKa)
pK1:9.03(0);pK2:11.63(+1) (25°C)
색상
하얀색
수소이온지수(pH)
4-5 (50g/l, H2O, 20℃)
수용성
400g/L(25℃)
감도
Light Sensitive
Merck
14,8000
BRN
907431
안정성
안정적이지만 빛에 따라 탈색됩니다. 타기 쉬운. 강산화제, 알칼리, 금속 산화물, 암모니아, 안티피린, 페놀, 요오드, 석회수, 멘톨, 과망간산 칼륨, 강염기와 호환되지 않습니다.
InChIKey
WQGWDDDVZFFDIG-UHFFFAOYSA-N
LogP
-0.47
CAS 데이터베이스
87-66-1(CAS DataBase Reference)
NIST
1,2,3-Benzenetriol(87-66-1)
EPA
Pyrogallol (87-66-1)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn
위험 카페고리 넘버 20/21/22-52/53-68-40-36/38
안전지침서 22-24/25-61-36/37-26
유엔번호(UN No.) UN 2811 6.1/PG 3
WGK 독일 3
RTECS 번호 UX2800000
F 고인화성물질 8
TSCA Yes
HS 번호 2907 29 00
위험 등급 6.1
포장분류 III
유해 물질 데이터 87-66-1(Hazardous Substances Data)
독성 LD50 orally in rabbits: 1.6 g/kg (Dollahite)
기존화학 물질 KE-02669
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H341 유전적인 결함을 일으킬 것으로 의심됨 (노출되어도 생식세포 유전독성을 일으키지 않는다는 결정적인 증거가 있는 노출경로가 있다면 노출경로 기재) 생식세포 변이원성 물질 구분 2 경고 P201,P202, P281, P308+P313, P405,P501
H412 장기적 영향에 의해 수생생물에 유해함 수생 환경유해성 물질 - 만성 구분 3 P273, P501
예방조치문구:
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P308+P313 노출 또는 접촉이 우려되면 의학적인 조치· 조언를 구하시오.
NFPA 704
0
3 0

피로갈롤 C화학적 특성, 용도, 생산

화학적 성질

White or nearly white needle- or leaf-shaped crystals or crystalline powder.Pyrogallol is practically odorless.

용도

Pyrogallol possesses importance as a spectrophotometric reagent in the determination of niobium and tantalum. The absorptions of niobium and tantalum complexes are usually measured at 340 and 335 nm, respectively. The niobium complex is formed in slightly acidic medium, and the tantalum complex in strongly acidic medium (4 N HC1). The absorption spectra are pH-dependen.

생산 방법

Pyrogallol is prepared by heating dried gallic acid at about 200°C with the loss of carbon dioxide or by the chlorination of cyclohexanol to tetrachlorocyclohexanone, followed by hydrolysis.

정의

ChEBI: A benzenetriol carrying hydroxy groups at positions 1, 2 and 3.

일반 설명

Odorless white to gray solid. Sinks and mixes with water.

공기와 물의 반응

Turns gray on exposure to light or air. Water soluble.

반응 프로필

Pyrogallol is a strong reducing agent. Reacts with alkalis, NH3, antipyrine, camphor, phenol, iron and lead salts, iodine, lime water, menthol and KMnO4.

위험도

Toxic by ingestion and skin absorption.

건강위험

Inhalation of dust causes irritation of nose and throat. Ingestion may cause severe gastrointestinal irritation, convulsions, circulatory collapse, and death. Contact with eyes causes irritation. Skin contact can cause local discoloration, irritation, eczema, and death; repeated contact can cause sensitization.

화재위험

Pyrogallol is probably combustible.

색상 색인 번호

Pyrogallol belongs to the phenols group. It is an old photograph developer and a low sensitizer in hair dyes.

Safety Profile

Human poison by ingestion and subcutaneous routes. An experimental poison by ingestion, subcutaneous, intravenous, and intraperitoneal routes. Experimental teratogenic and reproductive effects. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. 1 198 PPRSOO PYROSULFURYL CHLORIDE Readdy absorbed through the skin. Human systemic effects by ingestion: convulsions, dyspnea, gastrointestinal effects. A severe skin and eye irritant. Incompatible with alkalies, NH3, antipyrine, phenol, iron and lead salts, iodine, KMn04. When heated to decomposition it emits acrid smoke and irritating fumes. Used as a topical antibacterial agent, as an intermediate, hair dye component, and analytical reagent.

Carcinogenicity

Pyrogallol was not carcinogenic in mouse and rabbit chronic dermal studies. Mice were treated twice weekly with pyrogallol in acetone (50%) on the shaved flank for life. There was no increase in dermal or systemic tumors. A similar study in rabbits also revealed no skin tumors, although positive controls showed an increase in tumors in both mice and rabbits.
Pyrogallol was considered to be cocarcinogenic when administered dermally three times a week together with the skin carcinogen benzo[a]pyrene for 440 days; pyrogallol administered alone caused no increase in skin tumors.

피로갈롤 준비 용품 및 원자재

원자재

준비 용품


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