Diclofop-methyl

Diclofop-methyl 구조식 이미지
카스 번호:
51338-27-3
상품명:
Diclofop-methyl
동의어(영문):
HOELON;Hoelan;Iloxan;NOGRASS;ILLOXAN;HOEGRASS;HOXAN(R);DICLOSAN;ELOGRASS;HOELON(R)
CBNumber:
CB6118732
분자식:
C16H14Cl2O4
포뮬러 무게:
341.19
MOL 파일:
51338-27-3.mol
MSDS 파일:
SDS

Diclofop-methyl 속성

녹는점
39-41°C
끓는 점
173-175°C (0.1 mbar)
밀도
1.3
굴절률
1.5300 (estimate)
저장 조건
0-6°C
수용성
0.005g/100mL
Merck
13,3109
BRN
2224754
LogP
4.620
CAS 데이터베이스
51338-27-3(CAS DataBase Reference)
NIST
Propanoic acid, 2-[4-(2,4-dichlorophenoxy)phenoxy]-, methyl ester(51338-27-3)
EPA
Diclofop methyl (51338-27-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn;N,N,Xn
위험 카페고리 넘버 22-43-50/53
안전지침서 24-37-60-61
유엔번호(UN No.) UN 3077
WGK 독일 2
RTECS 번호 UF1180000
HS 번호 29189900
유해 물질 데이터 51338-27-3(Hazardous Substances Data)
독성 dog,LD50,oral,1600mg/kg (1600mg/kg),"Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A138, Pg. 1983,
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.

Diclofop-methyl C화학적 특성, 용도, 생산

화학적 성질

A white crystalline solid. Odorless. Can also be commercially available as a clear to dark brown liquid with a typical solvent odor

용도

Herbicide.

일반 설명

Colorless crystals. Decomposed by either strong acid or base. Used as a selective herbicide.

공기와 물의 반응

Slightly soluble in water (3 mg/l).

반응 프로필

A bridged diphenyl.

위험도

Moderately toxic by ingestion and skin contact. Low toxicity by inhalation.

농업용

Herbicide: Some uses are classified as U.S. Restricted Use Pesticide (RUP). Diclofop-methyl is a selective post-emergence herbicide used to control wild oats and annual grassy weeds in grain and vegetable crops: alfalfa, carrots, celery, box, field and french beans, barley, wheat, brassicas, parsnips, peas, potatoes, rapeseed (canola), soy beans, oilseed rape, onions, sugar beets and lettuce.

상품명

DICHLORDIPHENPROP®; HOELON®; HOELON® 3EC; HOE-GRASS®; HOEGRASS®; HOE® 23408; ILOXAN®; ILLOXAN®; ONE SHOT®[C]

잠재적 노출

Diclofop-methyl is a chlorophenoxy; aryloxyphenoxypropionate acid selective postemergenceherbicide used to control wild oats and annual grassy weeds in grain and vegetable crops: alfalfa, carrots, celery, box, field and French beans, barley, wheat, brassicas, parsnips, peas, potatoes, rapeseed (canola), soy beans, oilseed rape, onions, sugar beets and lettuce. Some uses are classified RUP

환경귀착

Biological. From the first-order biotic and abiotic rate constants of diclofop-methyl in estuarine water and sediment/water systems, the estimated biodegradation half-lives were 0.24–12.4 and 0.11–2.2 days, respectively (Walker et al., 1988).

신진 대사 경로

Two resistant biotypes of black-grass (Peldon A1 and Lincs. E1 of Alopecurus myosuroides) exhibit moderately enhanced metabolism of 14C-diclofop methyl. Diclofop methyl is hydrolyzed to the corresponding propionic acid which undergoes further degradation to give polar metabolites. The amounts of the metabolites depend on the metabolism activity of the individual biotypes. In wheat, three isomeric hydroxylated metabolites are identified in a major metabolic pathway after acid hydrolysis of the glucoside conjugates.

운송 방법

UN3345 Phenoxyacetic acid derivative pesticide, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3348 Phenoxyacetic acid derivative pesticide, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous material. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required. Note: Commercial product may also be a liquid in a flammable carrier.

비 호환성

Incompatible with oxidizers, chlorates nitrates, peroxides, sulfuric acid, caustics, ammonia, aliphatic amines, alkanolamines, isocyanates, alkylene oxides, and epichlorohydrin.

폐기물 처리

In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office

Diclofop-methyl 준비 용품 및 원자재

원자재

준비 용품


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