D(-)-과당

D(-)-과당
D(-)-과당 구조식 이미지
카스 번호:
57-48-7
한글명:
D(-)-과당
동의어(한글):
과일설탕;레불로즈;프럭톤;플럭토즈,D-;D-과당;과당(케토헥소스에속한다);아라비노-헥술로즈;프룩토오스;플럭토즈;과당
상품명:
D(-)-Fructose
동의어(영문):
FRUCTOSE;D-FRUCTOSE;Fluctose;D-(-)-Fructose 〔Levulose〕;Fructose Standard, 18000ppm;Krystar;d-fructos;LAEVULOSE;Fructose CRS;D-(-)-Fructose ,99% [Natural]
CBNumber:
CB6139083
분자식:
C6H12O6
포뮬러 무게:
180.16
MOL 파일:
57-48-7.mol
MSDS 파일:
SDS

D(-)-과당 속성

녹는점
119-122 °C (dec.)(lit.)
알파
-92.25 º (c=10,H2O,on dry sub.)
끓는 점
232.96°C (rough estimate)
밀도
1.59
굴절률
-92 ° (C=4, H2O)
저장 조건
room temp
용해도
H2O: 1 M at 20 °C, 투명, 무색
산도 계수 (pKa)
pKa (18°): 12.06
물리적 상태
결정 또는 결정성 분말
색상
하얀색
수소이온지수(pH)
5.0-7.0 (25℃, 0.1M in H2O)
냄새
100.00%에서. 냄새 없는
?? ??
냄새 없는
optical activity
[α]20/D 93.5 to 91.0°, c = 10% in H2O
수용성
3750g/L(20℃)
최대 파장(λmax)
λ: 260 nm Amax: 0.04
λ: 280 nm Amax: 0.04
Merck
14,4273
BRN
1239004
안정성
안정적인. 강한 산화제와 호환되지 않습니다.
InChIKey
LKDRXBCSQODPBY-GWVKGMJFSA-N
LogP
-1.029 (est)
CAS 데이터베이스
57-48-7(CAS DataBase Reference)
NIST
«beta»-D-Fructose(57-48-7)
EPA
D-Fructose (57-48-7)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 C
위험 카페고리 넘버 34
안전지침서 24/25-45-36/37/39-27-26
WGK 독일 3
RTECS 번호 LS7120000
F 고인화성물질 3
자연 발화 온도 360 °C
TSCA Yes
HS 번호 17025000
기존화학 물질 KE-17262
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P271 옥외 또는 환기가 잘 되는 곳에서만 취급하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
NFPA 704
1
1 0

D(-)-과당 MSDS


Fruit sugar

D(-)-과당 C화학적 특성, 용도, 생산

개요

과당이라 함은 전분을 주원료로 하여 당화시켜 얻은 포도당액을 이성화한 것이거나, 설탕을 가수분해하여 얻은 당액을 가공한 것으로 액상과당, 결정과당 등을 말한다.

용도

첨용 용도로는 감미, 노화방지, 부패방지, 보습성 증가, 향 증가, 색깔 및 식감 향상에 사용한다. 시약용 용도로는 화학적 방법에 의한 물질의 검출이나 정량을 위한 R&D용으로 사용한다.

화학적 성질

White Cyrstalline Solid

역사

Despite this ubiquity, fructose remained a noncommercial product until the 1980s because of the expense involved in its isolation and the care required for its handling. The development of technologies for preparing fructose from glucose in the isomerized mixture led to a greater availability of pure, crystalline fructose in the 1970s. However, the price for pure fructose was high enough in 1981 that the product was not competitive with sucrose and corn syrups as a commercial sweetener. With the entry of corn wet-milling companies into the crystalline fructose market in the late 1980s, raw material economies and enlarged manufacturing scale led to a nearly 10-fold production increase within a five-year period, making fructose prices competitive with other sweeteners for specific applications.

용도

D-Fructose occurs in a large number of fruits, honey, and as the sole sugar in bull and human semen

정의

A sugar found in fruit juices, honey, and cane sugar. It is a ketohexose, existing in a pyranose form when free. In combination (e.g. in sucrose) it exists in the furanose form.

생산 방법

Fructose, a monosaccharide sugar, occurs naturally in honey and a large number of fruits. It may be prepared from inulin, dextrose, or sucrose by a number of methods. Commercially, fructose is mainly manufactured by crystallization from high-fructose syrup derived from hydrolyzed and isomerized cereal starch or cane and beet sugar.

일반 설명

Fructose is a monosaccharide. It is present in fruits and vegetables. Fructose is the major carbohydrate in the diet. It binds with glucose to form sucrose. Excessive intake of fructose is associated with obesity, type 2 diabetes and cardiovascular disease.

Safety

Although it is absorbed more slowly than dextrose from the gastrointestinal tract, fructose is metabolized more rapidly. Metabolism of fructose occurs mainly in the liver, where it is converted partially to dextrose and the metabolites lactic acid and pyruvic acid. Entry into the liver and subsequent phosphorylation is insulinindependent. Further metabolism occurs by way of a variety of metabolic pathways. In healthy and well regulated diabetics, glycogenesis (glucose stored as glycogen) predominates.
Excessive oral fructose consumption (>75 g daily) in the absence of dietary dextrose in any form (e.g. sucrose, starch, dextrin, etc.) may cause malabsorption in susceptible individuals, which may result in flatulence, abdominal pain, and diarrhea. Except in patients with hereditary fructose intolerance, there is no evidence to indicate that oral fructose intake at current levels is a risk factor in any particular disease, other than dental caries.

저장

Fructose is hygroscopic and absorbs significant amounts of moisture at relative humidities greater than 60%. Goods stored in the original sealed packaging at temperatures below 25°C and a relative humidity of less than 60% can be expected to retain stability for at least 12 months.
Aqueous solutions are most stable at pH 3–4 and temperatures of 4–70°C; they may be sterilized by autoclaving.

Purification Methods

Dissolve D(-)-fructose in an equal weight of water (charcoal, previously washed with water to remove any soluble material), filter and evaporate under reduced pressure at 45-50o to give a syrup containing 90% of fructose. After cooling to 40o, the syrup is seeded and kept at this temperature for 20-30hours with occasional stirring. The crystals are removed by centrifugation, washed with a small quantity of water and dried to constant weight under a vacuum over conc H2SO4. For higher purity, this material is recrystallised from 50% aqueous ethanol [Tsuzuki et al. J Am Chem Soc 72 1071 1950]. [Beilstein 31 H 321, 1 IV 4401.]

비 호환성

Incompatible with strong acids or alkalis, forming a brown coloration. In the aldehyde form, fructose can react with amines, amino acids, peptides, and proteins. Fructose may cause browning of tablets containing amines.

Regulatory Status

Included in the FDA Inactive Ingredients Database (oral solutions, syrup, and suspensions; rectal preparations; intravenous infusions). Included in the Canadian List of Acceptable Non-medicinal Ingredients.

D(-)-과당 준비 용품 및 원자재

원자재

준비 용품


D(-)-과당 공급 업체

글로벌( 616)공급 업체
공급자 전화 이메일 국가 제품 수 이점
Hebei Mojin Biotechnology Co., Ltd
+8613288715578
sales@hbmojin.com China 12452 58
Hebei Guanlang Biotechnology Co,.LTD
+8619930503252
daisy@crovellbio.com China 5964 58
Shaanxi TNJONE Pharmaceutical Co., Ltd
+86-13474506593 +86-13474506593
sarah@tnjone.com China 713 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763
info@tnjchem.com China 2989 55
Shanghai Zheyan Biotech Co., Ltd.
18017610038
zheyansh@163.com CHINA 3620 58
career henan chemical co
+86-0371-86658258
sales@coreychem.com China 29914 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282
alice@crovellbio.com China 8822 58
Xiamen AmoyChem Co., Ltd
+86-592-6051114 +8618959220845
sales@amoychem.com China 6387 58
Xi'an Kono chem co., Ltd.,
029-86107037 13289246953
info@konochemical.com China 2995 58
Hubei xin bonus chemical co. LTD
86-13657291602
linda@hubeijusheng.com CHINA 22968 58

D(-)-과당 관련 검색:

Copyright 2019 © ChemicalBook. All rights reserved