헵타클로르 에폭시드

헵타클로르 에폭시드
헵타클로르 에폭시드 구조식 이미지
카스 번호:
1024-57-3
한글명:
헵타클로르 에폭시드
동의어(한글):
헵타클로르에폭사이드;헵타클로르에폭시드;헵타클로르에폭사이드;헵타클로르-에폭사이드
상품명:
CIS-HEPTACHLOREPOXIDE EXO-, ISOMER B
동의어(영문):
HEPTACHLOROEPOXIDE;HCE;HEPTACHLOR-EXO-EPOXIDE;HEPTACHLOR-ENDO-EPOXIDE;beta-Heptachlorepoxide;TRANS-HEPTACHLOR EPOXIDE;TRANS-HEPTACHLOR-ENDO-EPOXIDE;Heptachlor-exo-epoxide (cis-, isomer B);Heptachlor epoxide (Isomer B) 50mg [1024-57-3];CAP1A
CBNumber:
CB6250742
분자식:
C10H5Cl7O
포뮬러 무게:
389.32
MOL 파일:
1024-57-3.mol
MSDS 파일:
SDS

헵타클로르 에폭시드 속성

녹는점
160-161.5℃
끓는 점
503.92°C (rough estimate)
밀도
1.7335 (rough estimate)
증기압
2.6(x 10-6 mmHg) at 20 °C (IARC, 1974)300(x 10-6 mmHg) at 30 °C (Nash, 1983)
굴절률
1.5000 (estimate)
인화점
11 °C
저장 조건
APPROX 4°C
용해도
클로로포름(약간 용해됨), 에틸아세테이트(약간 용해됨), 메탄올(약간 용해됨)
용해도
클로로포름(약간), 에틸아세테이트(약간), 메탄올(약간)에 용해됨
수용성
(μg/L):
350 at 25–29 °C (Park and Bruce, 1968)
275 at 25 °C (quoted, Warner et al., 1987)
Henry's Law Constant
0.59(x 10-5 atm?m3/mol) at 5 °C, 0.84 at 15 °C, 1.48 at 20 °C, 2.27 at 25 °C, 3.26 at 35 °C:in 3% NaCl solution: 2.07 at 5 °C, 4.93 at 15 °C, 7.70 at 25 °C, 9.28 at 35 °C (gas stripping-GC, Cetin et al., 2006)
노출 한도
ACGIH TLV: TWA 0.05 mg/m3 (adopted).
안정성
감광성
EPA
Heptachlor epoxide (1024-57-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T,N,F
위험 카페고리 넘버 25-33-40-50/53-39/23/24/25-23/24/25-11-52/53
안전지침서 36/37-45-60-61-16-7
유엔번호(UN No.) 2761
WGK 독일 3
RTECS 번호 PB9450000
위험 등급 6.1(a)
포장분류 II
유해 물질 데이터 1024-57-3(Hazardous Substances Data)
독성 Acute oral LD50 for rats 47 mg/kg (RTECS, 1985)
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H300 삼키면 치명적임 급성 독성 물질 - 경구 구분 1,2 위험 GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H351 암을 일으킬 것으로 의심됨 (노출되어도 암을 일으키지 않는다는 결정적인 증거가 있는 노출경로가 있다면 노출경로 기재) 발암성 물질 구분 2 경고 P201, P202, P281, P308+P313, P405,P501
H373 장기간 또는 반복 노출되면 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킬 수 있음 특정 표적장기 독성 - 반복 노출 구분 2 경고 P260, P314, P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P202 모든 안전 조치 문구를 읽고 이해하기 전에는 취급하지 마시오.
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P270 이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P273 환경으로 배출하지 마시오.
P301+P310 삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.

헵타클로르 에폭시드 C화학적 특성, 용도, 생산

용도

The cis-metabolite of organochlorine pesticide Heptachlor.

정의

A degradation product of heptachlor that also acts as an insecticide.

일반 설명

Heptachlor epoxide is also a white powder. Bacteria and animals break down heptachlor to form heptachlor epoxide. The epoxide is more likely to be found in the environment than heptachlor. Heptachlor epoxide is a degradation product of heptachlor that occurs in soil and in or on crops when treatments with heptachlor, an insecticide, have been made. It forms readily upon exposing heptachlor to air. The U.S. EPA lists heptachlor epoxide as a possible human carcinogen.

반응 프로필

CIS-HEPTACHLOREPOXIDE EXO-, ISOMER B may react with acids, bases, and oxidizing and reducing agents.

위험도

Possible carcinogen.

건강위험

ACUTE/CHRONIC HAZARDS: Toxic.

화재위험

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Containers may explode when heated. Runoff may pollute waterways.

Safety Profile

Confirmed carcinogen with experimental carcinogenic data. Poison by ingestion and intravenous routes. Human mutation data reported. When heated to decomposition it emits toxic fumes of Cl-. See also HEITACHLOR

환경귀착

Biological. In a model ecosystem containing plankton, Daphnia magna, mosquito larva (Culex pipiens quinquefasciatus), ?sh (Cambusia af?nis), alga (Oedogonium cardiacum) and snail (Physa sp.), heptachlor epoxide degraded to hydroxychlordene epoxide (Lu et al., 1975). Using settled domestic wastewater inoculum, heptachlor epoxide (5 and 10 mg/L) did not degrade after 28 days of incubation at 25°C (Tabak et al., 1981). This is consistent with the ?ndings of Bowman et al. (1965). They observed that under laboratory conditions, heptachlor epoxide did not show any evidence of degradation when incubated in a variety of soils maintained at 45°C for 8 days. The soils used in this experiment included Lakeland sand, Lynchburg loamy sand, Magnolia sandy loam, Magnolia sandy clay loam, Greenville sandy clay and Susquehanna sandy clay (Bowman et al., 1965). When heptachlor epoxide was incubated in a sandy loam soil at 28°C, however, 1hydroxychlordene formed at yields of 2.8, 5.8 and 12.0% after 4, 8 and 12 weeks, respectively (Miles et al., 1971).
Photolytic. Irradiation of heptachlor epoxide by a 450-W high-pressure mercury lamp gave two half-cage isomers, each containing a ketone functional group (Ivie et al., 1972). Benson et al. (1971) reported a degradation yield of 99% when an aceton
Graham et al. (1973) reported that when solid heptachlor epoxide was exposed to July sunshine for 23.2 days, 59.3% degradation was achieved. In powdered form, however, only 5 days were required for complete degradation to occur.
Chemical/Physical. Heptachlor epoxide will hydrolyze via nucleophilic attack at the epoxide moiety forming heptachlor diol which may undergo further hydrolysis forming heptachlor triol and hydrogen chloride (Kollig, 1993).

헵타클로르 에폭시드 준비 용품 및 원자재

원자재

준비 용품


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