구리 프탈로시아닌

구리 프탈로시아닌
구리 프탈로시아닌 구조식 이미지
카스 번호:
147-14-8
한글명:
구리 프탈로시아닌
동의어(한글):
구리프탈로시아닌;구리프탈로시아닌;청색404호;(29H,31H-프탈로시아니네이토(2-)-N29,N30,N31,N32)쿠퍼(안료청색15호;CI74160);(29H,31H-프탈로시아니네이토(2-)-N29,N30,N31,N32)쿠퍼(안료청색15호;CI74160),염모제로사용될때;BT 4651;C.I. 74160;C.I. 피그먼트 블루 15;EM 블루 NCB;구리 베타-프탈로시아닌;구리 테트라벤조포르피라진;구리 프탈로시아닌;구리 프탈로시아닌 블루;구리(+2) 프탈로시아닌;구리(II) 프탈로 시아닌;구리, (29H,31H-프탈로시아니나토(2-)-N29,N30,N31,N32)-, (SP-4-1)-;그라프톨 블루 BL;다이니치 시안 블루 B;달토리트 페스트 블루 B;듀라틴트 블루 1001
상품명:
Copper(II) phthalocyanine
동의어(영문):
CUPC;PIGMENT BLUE 15;PHTHALOCYANINE BLUE;COPPER PHTHALOCYANINE;CI 74160;COPPER(II) PHTHALOCYANINE;cyanine blue;C.I. Pigment Blue 15:1;C.I. Pigment Blue 15:3;Monastral blue
CBNumber:
CB6255035
분자식:
C32H16CuN8
포뮬러 무게:
576.07
MOL 파일:
147-14-8.mol
MSDS 파일:
SDS

구리 프탈로시아닌 속성

녹는점
600°C (dec.)
밀도
1.62[at 20℃]
저장 조건
Inert atmosphere,Room Temperature
용해도
insoluble in H2O, ethanol; soluble in concHSO 4
색상 색인 번호
74160
물리적 상태
미세 결정성 분말
색상
진한 파란색
냄새
냄새 없는
수용성
20°C에서 <0.1g/100mL
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
최대 파장(λmax)
602nm(CHCl3)(lit.)
Merck
14,2520
BRN
4121848
노출 한도
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
화장품 원료 기능
COLORANT
HAIR DYEING
InChIKey
XCJYREBRNVKWGJ-UHFFFAOYSA-N
SMILES
c1ccc2c(c1)C3=NC4=[N@@H]5C(=Nc6n7c(N=C8c9ccccc9C%10=[N@@H]8[Cu]57N3C2=N%10)c%11ccccc6%11)c%12ccccc4%12
LogP
-1 at 23℃
NIST
Copper phthalocyanine(147-14-8)
EPA
C.I. Pigment Blue 15 (147-14-8)
Absorption
λmax 678 nm (DMF)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
안전지침서 22-24/25
WGK 독일 -
RTECS 번호 GL8510000
TSCA TSCA listed
HS 번호 32041300
스토리지 클래스 11 - Combustible Solids
유해 물질 데이터 147-14-8(Hazardous Substances Data)
독성 LD50 intraperitoneal in rat: > 3gm/kg
기존화학 물질 KE-07857
KE-33250
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P304+P340 흡입하면 신선한 공기가 있는 곳으로 옮기고 호흡하기 쉬운 자세로 안정을 취하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
0
0 0

구리 프탈로시아닌 MSDS


(29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32)copper

구리 프탈로시아닌 C화학적 특성, 용도, 생산

개요

Copper(II) phthalocyanine, known as CuPc, has been used as an electron donor?with fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV).?Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer . CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device . Device stability was achieved by?depositing a copper phthalocyanine CuPc hole-injection layer?HIL on the ITO anode.

화학적 성질

dark blue fine crystalline powder

용도

Copper(II) phthalocyanine are involved in the study of photosensitizer chemistry for uniform polymerization, luminescence chemistry and spectrophotometric analysis, organic synthesis and polymerization. This pigment is used in enamels, linoleum, inks, plastics, and rubber goods. Photoisomerizable phthalocyanines are used in rewritable CD or DVD printing.Other applications in organic solar cells, biosensitizers and display devices such as OLED , OTFT, Wearable Display, and e-paper.

주요 응용

Copper(II) phthalocyanine, known as CuPc, has been used as an electron donor with fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV). Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer.
CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device. Device stability was achieved by depositing a copper phthalocyanine CuPc hole-injection layer HIL on the ITO anode. The improved stability could be contributed to the good match of its highest-occupied molecular orbital (HOMO) level to the work function of ITO, and the improved wetting property of organic materials on ITO. Moreover, CuPc has very weak absorption of light, with wavelengths from 400 to 500 nm, making it suitable for use in blue and green OLEDs.
Effective electron-blocking was also observed for inorganic&ndash;organic hybrid perovskite solar cells when CuPc-doped spiro-OMeTAD was used as the hole-transporting layer.

일반 설명

Copper(II) phthalocynaine (CuPc) is a metal phthalocyanine dye that acts as a p-type semiconductor. It has a charge mobility of 10-4 cm2/Vs. It forms a chemically stable thin film that exhibits photoconductivity and catalytic activity.

Purification Methods

Precipitate it twice from conc H2SO4 by slow dilution with water. It has also been purified by two or three sublimations at 580o in an argon flow at 300-400Pa. [Beilstein 26 III/IV 4256.]

구리 프탈로시아닌 준비 용품 및 원자재

원자재

준비 용품


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