구리 프탈로시아닌

구리 프탈로시아닌
구리 프탈로시아닌 구조식 이미지
카스 번호:
147-14-8
한글명:
구리 프탈로시아닌
동의어(한글):
구리프탈로시아닌;구리프탈로시아닌;청색404호;(29H,31H-프탈로시아니네이토(2-)-N29,N30,N31,N32)쿠퍼(안료청색15호;CI74160);(29H,31H-프탈로시아니네이토(2-)-N29,N30,N31,N32)쿠퍼(안료청색15호;CI74160),염모제로사용될때;BT 4651;C.I. 74160;C.I. 피그먼트 블루 15;EM 블루 NCB;구리 베타-프탈로시아닌;구리 테트라벤조포르피라진;구리 프탈로시아닌;구리 프탈로시아닌 블루;구리(+2) 프탈로시아닌;구리(II) 프탈로 시아닌;구리, (29H,31H-프탈로시아니나토(2-)-N29,N30,N31,N32)-, (SP-4-1)-;그라프톨 블루 BL;다이니치 시안 블루 B;달토리트 페스트 블루 B;듀라틴트 블루 1001
상품명:
Copper(II) phthalocyanine
동의어(영문):
CUPC;PIGMENT BLUE 15;PHTHALOCYANINE BLUE;COPPER PHTHALOCYANINE;CI 74160;COPPER(II) PHTHALOCYANINE;cyanine blue;C.I. Pigment Blue 15:1;C.I. Pigment Blue 15:3;Monastral blue
CBNumber:
CB6255035
분자식:
C32H16CuN8
포뮬러 무게:
576.07
MOL 파일:
147-14-8.mol
MSDS 파일:
SDS

구리 프탈로시아닌 속성

녹는점
600°C (dec.)
밀도
1.62[at 20℃]
저장 조건
Inert atmosphere,Room Temperature
용해도
insoluble in H2O, ethanol; soluble in concHSO 4
색상 색인 번호
74160
물리적 상태
미세 결정성 분말
색상
진한 파란색
냄새
냄새 없는
수용성
20°C에서 <0.1g/100mL
최대 파장(λmax)
602nm(CHCl3)(lit.)
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
Merck
14,2520
BRN
4121848
노출 한도
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
InChIKey
XCJYREBRNVKWGJ-UHFFFAOYSA-N
LogP
-1 at 23℃
NIST
Copper phthalocyanine(147-14-8)
EPA
C.I. Pigment Blue 15 (147-14-8)
Absorption
λmax 678 nm (DMF)
안전
  • 위험 및 안전 성명
안전지침서 22-24/25
WGK 독일 -
RTECS 번호 GL8510000
TSCA Yes
HS 번호 32041300
유해 물질 데이터 147-14-8(Hazardous Substances Data)
독성 LD50 intraperitoneal in rat: > 3gm/kg
기존화학 물질 KE-07857
KE-33250
그림문자(GHS):
신호 어:
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
예방조치문구:
NFPA 704
0
0 0

구리 프탈로시아닌 MSDS


(29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32)copper

구리 프탈로시아닌 C화학적 특성, 용도, 생산

개요

Copper(II) phthalocyanine, known as CuPc, has been used as an electron donor?with fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV).?Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer . CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device . Device stability was achieved by?depositing a copper phthalocyanine CuPc hole-injection layer?HIL on the ITO anode.

화학적 성질

dark blue fine crystalline powder

용도

Copper(II) phthalocyanine are involved in the study of photosensitizer chemistry for uniform polymerization, luminescence chemistry and spectrophotometric analysis, organic synthesis and polymerization. This pigment is used in enamels, linoleum, inks, plastics, and rubber goods. Photoisomerizable phthalocyanines are used in rewritable CD or DVD printing.Other applications in organic solar cells, biosensitizers and display devices such as OLED , OTFT, Wearable Display, and e-paper.

주요 응용

Copper(II) phthalocyanine, known as CuPc, has been used as an electron donor with fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV). Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer.
CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device. Device stability was achieved by depositing a copper phthalocyanine CuPc hole-injection layer HIL on the ITO anode. The improved stability could be contributed to the good match of its highest-occupied molecular orbital (HOMO) level to the work function of ITO, and the improved wetting property of organic materials on ITO. Moreover, CuPc has very weak absorption of light, with wavelengths from 400 to 500 nm, making it suitable for use in blue and green OLEDs.
Effective electron-blocking was also observed for inorganic&ndash;organic hybrid perovskite solar cells when CuPc-doped spiro-OMeTAD was used as the hole-transporting layer.

일반 설명

Copper(II) phthalocynaine (CuPc) is a metal phthalocyanine dye that acts as a p-type semiconductor. It has a charge mobility of 10-4 cm2/Vs. It forms a chemically stable thin film that exhibits photoconductivity and catalytic activity.

Purification Methods

Precipitate it twice from conc H2SO4 by slow dilution with water. It has also been purified by two or three sublimations at 580o in an argon flow at 300-400Pa. [Beilstein 26 III/IV 4256.]

구리 프탈로시아닌 준비 용품 및 원자재

원자재

준비 용품


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