2,5-Furandicarboxylic acid

2,5-Furandicarboxylic acid 구조식 이미지
카스 번호:
3238-40-2
상품명:
2,5-Furandicarboxylic acid
동의어(영문):
FURAN-2,5-DICARBOXYLIC ACID;2,5-furandicarboxylate;2,5-Furandicarboxylic;2,3-furandicarboxylic acid;2,5-Furandicarboxylic acid (FDCA);FDCA;NSC 40740;5-Furandic;5-Furandicar;DEHYDROMUCIC ACID
CBNumber:
CB6264091
분자식:
C6H4O5
포뮬러 무게:
156.09
MOL 파일:
3238-40-2.mol
MSDS 파일:
SDS

2,5-Furandicarboxylic acid 속성

녹는점
>300 °C
끓는 점
240.29°C (rough estimate)
밀도
1.7400
굴절률
1.6400 (estimate)
저장 조건
Keep in dark place,Sealed in dry,Room Temperature
용해도
DMSO(약간 용해됨), 메탄올(약간 용해됨 초음파 처리)
물리적 상태
고체
물리적 상태
단단한 모양
산도 계수 (pKa)
2.28±0.10(Predicted)
색상
흰색에서 진한 갈색까지
수용성
1g/L(18ºC)
안정성
감광성, 흡습성이 매우 높음
InChIKey
CHTHALBTIRVDBM-UHFFFAOYSA-N
LogP
-1.43 at 20℃
CAS 데이터베이스
3238-40-2(CAS DataBase Reference)
NIST
Furan-2,5-dicarboxylic acid(3238-40-2)
EPA
2,5-Furandicarboxylic acid (3238-40-2)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 36/37/38-36
안전지침서 26-36/37/39-36/37
WGK 독일 1
TSCA Yes
위험 등급 IRRITANT
HS 번호 29321900
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
예방조치문구:
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P337+P313 눈에 대한 자극이 지속되면 의학적인 조치· 조언를 구하시오.
NFPA 704
0
2 0

2,5-Furandicarboxylic acid C화학적 특성, 용도, 생산

개요

2,5-Furandicarboxylic acid (FDCA) is an organic chemical compound consisting of two carboxylic acid groups attached to a central furan ring. It was first reported as dehydromucic acid by Rudolph Fittig and Heinzelmann in 1876, who produced it via the action of concentrated hydrobromic acid upon mucic acid. It can be produced from certain carbohydrates and as such is a renewable resource, it was identified by the US Department of Energy as one of 12 priority chemicals for establishing the “green” chemistry industry of the future.Furan-2,5-dicarboxylic acid (FDCA) has been suggested as an important renewable building block because it can substitute for terephthalic acid (PTA) in the production of polyesters and other current polymers containing an aromatic moiety.
wikipedia

화학적 성질

2,5-Furandicarboxylic acid is a chemical intermediate with high sensitivity and good stability. It is soluble in water under alkaline conditions and is a white powder solid under acidic conditions, and is an important monomer for the preparation of corrosion-resistant plastics. It is irritating to eyes, respiratory tract and skin.

역사

2,5-Furandicarboxylic acid, also known as dehydromucic acid, is a furan derivative. This organic compound was first obtained by Fittig and Heinzelmann in 1876. More than 125 years later, FDCA was identified by the US Department of Energy as one of 12 priority chemicals for establishing the "green" chemistry industry of the future. On a laboratory scale, it is often synthesized from 5- hydroxymethylfurfural (HMF), which in turn can be obtained from carbohydrate-containing sources such as glucose, fructose, sucrose, and starch. From fructose and glucose, HMF is obtained by acidic eliminating three moles of water.

용도

Interest in renewable based polymers has led to 2,5-furandicarboxylic acid being proposed as a green, sustainable alternative to the widely used petroleum-based terephthalic acid in the synthesis of polyesters. 2,5-Furandicarboxylic acid is produced from oxidation of 5-hydroxymethylfurfural (HMF) which is obtained from the dehydration of bio-based sugars such as fructose.

제조 방법

2,5-Furandicarboxylic acid (FDCA) can be produced from biomass or its derived sugars or platform chemicals, and has demonstrated to be a very promising substitute for petroleum-derived polymer products.
Chapter 5 - Advances in the synthesis and application of 2,5-furandicarboxylic acid

정의

ChEBI: A member of the class of furans carrying two carboxy substituents at positions 2 and 5.

주요 응용

2,5-Furandicarboxylic acid (FDCA) is a renewable, greener substitute for terephthalate in the production of polyesters. It is widely used as a precursor for the synthesis of bio-based polyesters and various other polymers.
Applications of FDCA in the synthesis of several metal-organic frameworks (MOFs) have also been reported.

2,5-Furandicarboxylic acid 준비 용품 및 원자재

원자재

준비 용품


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