트리스(4-플루오로페닐)포스핀
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트리스(4-플루오로페닐)포스핀 속성
- 녹는점
- 79-83 °C(lit.)
- 끓는 점
- 160°C/0.1mmHg(lit.)
- 저장 조건
- Inert atmosphere,Room Temperature
- 물리적 상태
- 결정성 분말
- 색상
- 흰색에서 아주 약간 노란색
- 수용성
- 물에 불용성.
- 감도
- Air Sensitive
- BRN
- 919838
- InChI
- InChI=1S/C18H12F3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H
- InChIKey
- GEPJPYNDFSOARB-UHFFFAOYSA-N
- SMILES
- P(C1=CC=C(F)C=C1)(C1=CC=C(F)C=C1)C1=CC=C(F)C=C1
- CAS 데이터베이스
- 18437-78-0(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
트리스(4-플루오로페닐)포스핀 C화학적 특성, 용도, 생산
화학적 성질
white to light yellow crystal powde용도
Tris(4-fluorophenyl)phosphine (TFPP) and tris(2,2,2- trifluoroethyl) phosphite (TTFP) were used as flame-retarding additives in Li-ion battery clectrolytes.Ligand for rhodium-catalyzed oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.
제조 방법
with 4-bromofluorobenzene, magnesium, and phosphorous (III) trichloride.3 Alternatively, reduction of tris(4-fluorophenyl)phosphine oxide with an iron catalyst.일반 설명
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.Synthesis
Tris (4-fluorophenyl)phosphine oxide could be used as a starting material to synthesize Tris(4-fluorophenyl)phosphine. Into the reactor were added 0.2 mmol of tris(4-fluorophenyl)phosphine oxide, 0.36 mmol of trifluoroacetic anhydride, and 1 ml of dioxane as a solvent. Stir at room temperature under a nitrogen atmosphere for 30 min; after the reaction, continue adding 0.2 mmol of sodium bicarbonate, 0.24 mmol of 15-Crown-5, and 1.2 mmol of sodium hydride under a nitrogen environment. Under 150 ℃, stir for 24 hours, stop the reaction, cool to room temperature, and distilled under reduced pressure to remove the solvent. The crude product is separated by column chromatography to obtain Tris(4-fluorophenyl)phosphine with a yield of 74%.
트리스(4-플루오로페닐)포스핀 준비 용품 및 원자재
원자재
준비 용품
트리스(4-플루오로페닐)포스핀 공급 업체
글로벌( 199)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
info@dakenam.com | China | 15371 | 58 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 |
fandachem@gmail.com | China | 9350 | 55 |
| career henan chemical co | +86-0371-86658258 |
sales@coreychem.com | China | 29914 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28180 | 58 |
| Accela ChemBio Inc. | (+1)-858-699-3322 |
info@accelachem.com | United States | 19965 | 58 |
| Wuhan Pengo Technology.,Ltd. | +86-27-81330736 +86-13628634921 |
sunny.w@boronicgroup.com | CHINA | 171 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 |
sales@chemdad.com | China | 39916 | 58 |
| Wuhan Chemwish Technology Co., Ltd | 027-67849912 |
sales@chemwish.com | CHINA | 10828 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 47465 | 58 |
트리스(4-플루오로페닐)포스핀 관련 검색:
트리스(4-플루오로페닐)포스핀 트리스(펜타플루오로페닐)포스핀
TRIS(3-FLUOROPHENYL)PHOSPHINE,Tris(3-fluorophenyl)phosphine 98%,Tris(3-fluorophenyl)phosphine98%
TRIS(4-CHLOROPHENYL)PHOSPHINE
Tris(2-carboxyethyl)phosphine hydrochloride
TRIS(NONYLPHENYL) PHOSPHITE
TRIS(3-CHLOROPHENYL)PHOSPHINE
Tris(4-methoxyphenyl)phosphine
TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE
TRIS(2-METHOXYPHENYL)PHOSPHINE
DIPHENYL(O-TOLYL)PHOSPHINE
tris(2-fluorophenyl)phosphane
Tris(3-methoxyphenyl)phosphine
TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE
TRIS(2,4-DIMETHYLPHENYL)PHOSPHINE
Tris(4-bromophenyl)amine
Tris(4-isocyanatophenyl) thiophosphate
TRIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE