트리에틸렌 글리콜 디메틸 에테르

트리에틸렌 글리콜 디메틸 에테르
트리에틸렌 글리콜 디메틸 에테르 구조식 이미지
카스 번호:
112-49-2
한글명:
트리에틸렌 글리콜 디메틸 에테르
동의어(한글):
1,2-비스(메톡시에톡시)에탄;트리에틸렌글리콜다이메틸에테르;트리에틸렌글리콜디메틸에테르;트리에틸렌글리콜다이메틸에테르;1,2-비스(2-메톡시에톡시)에탄;1,2-비스(2-메톡시에톡시)에탄;트리에칠렌글리콜디메칠에텔(TEGDME);트리글라임;트라이글라임;트라이에틸렌글라이콜다이메틸에터;티이지디엠이
상품명:
Triethylene glycol dimethyl ether
동의어(영문):
TRIGLYME;2,5,8,11-TETRAOXADODECANE;1,2-BIS(2-METHOXYETHOXY)ETHANE;DIMETHYLTRIGLYCOL;glyme4;Glyme-3;riglyme;ansulether161;dimethyltrigol;methyltriglyme
CBNumber:
CB6326946
분자식:
C8H18O4
포뮬러 무게:
178.23
MOL 파일:
112-49-2.mol
MSDS 파일:
SDS

트리에틸렌 글리콜 디메틸 에테르 속성

녹는점
−45 °C(lit.)
끓는 점
216 °C(lit.)
밀도
0.986 g/mL at 25 °C(lit.)
증기 밀도
>4.7 (vs air)
증기압
1.2 hPa (20 °C)
굴절률
n20/D 1.423(lit.)
인화점
231 °F
저장 조건
Store below +30°C.
용해도
>1000g/l 가용성
물리적 상태
액체
색상
APHA: ≤20
폭발한계
0.7%(V)
수용성
녹는
감도
Hygroscopic
Merck
14,9692
BRN
1700630
Dielectric constant
7.5
InChIKey
YFNKIDBQEZZDLK-UHFFFAOYSA-N
LogP
-0.52 at 20℃
CAS 데이터베이스
112-49-2(CAS DataBase Reference)
NIST
2,5,8,11-Tetraoxadodecane(112-49-2)
EPA
Triethylene glycol dimethyl ether (112-49-2)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T
위험 카페고리 넘버 61-19-62
안전지침서 53-45
WGK 독일 1
RTECS 번호 XF0665000
F 고인화성물질 3
자연 발화 온도 375 °F
TSCA Yes
HS 번호 29094990
독성 LD50 orally in Rabbit: 5390 mg/kg
기존화학 물질 KE-33642
중점관리물질 필터링 별표1-66
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
예방조치문구:
P202 모든 안전 조치 문구를 읽고 이해하기 전에는 취급하지 마시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P308+P313 노출 또는 접촉이 우려되면 의학적인 조치· 조언를 구하시오.
P337+P313 눈에 대한 자극이 지속되면 의학적인 조치· 조언를 구하시오.
NFPA 704
1
1 0

트리에틸렌 글리콜 디메틸 에테르 C화학적 특성, 용도, 생산

화학적 성질

Water-white liquid; mild ether odor. D 0.9862 (20/20C), refr index 1.4233 (20C), flash p 232F (111C), bp 216.0C (760mmHg), 153.6C (100 mm Hg), fp ?46C. Completely soluble in water and hydrocarbons at 20C. May contain peroxides. Combustible.

용도

Triethylene glycol dimethyl ether is used as a solvent for gases and coupling immiscible liquid. It is also used to prepare perfluoro-triethyleneglycoldimethylether.

정의

ChEBI: A polyether that consists of dodecane in which the carbon atoms at positions 2, 5, 8 and 11 are replaced by oxygen atoms.

반응 프로필

TRIETHYLENE GLYCOL DIMETHYL ETHER forms explosive peroxides on prolonged exposure to air. Its decomposition products may be sensitive to shock. The bulk chemical is stable for 2 weeks at temperatures up to 140° F when protected from light. TRIETHYLENE GLYCOL DIMETHYL ETHER is incompatible with strong oxidizers. TRIETHYLENE GLYCOL DIMETHYL ETHER is also incompatible with strong acids. TRIETHYLENE GLYCOL DIMETHYL ETHER may react with peroxides, oxygen, nitric acid and sulfuric acid. .

Toxicology

Triethylene glycol dimethyl ether (triEGdiME) is a widely used organic solvent. It is structurally related to several compounds that produce reproductive and developmental toxicity, including teratogenicity in laboratory animals. In the present studies, triEGdiME (0, 75, 125, 175, or 250 mg/kg/day) is administered by gavage in distilled water to timed-pregnant New Zealand white rabbits (15-25 dams/group) during major organogenesis [Gestational Days (gd) 6-19]. In the triEGdiME study, clinical signs of toxicity were minimal, and there was no increased maternal mortality. Maternal body weight and gravid uterine weight were significantly reduced at 250 mg/kg/day, whereas maternal weight gain during treatment was significant. They were depressed at doses of 175 mg/kg/day and above. Prenatal mortality was significantly increased at 250 mg triEGdiME/kg/day. TriEGdiME at doses of 175 and 250 mg/kg/day caused a significant increase in the incidence of malformed fetuses per litter. Malformations noted most frequently in fetuses of normal size included anonychia (missing toenails with no digital abnormalities), abnormally small spleen, and hydronephrosis[1].

Purification Methods

Reflux it with, and distil it from sodium hydride or LiAlH4. [Beilstein 1 IV 2401.]

트리에틸렌 글리콜 디메틸 에테르 준비 용품 및 원자재

원자재

준비 용품


트리에틸렌 글리콜 디메틸 에테르 공급 업체

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