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Copper(I) bromide-dimethyl sulfide

Copper(I) bromide-dimethyl sulfide 구조식 이미지
카스 번호:
54678-23-8
상품명:
Copper(I) bromide-dimethyl sulfide
동의어(영문):
Copper, bromothiobismethane-;bromo[thiobis[methane]]copper;COPPER BROMIDE-DIMETHYL SULFIDE;BROMO(DIMETHYLSULFIDE)COPPER(I);COPPER(I) BROMIDE DIMETHYL SULFIDE;CUPROUS BROMIDE METHYLSULFIDE COMPLEX;COPPERBROMIDE-DIMETHYL SULFIDE COMPLEX;Copper(I) bromide methylsulfide complex;Cuprous bromide dimethyl sulfide complex;COPPER(I) BROMIDE-DIMETHYL SULFIDE COMPLEX
CBNumber:
CB6332325
분자식:
C2H6BrCuS
포뮬러 무게:
205.58
MOL 파일:
54678-23-8.mol

Copper(I) bromide-dimethyl sulfide 속성

녹는점
132 °C (dec.)(lit.)
물리적 상태
Crystalline Powder and/or Chunks
색상
Pale brown or pale green
수용성
Soluble in water. Reacts with water and decomposes.
감도
Moisture Sensitive/Air Sensitive
BRN
4386581
CAS 데이터베이스
54678-23-8(CAS DataBase Reference)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 36/37/38
안전지침서 26-36-24/25
유엔번호(UN No.) 1759
WGK 독일 3
F 고인화성물질 10-13-21
위험 등급 8
포장분류 III
HS 번호 29309090
그림문자(GHS):
신호 어:
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 P264, P280, P305+P351+P338,P337+P313P
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고
예방조치문구:
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.

Copper(I) bromide-dimethyl sulfide MSDS


Copper(I) bromide-dimethyl sulfide

Copper(I) bromide-dimethyl sulfide C화학적 특성, 용도, 생산

화학적 성질

off-white to beige, grey or green crystalline

용도

Copper(I) bromide-dimethyl sulfide can be used as catalyst for adding Grignard reagents to fullerenes.

Purification Methods

Purify it by recrystallisation in the presence of Me2S. A solution of the complex (1.02g) in Me2S (5mL) is slowly diluted with hexane (20mL), and the pure colourless prisms of the complex (0.96g) separate and are collected and dried, m 124-129o(dec). The complex is insoluble in hexane, Et2O, Me2CO, CHCl3 and CCl4. It dissolves in DMF and DMSO, but the solution becomes hot and green indicating decomposition. It dissolves in *C6H6, Et2O, MeOH and CHCl3 if excess of Me2S is added and a colourless solution is obtained. [House et al. J Org Chem 40 1460 1975.] Prior to use, the complex is dissolved in Me2S and evaporated to dryness in the weighed reaction flask [Bourgain-Commer.on et al. J Organomet Chem 228 321 1983].

Copper(I) bromide-dimethyl sulfide 준비 용품 및 원자재

원자재

준비 용품


Copper(I) bromide-dimethyl sulfide 공급 업체

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