Iodosobenzene
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Iodosobenzene 속성
- 녹는점
- 210°C (rough estimate)
- 밀도
- 1.8665 (estimate)
- 저장 조건
- Freezer
- 수용성
- 물에 약간 용해됨
- 용해도
- 메탄올(약간), TFA(약간)에 용해됨
- 물리적 상태
- powder to crystal
- 색상
- White to Yellow to Green
- Merck
- 14,5044
- InChIKey
- JYJVVHFRSFVEJM-UHFFFAOYSA-N
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
안전지침서 | 17-36/37/39 | ||
---|---|---|---|
유엔번호(UN No.) | 1479 | ||
RTECS 번호 | DA3500000 | ||
위험 등급 | 4.1 | ||
포장분류 | II | ||
HS 번호 | 29039990 |
Iodosobenzene C화학적 특성, 용도, 생산
화학적 성질
Iodosobenzene is an amorphous yellow substance; it explodes at 210℃, decomposing with the evolution of iodine vapour, and dissolves in hot water and alcohol. If acids do not oxidise C6H5IO, they give saline compounds in which iodosobenzene appears as a basic oxide of a diatomic metal, C6H5I. Thus, for instance, when an acetic acid solution of iodosobenzene is treated with a solution of nitric acid, it gives large monoclinic crystals of a nitric acid salt having the composition C6H5(NO3)2 [like Ca(NO3)2). Iodosobenzene displaces iodine from potassium iodide (in a solution acidulated with acetic or hydrochloric acid)-ie, it acts with its oxygen like HClO. The action of peroxide of hydrogen, chromic acid, and other similar oxidising agents gives C6H5IO2, which is a neutral substance-i.e, is incapable of giving salts with acids.Iodosobenzene is one of the very first oxidants and remains in use because it has excellent oxygen-transfer behavior and mechanistic cleanliness (Hill & Schardt, 1980; Rezaeifard et al., 2007; Po?towicz et al., 2006).
The Principles of Chemistry Volume 1
용도
Oxygen transfer reagent for stiochiometric or catalytic cross-functionalization of alkenes, alcohols, sulfides, and organometallo Compounds.Iodosobenzene is used as an oxidizing and acetoxylating agent in organic synthesis. It is actively involved in the preparation of (Z)-3,7-dimethyl-2,6-octadien-1-al(neral) from (Z)-3,7-dimethyl-2,6-octadien-1-ol (nerol) in presence of 2,2,6,6-tetramethylpiperidin-1-oxyl (TEMPO). It is a useful reagent for the synthesis of a wide variety of heterocyclic compounds. It is also used in the Pd-catalyzed 2-arylation of indoles.
Synthesis
Iodosobenzene has been prepared by the action of sodium or potassium hydroxide solution on iodobenzene dichloride and by addition of water to the dichloride.Iodosobenzene is prepared from iodobenzene.It is prepared by first oxidizing iodobenzene by peracetic acid. Hydrolysis of resulting diacetate affords "PhIO":
C6H5I + CH3CO3H + CH3CO2H → C6H5I(O2CCH3)2 + H2O
C6H5I(O2CCH3)2 + H2O → C6H5IO + 2CH3CO2H
http://orgsyn.org
Iodosobenzene 준비 용품 및 원자재
원자재
준비 용품
Iodosobenzene 공급 업체
글로벌( 114)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21695 | 55 |
Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22968 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 47465 | 58 |
career henan chemical co | +86-0371-86658258 15093356674; |
factory@coreychem.com | China | 29826 | 58 |
Shaanxi Dideu Medichem Co. Ltd | +86-029-81148696 +8615536356810 |
1047@dideu.com | China | 3527 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 |
sales@tnjchem.com | China | 34572 | 58 |
Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 |
1026@dideu.com | China | 9409 | 58 |
Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 |
info@dycnchem.com | CHINA | 52867 | 58 |
sgtlifesciences pvt ltd | +8617013299288 |
dj@sgtlifesciences.com | China | 12382 | 58 |
Nanjing Doge Biomedical Technology Co., Ltd | +86-25-58227606 +86-15305155328 |
sales@dogechemical.com | China | 4128 | 58 |
Iodosobenzene 관련 검색:
2,5-시클로헥사디엔-1,4-디온 1-브로모벤젠 DDT (디디티) 아이오도벤젠 2-아이오도소벤조산
Nitrobenzene
2',3'-Dideoxythymidine
1-BUTENE
[Hydroxy(tosyloxy)iodo]benzene
IODOSOBENZENE I,I-BIS(TRIFLUOROACETATE),Iodosobenzene-bis(trifluoroacetate)
IODOSOBENZENE DIACETATE,IODOSOBENZENE I,I-DIACETATE,Iodobenzene I,I-diacetate, Iodosobenzene I,I-diacetate
Iodosobenzene
2-Iodoxybenzoic acid
1-HYDROXY-1,3-DIOXO-1,3-DIHYDRO-1L5-BENZO[D][1,2]IODOXOLE-4-CARBOXYLIC ACID
Iodoxybenzene
O-IODOSOBENZOIC ACID, SODIUM SALT
IODOSOBENZENE DIACETATE, [(DIACETOXYIODO)BENZENE; PHENYLIODOSODIACETATE)
BENZOIC ACID, 2-IODYL, 1-METHYLETHYL ESTER