테트라히드로푸르푸릴 알코올

테트라히드로푸르푸릴 알코올
테트라히드로푸르푸릴 알코올 구조식 이미지
카스 번호:
97-99-4
한글명:
테트라히드로푸르푸릴 알코올
동의어(한글):
테트라히드로푸르푸릴알코올;테트라히드로푸르푸릴알코올;테트라하이드로퍼퓨릴알코올
상품명:
Tetrahydrofurfuryl alcohol
동의어(영문):
THFA;Tetrahydrofurfuryl;TETRAHYDRO-2-FURANMETHANOL;Oxolane-2-methanol;2-Hydroxymethyl oxolane;Tetrahydrofuran methanol;Tetrahydro-2-furylmethanol;Tetrahydrofurfruyl Alcohol;(tetrahydro-furan-2-yl)-methanol;qothfa
CBNumber:
CB6414751
분자식:
C5H10O2
포뮬러 무게:
102.13
MOL 파일:
97-99-4.mol
MSDS 파일:
SDS

테트라히드로푸르푸릴 알코올 속성

녹는점
-80 °C (lit.)
끓는 점
178 °C (lit.)
밀도
1.054 g/mL at 25 °C (lit.)
증기 밀도
3.52 (vs air)
증기압
2.3 mm Hg ( 39 °C)
굴절률
n20/D 1.452(lit.)
FEMA
3056 | TETRAHYDROFURFURYL ALCOHOL
인화점
183 °F
저장 조건
Store below +30°C.
용해도
아세톤: 혼화성(lit.)
물리적 상태
액체
산도 계수 (pKa)
14.44±0.10(Predicted)
색상
투명한
냄새
100.00%에서. 야채 콜리플라워 희미한 따뜻한 기름진 카라멜
?? ??
채소
폭발한계
1.5-9.7%(V)
수용성
녹는
감도
Hygroscopic
Merck
14,9213
JECFA Number
1443
BRN
102723
Dielectric constant
13.48
InChIKey
BSYVTEYKTMYBMK-UHFFFAOYSA-N
LogP
-0.14 at 24.7℃
CAS 데이터베이스
97-99-4(CAS DataBase Reference)
NIST
2-Furanmethanol, tetrahydro-(97-99-4)
EPA
Tetrahydrofurfuryl alcohol (97-99-4)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi,T
위험 카페고리 넘버 36-62-61
안전지침서 39-36/37/39
유엔번호(UN No.) NA 1993 / PGIII
WGK 독일 2
RTECS 번호 LU2450000
자연 발화 온도 282 °C
TSCA Yes
HS 번호 29321300
유해 물질 데이터 97-99-4(Hazardous Substances Data)
독성 LD50 orally in Rabbit: 1600 mg/kg
기존화학 물질 KE-33456
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
예방조치문구:
P201 사용 전 취급 설명서를 확보하시오.
P202 모든 안전 조치 문구를 읽고 이해하기 전에는 취급하지 마시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P308+P313 노출 또는 접촉이 우려되면 의학적인 조치· 조언를 구하시오.
NFPA 704
2
2 0

테트라히드로푸르푸릴 알코올 MSDS


THFA

테트라히드로푸르푸릴 알코올 C화학적 특성, 용도, 생산

용도

1) 사용하실 수 있습니다 아 furan 수 지, furfuryl 알코올 수 지와 페 놀의 모든 종류의 물질 수 지, tetrahydrofurfuryl 알코올, 부식 방지 코팅, 등.
2) THFA는 소멸 및 염료의 좋은 솔루션에 사용할 수 있습니다.
3) THFA Sythetic febric, 고무, 농약 사용 수 있다
4) THFA는 열 코어 슈팅 상자 정밀 주조 업계에서의 모래 코어의 모래 코어의 바인더로 사용을 수도 있습니다.
5) 용 제, 희석제 또는 다른 유기 원료도 사용 됩니다.

포장, 보관 및 운송

멋진, 통풍이 잘되는 지역에서 컨테이너를 유지.
긴밀 하 게 폐쇄 하 고 사용 하기 위해 준비까지 밀봉 컨테이너를 유지 합니다.
점화 (스파크 또는 불꽃)의 모든 가능한 소스를 피하십시오.

화학적 성질

Tetrahydrofurfuryl alcohol is a colorless to light yellow hygroscopic liquid that has a faint, warm, oily, caramellic odor with a coffee and nut-like flavor at very low levels (0.03 to 1 ppm). Miscible with water, ethanol, ether, acetone, chloroform and benzene, insoluble in paraffin hydrocarbons. It has an extensive history of use as a highly versatile, high purity solvent.

출처

Reported found in shoyu (fermented soya hydrolysate), coffee and fresh mango.

용도

Tetrahydrofurfuryl alcohol is used extensively in various industries as a high-purity, water miscible solvent, and as a chemical intermediate. It was used as Solvent for vinyl resins; dyes for leather; chlorinated rubber; cellulose esters; solvent softener for nylon; vegetable oils; coupling agent; organic synthesis.

주요 응용

Tetrahydrofurfuryl alcohol (THFA) is generally regarded as a "green" solvent in industrial applications. THFA is a low cost, biodegradable solvent mainly used as a reactive diluent for epoxy resins and is a good solvent for many of the curative and catalysts used in epoxy formulations. It is also used in the following applications:
Tetrahydrofurfuryl alcohol undergoes chemoselective hydrogenolysis catalyzed by Rh/SiO2 modified with ReOx species to yield 1,5-pentanediol. It undergoes lanthanum-mediated Michael-type addition reaction with maleate to form alkoxybutanedioic acid.
Tetrahydrofurfuryl alcohol was used as refractive-index matching solvent to ensure hard sphere suspension of silica particles for rheological measurements.
Tetrahydrofurfuryl alcohol may be used as an analytical reference standard for the quantification of the analyte in rats and smoke flavoring from rice husk using chromatography techniques.

제조 방법

Tetrahydrofurfuryl alcohol is produced by catalytic reduction of furfural with Raney-Ni; also by destructive hydrogenation of lignin.

정의

ChEBI: Tetrahydrofurfuryl alcohol is a primary alcohol that is methanol in which one of the hydrogens of the methyl group has been replaced by a tetrahydrofuran-2-yl group. It has a role as a protic solvent. It is a primary alcohol and a member of oxolanes.

일반 설명

Tetrahydrofurfuryl alcohol appears as a clear colorless liquid with a mild odor. Vapors are heavier than air.

공기와 물의 반응

Denser than water and soluble in water.

반응 프로필

Acetyl bromide reacts violently with alcohols or water [Merck 11th ed. 1989]. Mixtures of alcohols with concentrated sulfuric acid and strong hydrogen peroxide can cause explosions. Example: An explosion will occur if dimethylbenzylcarbinol is added to 90% hydrogen peroxide then acidified with concentrated sulfuric acid. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. Mixtures of hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid [Chem. Eng. News 45(43):73. 1967; J, Org. Chem. 28:1893. 1963]. Alkyl hypochlorites are violently explosive. They are readily obtained by reacting hypochlorous acid and alcohols either in aqueous solution or mixed aqueous- carbon tetrachloride solutions. Chlorine plus alcohols would similarly yield alkyl hypochlorites. They decompose in the cold and explode on exposure to sunlight or heat. Tertiary hypochlorites are less unstable than secondary or primary hypochlorites [NFPA 491 M 1991]. Base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. Such reactions in the absence of solvents often occur with explosive violence [Wischmeyer 1969].

건강위험

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Carcinogenicity

Tetrahydro-2-furanmethanol was not mutagenic to S. typhimurium strains TA100, TA1535, TA1537, or TA98 in an in vitro gene mutation assay or to E. coliWP2uvrA/pKM101 with or withoutmetabolic activation. No chromosomal aberrations or polypoidy were observed when tetrahydro-2-furanmethanol was added to cultured Chinese hamster lung cells with or without metabolic activation .

테트라히드로푸르푸릴 알코올 준비 용품 및 원자재

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