아이소펠레티에린;1-(2-피페리디닐)-2-프로판온

아이소펠레티에린;1-(2-피페리디닐)-2-프로판온
아이소펠레티에린;1-(2-피페리디닐)-2-프로판온 구조식 이미지
카스 번호:
4396-01-4
한글명:
아이소펠레티에린;1-(2-피페리디닐)-2-프로판온
동의어(한글):
아이소펠레티에린;1-(2-피페리디닐)-2-프로판온
상품명:
pelletierine
동의어(영문):
pelletierine;isopelletierine;1-piperidin-2-ylacetone;1-(2-Piperidinyl)acetone;2-(2-Oxopropyl)piperidine;1-(2-Piperidyl)-2-propanone;1-piperidin-2-ylpropan-2-one;1-(2-Piperidinyl)-2-propanone;2-Propanone, 1-(2-piperidinyl)-;1-piperidin-2-ylacetone (SALTDATA: FREE)
CBNumber:
CB6937672
분자식:
C8H15NO
포뮬러 무게:
141.21
MOL 파일:
4396-01-4.mol

아이소펠레티에린;1-(2-피페리디닐)-2-프로판온 속성

녹는점
130-132 °C
끓는 점
195 °C
밀도
0.918±0.06 g/cm3(Predicted)
저장 조건
Hygroscopic, -20°C Freezer, Under inert atmosphere
용해도
클로로포름(약간 용해됨), 에틸아세테이트(약간 용해됨)
물리적 상태
기름
산도 계수 (pKa)
pK1:9.45 (15°C)
색상
무색~연황색
안정성
흡습성

안전

아이소펠레티에린;1-(2-피페리디닐)-2-프로판온 C화학적 특성, 용도, 생산

개요

An alkaloid of this name was discovered by Tanret but when this alkaloid was shown to be (±)-pelletierine, the name was adopted for this particular base isolated from Punica granatum. The alkaloid is an oily liquid which yields a number of well crystalline salts and derivative: the hydrochloride, m.p. 143°C; hydrobromide, m.p. 149°C; picrate, m.p. 147 -8°C and the picrolonate, m.p. 185-6°C. The N-acetyl derivative is an oily liquid, b.p. 110-5°C/0.I mm while the N-benzoyl compound is crystalline with m.p. 72-4°C. The alkaloid may be prepared by the demethylation of methylisopelletierine, the action being revers_x0002_ible.

참고 문헌

Tanret., Compt. rend., 88, 716 (1879) Tanret., ibid, 90, 696 (1880) Hesse., Rev. trav. Chim., 52, 1005 (1919) Hess, Littman., Annalen, 494, 7 (1932) Wibaut, Kloppenburg, Beets., Rev. trav. Chim., 63, 134 (1944) Anet, Hughes, Ritchie., Nature, 164, 50 I (1949) Galinovsky, Branchetti, Vogl.,Monatsh., 84, 1221 (1953) Galinovsky, Hollinger., ibid, 85, 1012 (1954) Wibaut, Hirschel., Rev. trav. Chim., 75,225 (1956)

아이소펠레티에린;1-(2-피페리디닐)-2-프로판온 준비 용품 및 원자재

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