이프로다이온
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이프로다이온 속성
- 녹는점
- 130-134 °C(lit.)
- 밀도
- 1.6223 (rough estimate)
- 증기압
- 5 x 10-7 Pa (25 °C)
- 굴절률
- 1.6140 (estimate)
- 인화점
- 2 °C
- 저장 조건
- Sealed in dry,Room Temperature
- 용해도
- DMSO: 100 mg/mL (302.87 mM)
- 물리적 상태
- Solid
- 산도 계수 (pKa)
- 9.19±0.20(Predicted)
- 색상
- White to off-white
- 수용성
- 0.0013g/100mL
- Merck
- 13,5096
- BRN
- 895003
- LogP
- 3.000
- CAS 데이터베이스
- 36734-19-7(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | Xn,N,F | ||
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위험 카페고리 넘버 | 40-50/53-36-20/21/22-11 | ||
안전지침서 | 36/37-60-61-36-26-16 | ||
유엔번호(UN No.) | UN 3077 9/PG 3 | ||
WGK 독일 | 3 | ||
RTECS 번호 | NI8870000 | ||
HS 번호 | 29332900 | ||
유해 물질 데이터 | 36734-19-7(Hazardous Substances Data) | ||
독성 | LD50 in mice, rats (g/kg): 4, 3.5 orally (Lacroix, 1980) | ||
기존화학 물질 | KE-10192 |
그림문자(GHS): | ||||||||||||||||||||||
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신호 어: | Warning | |||||||||||||||||||||
유해·위험 문구: |
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예방조치문구: |
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이프로다이온 C화학적 특성, 용도, 생산
용도
Iprodione is a non-systemic fungicide that exhibits both protectant and eradicant activities against the spores and mycelium of a number of parasitic fungi. It is effective against Alternaria, Botrytis, Corticium, Fusarium, Helminthosporium, Monilinia, Phoma, Pleiochaeta, Rhizoctonia and Sclerotinia, etc. in nut crops, fruit trees (stone and pome fruit), vines, berries, vegetables, cereals, oilseed rape, cotton and ornamentals. Iprodione also controls various summer and winter turf diseases.정의
ChEBI: An imidazolidine-2,4-dione in which the nitrogen at position 1 is substituted by an N-(isopropyl)carboxamide group while that at position 3 is substituted by a 3,5-dichlorophenyl group. A contact fungicide, it blocks the growth of the fu gal mycelium and inhibits the germination of fungal spores. It is used on fruit and vegetable crops affected by various fungal diseases. It is also used as a nematicide.생산 방법
The synthesis uses 3,5-dichloroaniline which is coupled with glycine and phosgene. The urea substructure is formed by reaction with isopropylamine and phosgene. Many fungicide mixtures with Iprodione are on the market.Safety Profile
Moderately toxic by ingestion. When heated to decomposition it emits very toxic fumes of NOx and Cl-.환경귀착
Soil. Readily degrades in soil (half-life 20 to 160 days) releasing carbon dioxide 3,5dichloroaniline (Walker, 1987) and (Hartley and Kidd, 1987; Worthing and Hance, 1991). The rate of degradation increases with repeated applications of this fungicide. In a clay loam, the half-life was 1 week. After the second and third applications, the half-lives were 5 and 2 days, respectively (Walker et al., 1986).Plant. Translocation and uptake by potato plants were reported (Cayley and Hide, 1980). Iprodione is rapidly metabolized in plants to 3,5-dichloroaniline (Cayley and Hide, 1980; Hartley and Kidd, 1987).
Chemical/Physical. In an aqueous solution at pH 8.7, iprodione hydrolyzed to N-(3,5dichloroanilinocarbonyl)-N-(isopropylaminocarbonyl)glycine (Belafdal et al., 1986). At pH 8.7, complete hydrolysis occurred after 14 hours (Cayley and Hide, 1980).
Gomez et al. (1982) studied the pyrolysis of iprodione in an helium atmosphere at 400–1,000°C. Decomposition began at 300°C producing isopropyl isocyanate and 3-(3,5dichlorophenyl)hydantoin. Above 600°C, the hydantoin ring began to decompose forming the following products: 3-chloroaniline, 3,5-dichloroaniline, chlorinated benzenes and benzonitrile. From 800 to 1,000°C, the hydantoin ring was completed destroyed whichled to the formation of aryl isocyanates, anilines and the corresponding diarylureas, namely 3-(3,5-dichlorophenyl)urea and 1-(3-chlorophenyl)-3-(3,5-dichlorophenyl)urea (Gomez et al., 1982).
신진 대사 경로
The opening and rearrangement of the dioxoimidazolidine ring is the initial and major degradation/metabolic reaction for iprodione. Iprodione degrades in soil via cleavage of the dioxoimidazolidine-carboxamide linkage, followed by ring opening to yield 3,5-dichloroaniline and CO2. In plants and animals, primary degradation reactions include N-dealkylation of the isopropyl moiety, ring opening and aryl hydroxylation (Scheme 1).이프로다이온 준비 용품 및 원자재
원자재
이소프로필이소시아네이트
HYDANTOIC ACID
글리신
트리에틸아민
포스겐
3,5-Dichlorophenyl isocyanate
이소프로필에테르
이소프로필아민
3,5-디클로로아닐린
준비 용품
이프로다이온 공급 업체
글로벌( 271)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
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Qingdao Trust Agri Chemical Co.,Ltd | +8613573296305 |
aroma@qdtrustagri.com | China | 299 | 58 |
Henan Bao Enluo International TradeCo.,LTD | +86-17331933971 +86-17331933971 |
deasea125996@gmail.com | China | 2503 | 58 |
HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD | +8615383190639 |
admin@86-ss.com | China | 1000 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21667 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 |
sales@coreychem.com | China | 29888 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28180 | 58 |
Xiamen AmoyChem Co., Ltd | +86-592-6051114 +8618959220845 |
sales@amoychem.com | China | 6387 | 58 |
Shandong chuangyingchemical Co., Ltd. | 18853181302 |
sale@chuangyingchem.com | CHINA | 5909 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 |
sales@chemdad.com | China | 39916 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 49392 | 58 |
이프로다이온 관련 검색:
히단토인 디페닐디클로로실란 디클로로메틸페닐실란 뷰렛 1,3-디메틸-2-이미다졸리디논 이프로다이온
Sodium lauroylglutamate
3-(3,5-Dichlorophenyl)-1-methylhydantoin
1-METHYLHYDANTOIN
1-METHYL-2-IMIDAZOLIDINONE
3-PHENYLIMIDAZOLIDINE-2,4-DIONE
IPRODIONE METABOLITE,IPRODIONE METABOLITE STANDARD
1-PHENYL-IMIDAZOLIDIN-2-ONE
N-(3,5-DICHLORO-PHENYL)-FORMAMIDE
3-CHLOROANILINE-2,4,6-D3
3-(3,5-dichlorophenyl)imidazolidine-2,4-dione
N-ME-GLY-NME2
1-(3,5-DICHLOROPHENYL)UREA