Copper chromite

Copper chromite 구조식 이미지
카스 번호:
12053-18-8
상품명:
Copper chromite
동의어(영문):
Oxocopper;COPPER CHROMITE;COOPER CHROMITE;Einecs 235-000-1;COPPER(II) CHROMITE;COPPERCHROMIUM OXIDE;COPPER CHROMITE CATALYST;oxo-(oxochromiooxy)chromium;CopperChromite(Ba/MnPromoted);copper(ii) chromium(iii) oxide
CBNumber:
CB7172861
분자식:
CrCuH2O
포뮬러 무게:
133.56
MOL 파일:
12053-18-8.mol

Copper chromite 속성

물리적 상태
가루
InChI
InChI=1S/Cr.Cu.H2O/h;;1H2
InChIKey
ZKEGZFIDFXEQLM-UHFFFAOYSA-N
SMILES
[Cr].[Cu].O
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 O,Xi,T,N
위험 카페고리 넘버 8-37-22-49-50
안전지침서 17-45-53-61
유엔번호(UN No.) UN 1479 5.1/PG 2
WGK 독일 3
TSCA Yes
위험 등급 5.1
기존화학 물질 KE-08911
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H272 화재를 강렬하게 함; 산화제 산화성 액체;산화성 고체 구분 2
구분 3
위험
경고
GHS hazard pictograms P210, P220, P221P280, P370+P378,P501
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P220 의류 그리고 가연성 물질로부터 멀리하시오.
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P271 옥외 또는 환기가 잘 되는 곳에서만 취급하시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
NFPA 704
0
1 0

Copper chromite C화학적 특성, 용도, 생산

개요

Copper chromite is a black powder and inorganic pigment thatadopts a spinel crystal structure. It can be made by the high-temperaturecalcination of copper(II) oxide and chromium(III) oxide or the thermaldecomposition of copper chromate, which evolves oxygen at higher temperaturesand decomposes to copper chromite.
Copper chromite
The copper chromite (CuCr2O4) is one of the most efficient materials, has wide commercial application as catalysts being used in the unit processes of organic synthesis such as hydrogenation, dehydrogenation, hydrogenolysis, oxidation, alkylation, cyclization, etc. It can be used in the pollution abatement as the catalyst to remove aqueous organic wastes, volatile organic compound (VOC) and vehicular primary emissions such as CO, unburned hydrocarbon, NOx and soot.

화학적 성질

black powder

용도

Copper chromite is primarily used as a catalyst forhydrogenation reactions because of its ability to hydrogenate functional groupsin aliphatic and aromatic compounds selectively. Industrially, copper chromiteis used to reduce furfural to furfuryl alcohol and butyraldehyde to 1-butanol,partially reduce conjugated dienes to monoenes, and selectively reduce carbonylgroups in vegetable oils. This CuCr catalyst is studied for a variety ofcatalytic applications including converting the hydrogenolysis of cellulose.It is also used as a catalyst for combustion to help control burn rate and as alight-absorbing pigment.

제조 방법

Copper chromite is produced by thermal decomposition of one of three substances. The traditional method is by the ignition of copper chromate:
2CuCrO4 → 2CuCrO3 + O2
Copper barium ammonium chromate is the most commonly used substance for production of copper chromite. The resulting copper chromite mixture produced by this method can only be used in procedures that contain materials inert to barium, as barium is a product of the decomposition of copper barium ammonium chromate, and is thus present in the resulting mixture. The by-product copper oxide is removed using an acetic acid extraction, consisting of washing with the acid, decantation and then heat drying of the remaining solid to yield isolated copper chromite. Copper chromite is produced by the exposure of copper barium ammonium chromate to temperatures of 350-450 °C, generally by a muffle furnace:
Ba2Cu2(NH4)2(CrO4)5 → CrCuO3 + CuO + 2Ba + 4H2O + 4Cr + N2 + 6O2

Copper chromite 준비 용품 및 원자재

원자재

준비 용품


Copper chromite 공급 업체

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