1,3-디페닐-1,3-프로판디온

1,3-디페닐-1,3-프로판디온
1,3-디페닐-1,3-프로판디온 구조식 이미지
카스 번호:
120-46-7
한글명:
1,3-디페닐-1,3-프로판디온
동의어(한글):
1,3-디페닐-1,3-프로판디온
상품명:
Dibenzoylmethane
동의어(영문):
DBM;1,3-diphenylpropane-1,3-dione;1,3-DIPHENYL-1,3-PROPANEDIONE;karenzudk2;phenylphenacylketone;Phenyl phenacyl ketone;1,3-Diphenylpropanedione;1,3-diphenyl-3-propanedione;dppd-h;arenzu dk 2
CBNumber:
CB7175433
분자식:
C15H12O2
포뮬러 무게:
224.25
MOL 파일:
120-46-7.mol
MSDS 파일:
SDS

1,3-디페닐-1,3-프로판디온 속성

녹는점
77-79 °C(lit.)
끓는 점
219-221 °C18 mm Hg(lit.)
밀도
0.800 g/cm3
증기압
0.01Pa at 20℃
굴절률
1.6600 (estimate)
인화점
219-221°C/18mm
저장 조건
Store below +30°C.
용해도
클로로포름(약간 용해됨), 메탄올(약간 용해됨, 초음파처리)
산도 계수 (pKa)
8.95±0.10(Predicted)
물리적 상태
크리스탈
색상
밝은 노란색에서 노란색까지
수용성
에테르, 클로로포름 및 수산화나트륨 수용액에 용해됩니다. 물에 불용성.
Merck
14,3009
BRN
514910
안정성
안정적인. 강한 산화제와 호환되지 않습니다.
InChIKey
NZZIMKJIVMHWJC-UHFFFAOYSA-N
LogP
4.59 at 25℃
CAS 데이터베이스
120-46-7(CAS DataBase Reference)
NIST
1,3-Propanedione, 1,3-diphenyl-(120-46-7)
EPA
1,3-Propanedione, 1,3-diphenyl- (120-46-7)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 36/37/38
안전지침서 22-24/25
WGK 독일 3
RTECS 번호 TZ1930000
위험 참고 사항 Irritant
TSCA Yes
HS 번호 29143900
독성 rat,LD,oral,> 500mg/kg (500mg/kg),National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. Vol. 5, Pg. 28, 1953.
기존화학 물질 KE-12099
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P271 옥외 또는 환기가 잘 되는 곳에서만 취급하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
NFPA 704
1
0 0

1,3-디페닐-1,3-프로판디온 MSDS


Dibenzoylmethane

1,3-디페닐-1,3-프로판디온 C화학적 특성, 용도, 생산

화학적 성질

Dibenzoylmethane (DB), a minor constituent of the root extract of licorice, belongs to the flavonoid family. It is a colorless rhombus flake crystal or yellowish-white powder. soluble in chlorohydrin and chloroform, soluble in sodium hydroxide solution, insoluble in sodium carbonate solution, and very slightly soluble in water. It is used as a colorimetric reagent for the determination of uranium.

출처

Dibenzoylmethane(DBM) is a 1,3-diketone derivative of acetylacetone that has both methyl groups replaced with phenyl groups.Although smaller in size and lacking hydroxyl and methoxy groups,DBM resembles the turmeric spice curcumin (CUR),a diferuloylmethane. Both molecules are metal-chelating agents,contain a B-diketone flanked by two aryl groups,and exhibit anti-proliferative and anticarcinogenic activity. In addition to sharing structural similarity with DBM,CUR,which is also a naturally occurring compound is found in the plant Curcuma longa and has numerous medicinal uses.
DBM and its many naturally occurring derivatives are minor constituentsof licorice. DBM has been isolated from licorice root extracts and otherspecies of Glycyrrhiza.

용도

Dibenzoylmethane is a new kind of PVC heat stabilizer, it has better transparency, nontoxic and odorless. In case of combined use with Calcium/Zinc, Barium/Zin and other heat stabilizer, it can greatly improve the initial color, transparency, long term stability of PVC, and also can improve the precipitation and “zinc burning” problem during the process. It has very good synergy with zinc soaps, and can protect the PVC color. This material can absorb UV at 290nm, which has the effect as light stabilizer and act as long term stabilizer for PVC products.

정의

ChEBI: Dibenzoylmethane is a beta-diketone that is acetylacetone (acac) in which both methyl groups have been replaced by phenyl groups. It is a minor constituent of the root extract of licorice (Glycyrrhiza glabra) and exhibits antimutagenic and anticancer effects. It has a role as an antineoplastic agent, a metabolite and an antimutagen. It is a beta-diketone and an aromatic ketone.

제조 방법

dibenzoylmethane is prepared by condensation of ethyl benzoate with acetophenone.

Safety Profile

Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating vapors

Purification Methods

Dibenzoylmethane (1,3-diphenyl-1,3-propanedione) [120-46-7] M 224.3, m 8 0o. Crystallise dibenzoylmethane from pet ether or MeOH. [Beilstein 7 IV 2512.]

1,3-디페닐-1,3-프로판디온 준비 용품 및 원자재

원자재

준비 용품


1,3-디페닐-1,3-프로판디온 공급 업체

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