1,2,3,4,5,6-헥사클로로사이클로헥세인

1,2,3,4,5,6-헥사클로로사이클로헥세인
1,2,3,4,5,6-헥사클로로사이클로헥세인 구조식 이미지
카스 번호:
608-73-1
한글명:
1,2,3,4,5,6-헥사클로로사이클로헥세인
동의어(한글):
1,2,3,4,5,6-헥사클로로사이클로헥세인(1,2,3,4,5,6-헥사클로로시클로헥산);헥사클로로시클로헥산;헥사클로로사이클로헥산;1,2,3,4,5,6-헥사클로로사이클로헥세인;1,2,3,4,5,6-헥사클로로사이클로헥세인 (이성질체 혼합물);벤젠헥사염화물;헥사클로로사이클로헥세인;헥사클로로사이클로헥세인 (이성질체 혼합물)
상품명:
BHC
동의어(영문):
dol;HCH;hexachlor;BENZENE HEXACHLORIDE;hexachlorocyclohexanes;BHC;fbhc;gyben;kotol;gamtox
CBNumber:
CB7190232
분자식:
C6H6Cl6
포뮬러 무게:
290.83
MOL 파일:
608-73-1.mol
MSDS 파일:
SDS

1,2,3,4,5,6-헥사클로로사이클로헥세인 속성

녹는점
112.75°C
끓는 점
373.64°C (rough estimate)
밀도
1.8700
굴절률
1.5691 (estimate)
용해도
DMSO(약간 용해됨), 메탄올(약간 용해됨)
물리적 상태
분말 또는 플레이크
색상
백색, 결정성 분말
수용성
31.4mg/L(25℃)
EPA
1,2,3,4,5,6-Hexachlorocyclohexane (608-73-1)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T,N
위험 카페고리 넘버 21-25-40-50/53-64-48/22-20/21
안전지침서 22-36/37-45-60-61
유엔번호(UN No.) 2761
WGK 독일 3
RTECS 번호 GV4375000
위험 등급 6.1(b)
포장분류 III
유해 물질 데이터 608-73-1(Hazardous Substances Data)
독성 otr-rat-orl 875 mg/kg/7W-I CRNGDP 5,479,84
기존화학 물질 KE-05-0686
유해화학물질 필터링 97-1-62;06-4-51
함량 및 규제정보 물질구분: 금지물질; 혼합물(제품)함량정보: 헥사클로로시클로헥산 및 이를 1.5% 이상 함유한 혼합물
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H301 삼키면 유독함 급성 독성 물질 - 경구 구분 3 위험 GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H312 피부와 접촉하면 유해함 급성 독성 물질 - 경피 구분 4 경고 GHS hazard pictograms P280,P302+P352, P312, P322, P363,P501
H351 암을 일으킬 것으로 의심됨 (노출되어도 암을 일으키지 않는다는 결정적인 증거가 있는 노출경로가 있다면 노출경로 기재) 발암성 물질 구분 2 경고 P201, P202, P281, P308+P313, P405,P501
H362 모유를 먹는 아이에게 유해할 수 있음 생식독성 물질,수유 또는 수유기에 미치는 영향 추가 카테고리 P201, P260, P263, P264, P270,P308+P313
H373 장기간 또는 반복 노출되면 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킬 수 있음 특정 표적장기 독성 - 반복 노출 구분 2 경고 P260, P314, P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P263 임신·수유 기간에는 접촉하지 마시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P310 삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.

1,2,3,4,5,6-헥사클로로사이클로헥세인 C화학적 특성, 용도, 생산

화학적 성질

BHC is a white-to-brownish crystalline solid with a musty, phosgene-like odor.

용도

Insecticide.

정의

An environmentally persistent constituent of a wide variety of agricultural, medical, and veterinary products.

일반 설명

White to yellow powder or flakes. Musty odor. The gamma isomer is known as lindane, a systemic insecticide. Toxic by ingestion or inhalation.

반응 프로필

Halogenated aliphatic compounds, such as HEXACHLOROCYCLOHEXANE, are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Materials in this group may be incompatible with strong oxidizing and reducing agents. Also, they may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.

위험도

Highly toxic; questionable carcinogen.

잠재적 노출

The major commercial usage of BHC is based upon its insecticidal properties. α-BCH is used as an Agricultural chemical, pesticide, pharmaceutical, and veterinary drug. The 7-isomer has the highest acute toxic ity, but the other isomers are not without activity. It is gen erally advantageous to purify the 7-isomer from the less active isomers. The γ-isomer acts on the nervous system of insects, principally at the level of the nerve ganglia. As a result, lindane has been used against insects in a wide range of applications including treatment of animals, buildings, humans for ectoparasites, clothes; water for mosquitoes; living plants; seeds and soils. Some applications have been abandoned due to excessive residues, e.g., stored food stuffs. By voluntary action, the principal domestic producer of technical grade BHC requested cancellation of its BHC registrations on September 1, 1976. As of July 21, 1978, all registrants of pesticide products containing BHC voluntar ily canceled their registrations or switched their former BHC products to lindane formulations.

Carcinogenicity

A bioassay of lindane of the NCI was published in 1977. The compound was administered for 80 weeks to groups of Osborne–Mendel rats and B6C3F1 mice. Time-weighted dietary levels for male rats were 236 or 472 ppm; for female rats, 135 or 270 ppm; and for male and female mice, 80 or 160 ppm. Results were as follows: in rats, no tumors occurred at a statistically significant incidence in the treated groups of either sex but (2) in mice, the incidence of hepatocellular carcinoma in lowdose males was significant when compared with that in the pooled controls (controls 5/49, low dose 19/49, p = 0.001). This finding, by itself, is insufficient to establish the carcinogenicity of lindane. The incidence of hepatocellular carcinoma in high-dose male mice was not significantly different from that in matched or pooled controls. It is concluded that under the conditions of this bioassay lindane was not carcinogenic for Osborne–Mendel rats or B6C3F1 mice.
As with most other chlorinated insecticides, lindane has been shown to exhibit tumor promotional activity, possibly via inhibition of intercellular communication. Lindane exposures do inhibit formation of liver tumors following exposures to aflatoxin B1, suggesting an activity other than tumor promotion for lindane. Enhancement of enzymatic deactivation of aflatoxin via induction of microsomal enzymes may play a role in this phenomenon.
The combination of lindane’s lack of significant mutagenic activity, its tumor promotional properties, and the lack of epidemiologic evidence suggest that lindane poses a minimal to nonexistent risk of cancer to humans under reasonable and prescribed use conditions.

운송 방법

UN2761 Organochlorine pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

비 호환성

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Decomposes on contact with powdered iron, aluminum, zinc, and on contact with strong bases producing trichlorobenzene.

폐기물 처리

A process has been developed for the destructive pyrolysis of benzene hexachloride @ 400 500℃ with a catalyst mixture which contains 5 10% of either cupric chloride, ferric chloride; zinc chloride; or aluminum chloride on activated carbon.

1,2,3,4,5,6-헥사클로로사이클로헥세인 준비 용품 및 원자재

원자재

준비 용품


1,2,3,4,5,6-헥사클로로사이클로헥세인 공급 업체

글로벌( 40)공급 업체
공급자 전화 이메일 국가 제품 수 이점
Hubei xin bonus chemical co. LTD
86-13657291602
linda@hubeijusheng.com CHINA 22968 58
Hangzhou MolCore BioPharmatech Co.,Ltd.
+86-057181025280; +8617767106207
sales@molcore.com China 49739 58
ZHEJIANG JIUZHOU CHEM CO., LTD
+86-0576225566889 +86-13454675544
admin@jiuzhou-chem.com;jamie@jiuzhou-chem.com;alice@jiuzhou-chem.com China 20000 58
Shaanxi Didu New Materials Co. Ltd +86-89586680 +86-13289823923
1026@dideu.com China 9602 58
Shenzhen Polymeri Biochemical Technology Co., Ltd. +86-400-002-6226 13028896684
sales@rrkchem.com China 55477 58
ShangHai Anpel Co, Ltd. 18501792038
shanpel@anpel.com.cn China 9074 58
QUALITY CONTROL SOLUTIONS LTD. 15920483169
ORDERS@QCSRM.COM China 18735 58
Shaanxi DIDU pharmaceutical and Chemical Co., Ltd 15229059051
1027@dideu.com China 9931 58

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