플루오르화비닐리덴

플루오르화비닐리덴
플루오르화비닐리덴 구조식 이미지
카스 번호:
75-38-7
한글명:
플루오르화비닐리덴
동의어(한글):
1,1-다이플루오로에텐;플루오르화비닐리덴;플루오린화바이닐리덴(플루오르화비닐리덴);플루오린화바이닐리덴(플루오르화비닐리덴);1,1-다이플루오로에틸렌;불화비닐리덴;에텐, 1,1-다이르루오로-;에텐, 1,1-다이플루오로-;에틸렌, 1,1-다이플루오로-;플루오르화 바이닐리덴
상품명:
1,1-DIFLUOROETHYLENE
동의어(영문):
VDF;R1132A;CH2=CF2;HFC1132a;FC-1132A;nci-c60204;NCI-C60208;genetron1132a;Genetron 1132a;halocarbon1132a
CBNumber:
CB7240544
분자식:
C2H2F2
포뮬러 무게:
64.03
MOL 파일:
75-38-7.mol
MSDS 파일:
SDS

플루오르화비닐리덴 속성

녹는점
−144 °C(lit.)
끓는 점
−83 °C(lit.)
밀도
0,617 g/cm3
증기 밀도
2.2 (vs air)
증기압
518 psi ( 21 °C)
굴절률
1.3225 (estimate)
인화점
<-60°C
폭발한계
21.3%
BRN
1733321
Dielectric constant
3.0(Ambient)
CAS 데이터베이스
75-38-7(CAS DataBase Reference)
IARC
3 (Vol. 39, Sup 7, 71) 1999
EPA
Vinylidene fluoride (75-38-7)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 F+,F
위험 카페고리 넘버 12
안전지침서 16-7/9
유엔번호(UN No.) UN 1959 2.1
WGK 독일 3
RTECS 번호 KW0560000
F 고인화성물질 4.5
자연 발화 온도 1184 °F
위험 참고 사항 Flammable
TSCA T
위험 등급 2.1
HS 번호 2903590090
유해 물질 데이터 75-38-7(Hazardous Substances Data)
독성 LCLo inhalation in guinea pig: 800ppb/4H
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H220 극인화성 가스 인화성 가스 구분 1 위험 GHS hazard pictograms P210, P377, P381, P403
H280 고압가스; 가열시 폭발할 수 있음 고압가스 압축가스
액화가스
용존 가스
경고 GHS hazard pictograms P410+P403
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P377 누출성 가스 화재 시 : 누출을 안전하게 막을 수 없다면, 불을 끄려하지 마시오.
P381 누출의 경우, 모든 점화원을 제거하시오.
P410+P403 직사광선을 피하고 환기가 잘 되는 곳에 보관하시오.
NFPA 704
4
1 2

플루오르화비닐리덴 C화학적 특성, 용도, 생산

화학적 성질

Colorless gas; faint ethereal odor. Slightly soluble in water; soluble in alcohol and ether.

용도

1,1-Difluoroethylene is used in the manufacture of polyvinylidene fluoride for its use as a thermal, chemical, and ultraviolet light–resistant agent, and as an anticorrosive agent. The monofilament form is used as filter cloth in the pulp and paper industry. Due to its high melting temperature, it can be used as an insulator. Some of its copolymers are used for their heat- and moisture-resistant properties, primarily in industrial, aerospace, and automotive applications.

일반 설명

1,1-DIFLUOROETHYLENE (or vinylidene fluoride) is a colorless gas which is flammable in the ranges of 5.5 to 21%. 1,1-DIFLUOROETHYLENE is toxic by inhalation and contact. 1,1-DIFLUOROETHYLENE is slightly soluble in water and soluble in alcohol and ether. Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket.

반응 프로필

1,1-DIFLUOROETHYLENE is sensitive to heat. 1,1-DIFLUOROETHYLENE is incompatible with oxidizers. 1,1-DIFLUOROETHYLENE can react violently with hydrogen chloride. Alkyl boron and alkyl hyponitrite compounds initiate polymerization. 1,1-DIFLUOROETHYLENE will form peroxides on exposure to pure oxygen. .

건강위험

Vapors may cause dizziness or asphyxiation without warning. Some may be toxic if inhaled at high concentrations. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating and/or toxic gases.

화재위험

EXTREMELY FLAMMABLE. Will be easily ignited by heat, sparks or flames. Will form explosive mixtures with air. Silane will ignite spontaneously in air. May polymerize explosively when heated or involved in a fire. Vapors from liquefied gas are initially heavier than air and spread along ground. Vapors may travel to source of ignition and flash back. Cylinders exposed to fire may vent and release flammable gas through pressure relief devices. Containers may explode when heated. Ruptured cylinders may rocket.

Safety Profile

Suspected carcinogen with experimental neoplastigenic data. Mildly toxic by inhalation. Mutation data reported. A very dangerous fire hazard when exposed to heat, flame, or oxidzers. Explosive in the form of vapor when exposed to heat or flame. Violent reaction with hydrogen chloride when heated under pressure. To fight fire, stop flow of gas. When heated to decomposition it emits toxic fumes of F-. See also FLUORIDES.

잠재적 노출

Vinylidene fluoride is used in the formulation of many polymers and copolymers, such as chlorotrifluoroethylene-vinylidene fluoride (Kel F), perfluoropropylene-vinylidene fluoride (Viton, Fluorel); polyvinylidene fluoride; and hexafluoropropylene-tetra-fluoroethylene- vinylidene fluoride; elastomeric copolymers. It is also used as a chemical intermediate in organic synthesis. NIOSH has estimated 32,000 workers are exposed annually.

환경귀착

Oxidative metabolism of 1,1-Difluoroethylene is mediated by the hepatic microsomal monooxygenase to form epoxide and the inactivation of hemeprotein.

운송 방법

UN1959 Vinylidene fluoride shipped as 1,1-Difluoroethylene or Refrigerant gas R-1132a, Hazard Class: 2.1; Labels: 2.1-Flammable gas. Cylinders must be transported in a secure upright position, in a well-ventilated truck. Protect cylinder and labels from physical damage. The owner of the compressed gas cylinder is the only entity allowed by federal law (49CFR) to transport and refill them. It is a violation of transportation regulations to refill compressed gas cylinders without the express written permission of the owner.

비 호환성

idizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, aluminum chloride. Capable of forming unstable peroxides, which can cause explosive polymerization. It can re act violently with hydrogen chloride. Alkyl boron and alkyl hyponitrite compounds initiate polymerization. It will form peroxides on exposure to pure oxygen. May accumulate static electricity, and cause ignition of its vapors.

폐기물 처리

Return refillable compressed gas cylinders to supplier.

플루오르화비닐리덴 준비 용품 및 원자재

원자재

준비 용품


플루오르화비닐리덴 공급 업체

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