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자일리딘

자일리딘 구조식 이미지

카스 번호:: 95-68-1

한글명:: 자일리딘

동의어(한글):: 2,4-자일리딘;M-크실리딘;자일리딘;2,4-자일리딘;2,4-다이메틸아닐린;m-자일리딘;벤젠아마이드,2,4-다이메틸-

상품명:: 2,4-Dimethyl aniline

동의어(영문):: 2,4-DIMETHYLANILINE;2,4-XYLIDINE;Benzenamine, 2,4-dimethyl-;M-XYLIDINE;m-4-Xylidine;meta-xylidine;2,4-Xylylamine;2.4-DiMethylan;ASYM-M-XYLIDINE;4-AMINO-M-XYLENE

CBNumber:: CB7278882

분자식:: C8H11N

포뮬러 무게:: 121.18

MOL 파일:: 95-68-1.mol

MSDS 파일:: SDS

속성

안전

MSDS

용도

공급 업체 369

자일리딘 속성

녹는점: 16 °C

끓는 점: 218 °C(lit.)

밀도: 0.98 g/mL at 25 °C(lit.)

증기 밀도: 4.2 (vs air)

증기압: 0.16 mm Hg ( 25 °C)

굴절률: n20/D 1.558(lit.)

인화점: 195 °F

저장 조건: room temp

용해도: 5g/L

물리적 상태: 액체

산도 계수 (pKa): pK1:4.89(+1) (25°C)

색상: 투명한 노란색에서 적갈색까지

냄새: 아민 같은

수소이온지수(pH): 7 (22g/l, H2O, 20℃)

폭발한계: 1.1-7.0%(V)

수용성: 5g/L(20℃)

Merck: 14,10084

BRN: 636243

Dielectric constant: 4.9000000000000004

안정성: 안정적인. 타기 쉬운. 강한 산화제, 산, 산 무수물, 산 염화물, 클로로포름산염, 할로겐과 호환되지 않습니다.

LogP: 2.02 at 23℃ and pH8

CAS 데이터베이스: 95-68-1(CAS DataBase Reference)

IARC: 3 (Vol. 16, Sup 7) 1987

NIST: Benzenamine, 2,4-dimethyl-(95-68-1)

EPA: 2,4-Dimethylaniline (95-68-1)

안전

위험 및 안전 성명
위험 및 사전주의 사항 (GHS)

위험품 표기	T,N
위험 카페고리 넘버	23/24/25-33-51/53
안전지침서	28-36/37-45-61-28A
유엔번호(UN No.)	UN 1711 6.1/PG 2
WGK 독일	2
RTECS 번호	ZE8925000
F 고인화성물질	8
자연 발화 온도	860 °F
TSCA	Yes
위험 등급	6.1
포장분류	II
HS 번호	29214910
유해 물질 데이터	95-68-1(Hazardous Substances Data)
기존화학 물질	KE-11201

그림문자(GHS):

신호 어:

Danger

유해·위험 문구:

암호	유해·위험 문구	위험 등급	범주	신호 어	그림 문자	P- 코드
H373	장기간 또는 반복 노출되면 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킬 수 있음	특정 표적장기 독성 - 반복 노출	구분 2	경고		P260, P314, P501
H411	장기적 영향에 의해 수생생물에 유독함	수생 환경유해성 물질 - 만성	구분 2

예방조치문구:

P273	환경으로 배출하지 마시오.
P280	보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P310	삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
P314	불편함을 느끼면 의학적인 조치·조언을 구하시오.

NFPA 704

	1
3		0

자일리딘 MSDS

1-Amino-2,4-dimethylbenzene

자일리딘 C화학적 특성, 용도, 생산

화학적 성질

colourless to yellow or dark brown liquid

용도

2,4-Xylidine, as part of the commercial mixture, has the same uses as xylidine.

정의

ChEBI: A primary arylamine that is aniline in which the hydrogens at the 2- and 4-positions are replaced by methyl groups. A clear to yellow liquid, it is used in production of certain dyes, pesticides and other chemicals.

일반 설명

Dark brown liquid.

공기와 물의 반응

2,4-Dimethyl aniline may be sensitive to prolonged exposure to air. Slightly soluble in water.

반응 프로필

2,4-Dimethyl aniline ignites on contact with fuming nitric acid . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

화재위험

2,4-Dimethyl aniline is combustible.

Safety Profile

Suspected carcinogen. Poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also other xylidine entries.

신진 대사 경로

The major urinary metabolite of 2,4-dimethylaniline (2,4-DMA) in rats is N-acetyl-4-amino-3-methylbenzoic acid, while in dogs, it is 6-hydroxy-2,4-dimethylaniline. Dogs also produce a smaller amount of unacetylated 4-amino-3-methylbenzoic acid and its glycine conjugate. 2,6-Dimethylaniline (2,6-DMA) is metabolized principally to 4-hydroxy-2,6- dimethylaniline in both species, but dogs also produce a significant quantity of 2-amino-3-methylbenzoic acid along with a trace amount of the glycine conjugate of the latter metabolite and 2,6-dimethylnitrosobenzene. Trace levels of an unknown postulated to be 3,5- dimethyl-4-iminoquinone are found in dog urine.

Purification Methods

Convert uns-xylidine to a derivative (see below) which, after recrystallisation, is decomposed with alkali to give the free base. Dry it over KOH and fractionally distil. The acetyl derivative has m 130o, the benzoyl derivative has m 192o, and the picrate has m 209o. [Beilstein 12 H 1111, 12 IV 2545.]

자일리딘 준비 용품 및 원자재

원자재

디메틸니트로벤젠 디메틸니트로벤젠 3-자일렌

준비 용품

AMITRAZ METABOLITE HYDROCHLORIDE 6-아미노-2-((2,4-다이메틸페닐)-1H-벤즈[de]아이소퀴놀린-1,3-(2 H)-다이온 2,6-다이메틸아닐린 Solvent Yellow 18 아미트라즈 4-브로모-메타-크실렌 1,4-DICYANONAPHTHALENE 2,4-Dimethyl-3-nitroaniline 4-CHLORO-M-XYLENE 5,7-DIMETHYLISATIN 2,4-DIMETHYL-5-NITROANILINE 2,4-Dimethylphenylhydrazine hydrochloride Naphtho[2,1-d]thiazole-8-sulfonic acid, 2-(3-aminophenyl)-7-[(2,4-dimethylphenyl)azo]-6-hydroxy-, monosodium salt disodium 5-(acetylamino)-3-[(dimethylphenyl)azo]-4-hydroxynaphthalene-2,7-disulphonate 2,4-bis(2,4-xylylazo)resorcinol Direct Red 264 Jute Scarlet R

자일리딘 공급 업체

글로벌( 369)공급 업체

공급자	전화	이메일	국가	제품 수	이점
Changde Changlian Chemical Co., Ltd.	+86-25-86736270 +86-15905172087	brian.he@royal-chem.com	China	103	58
Hebei Yanxi Chemical Co., Ltd.	+8617531190177	peter@yan-xi.com	China	5993	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55
Hangzhou FandaChem Co.,Ltd.	008657128800458; +8615858145714	fandachem@gmail.com	China	9348	55
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32480	60
Anhui Royal Chemical Co., Ltd.	+86-25-86655873 +8613962173137	marketing@royal-chem.com	China	142	55
Tianjin Zhongxin Chemtech Co., Ltd.	+86-022-66880623 +8618622897568	sales@tjzxchem.com	China	559	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Shanghai Worldyang Chemical Co.,Ltd.	,+86-21-56795779; +8613651600618	sales@worldyachem.com	China	879	58