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펜발러레이트

펜발러레이트
펜발러레이트 구조식 이미지
카스 번호:
51630-58-1
한글명:
펜발러레이트
동의어(한글):
펜발러레이트;펜발레레이트,4-클로로-(알파-(1-메틸에틸)벤젠아세트산시아노(3-펜옥시페닐)메틸에스테르
상품명:
Fenvalerate
동의어(영문):
DUFON;FENNY;ARFEN;fenkem;Tirade;ectrin;FENVAL;Extrin;Pydrin;S-5602
CBNumber:
CB7281563
분자식:
C25H22ClNO3
포뮬러 무게:
419.9
MOL 파일:
51630-58-1.mol

펜발러레이트 속성

녹는점
54-59℃
끓는 점
300°C
밀도
d23 1.17
증기압
1.92×10-5 Pa (20 °C)
굴절률
nD20 1.5533
저장 조건
−20°C
물리적 상태
neat
수용성
Soluble in 100% ethanol (>25 mg/ml), water (0.001 g/L) at 20°C, and DMSO.
Merck
13,4038
BRN
2025982
NIST
Benzeneacetic acid, 4-chloro-«alpha»-(1-methylethyl)-, cyano(3-phenoxyphenyl)methyl ester(51630-58-1)
EPA
Benzeneacetic acid, 4-chloro-.alpha.-(1-methylethyl)-, cyano(3-phenoxyphenyl)methyl ester(51630-58-1)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T,N
위험 카페고리 넘버 25-36/37/38-50/53-57
안전지침서 26-45-60-61
유엔번호(UN No.) UN 2811 6.1/PG 3
WGK 독일 3
RTECS 번호 CY1576350
위험 등급 6.1(b)
포장분류 III
HS 번호 29269090
유해 물질 데이터 51630-58-1(Hazardous Substances Data)
독성 LD50 orally in rats: 451 mg/kg (DMSO); >3200 mg/kg (aqueous suspension), Shell Technical Data Bulletin
그림문자(GHS):
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H301 삼키면 유독함 급성 독성 물질 - 경구 구분 3 위험 P264, P270, P301+P310, P321, P330,P405, P501
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 P264, P280, P305+P351+P338,P337+P313P
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고
H400 수생생물에 매우 유독함 수생 환경유해성 물질 - 급성 구분 1 경고 P273, P391, P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 P273, P391, P501
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P273 환경으로 배출하지 마시오.
P301+P310 삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P405 밀봉하여 저장하시오.
P501 ...에 내용물 / 용기를 폐기 하시오.

펜발러레이트 C화학적 특성, 용도, 생산

개요

Fenvalerate is a yellow-brown viscous liquid that is practically soluble in water. It is stable to moderate heat and light and is rapidly hydrolysed in basic environments (above pH 8). Fenvalerate is a racemic mixture of four stereoisomers in equal proportions owing to the presence of two chiral centres. It is a synthetic type II pyrethroid.
Fenvalerate is registered as an insecticide for a wide array of crop uses, as well as a termiticide and insect repellent.

화학적 성질

It is an ester of 2-(4-chlorophenyl)-3-methylbutyric acid and alpha-cyano-3-phenoxybenzyl alcohol but lacks a cyclopropane ring. However, in terms of its insecticidal behaviour, it belongs to the pyrethroid insecticides. Technical grade fenvalerate is a yellow or brown viscous liquid having a specific gravity of 1.175 at 25°C. The vapour pressure is 0.037 mPa at 25°C, and it is relatively non-volatile. It is practically insoluble in water (approximately 2 μg/L) but soluble in organic solvents such as acetone, xylene, and kerosene. It is stable to light, heat, and moisture but unstable in alkaline media.

화학적 성질

Yellowish to brown viscous liquid. Also available as an emulsifiable concentrate, which is corrosive. Technical grade is a brown viscous liquid. Faint chemical odor. Boiling point = decomposes.

용도

Insecticide used against a wide variety of pests.

용도

An insecticide, used to control insects from food crops, animal feed and cotton products.

용도

Fenvalerate controls a wide range of insect pests in fruit, vines, olives, hops, nuts, vegetables, cotton, oilseed rape, sunflowers, alfalfa, cereals, maize, sorghum, potatoes, beets, soyabeans, tobacco, sugar cane and ornamentals. It is also used in public health situations and in animal houses.

정의

ChEBI: A carboxylic ester obtained by formal condensation between 2-(4-chlorophenyl)-3-methylbutyric acid and cyano(3-phenoxyphenyl)methanol.

일반 설명

A clear viscious yellow liquid with a mild odor. Used as broad spectrum insecticide.

공기와 물의 반응

Insoluble in water. Rapidly hydrolyzed by alkaline solution.

반응 프로필

A pyrethroid. Phenvalerate is an ester and nitrile. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Nitriles may polymerize in the presence of metals and some metal compounds. They are incompatible with acids; mixing nitriles with strong oxidizing acids can lead to extremely violent reactions. Nitriles are generally incompatible with other oxidizing agents such as peroxides and epoxides. The combination of bases and nitriles can produce hydrogen cyanide. Nitriles are hydrolyzed in both aqueous acid and base to give carboxylic acids (or salts of carboxylic acids).

위험도

Questionable carcinogen.

색상 색인 번호

Fenvalerate is an insecticide of the synthetic pyrethroid group, which induced sensitization in farmers.

Safety Profile

Poison by ingestion, intravenous, and intracerebral routes. Moderately toxic by skin contact.Experimental reproductive effects. Mutation data reported. Highly toxic to fish and bees. Corrosive, causes eye damage. A skin irritant. When heated to decomposition it emits toxic fumes of Cl-, NOx, and CN-. See also CYANIDE.

잠재적 노출

Fenvalerate is one of the most versatile synthetic pyrethroid insecticides. It is mostly used in agriculture and on cattle, but also in homes and gardens. It acts as a stomach poison against a wide variety of leaf and fruit eating such as bollworm fruit and shoot borers and aphids. Crops on which it is used include cotton, cauliflower, okra, vines and fruits. It is also used in public health and animal husbandry. It is effective against pests whose strains are resistant to organochlorine, organophosphorus, and carbamate insecticides. Not used in EU countries

환경귀착

Soil. Fenvalerate is moderately persistent in soil. The percentage of the initial dosage (1 ppm) remaining after 8 weeks of incubation in an organic and mineral soil were 58 and 12%, respectively, while in sterilized controls 100 and 91% remained, respectively (Chapman et al., 1981).
In a sugarcane runoff plot, fenvalerate was applied at a rate of 0.22 kg/ha 4 times each year in 1980 and 1981. Runoff losses in 1980 and 1981 were 0.08 and 0.56 of the applied amount, respectively (Smith et al., 1983).
Plant. Dislodgable residues of fenvalerate on cotton leaf 0, 24, 48, 72 and 96 hours after application (0.22 kg/ha) were 0.85, 0.36, 0.38, 0.28 and 0.28 μg/m2, respectively (Buck et al., 1980).
Surface Water. In an estuary, the half-life of fenvalerate was 27–42 days (Schimmel et al., 1983).
Chemical/Physical. Undergoes hydrolysis at the ester bond (Hartley and Kidd, 1987). Decomposes gradually at 150–300°C (Windholz et al., 1983) probably releasing toxic fumes of nitrogen and chlorine.

신진 대사 경로

After foliar treatment of 14C-fenvalerate on wheat plants, the amount of residual radioactivity in the grain and hull is below the limit of reliable measurement. Individual degradation products accounting for more than 1% of the applied radioactivity are not present in the foliage or straw. Important degradation pathways include decarboxylation and ester cleavage.

운송 방법

UN3349 Pyrethroid pesticide, solid toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous material. UN3352 Pyrethroid pesticide, liquid toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Degradation

Fenvalerate is relatively stable at pH 5 and 7 (half-lives of 130-220 days), while at pH 9.0 it undergoes ester hydrolysis (half-life of about 65 days), resulting in the formation of 2-(4-chlorophenyl)-3-methylbutyric acid (CPIA, 2) as a major degradation product. Esfenvalerate and fenvalerate showed no significant difference in hydrolysis rate in water; however, esfenvalerate underwent epimerisation in the alcohol moiety under alkaline and neutral aqueous conditions (ICPS, 1990).
Fenvalerate, underwent rapid photodegradation under the action of UV light with a half-life of 16-18 min in methanol, hexane, or acetonitrile/ water (60/40). 2-(3-Phenoxyphenyl)-3-(4-chlorophenyl)methylpentanenitrile (decarboxy-fenvalerate) (3) was the major photoproduct, amounting to 54-57% of the total reaction mixture. There were smaller amounts of the dechlorinated analogue of decarboxy-fenvalerate (3) and the dimer of 2,2-dimethyl-4-chlorostyrene3,- phenoxybenzoyl cyanide, 4-chloroisobutylbenzene, 2,2-dimethyl-4-chlorostyrene, 3-phenoxybenzyl cyanide, its dimer, 1,2-bis(phenoxyphenyl)ethane, CPIA (Z), 3-phenoxybenzoic acid (3PBA) (4) and 1-(4-chlorophenyl)-2-methylpropano(lH olmstead et al., 1978). The products are shown in Scheme 1.
The photodegradation of fenvalerate in water and on soil was investigated using several 14C-labelled preparations. On exposure to sunlight, fenvalerate was rapidly decomposed in distilled water, 2% aqueous acetone, filter-sterilised river water or sea water to almost the same extent. The half-lives were approximately 4 days in summer and 13-15 days in winter. On soil surfaces, the rate of photodegradation was dependent on the soils used, the half-lives being 2-18 days. One of the major photodegradation products was decarboxy-fenvalerate (3). Other major products were 3PBA (4) and CPIA (2), derived from the ester bond cleavage, amounting to 43% and 58%, respectively, of the applied radioactivity after 6 weeks. In addition, small amounts of a-carbamoyl-3-phenoxybenzyl 2-(4-chloropheny)-3-methylbutyrate(CONH2-fenvalerate) (5), α-carboxy-3-phenoxybenyl 2-(4-chlorophenyl)-3-methylbutyrate( CONH2-fenvalerate) (6), 3-phenoxybenzyl cyanide, 3-phenoxyphenylacetamide and Sphenoxyphenylacetic acid were formed (Mikami et al., 1980). Traces of 3-phenoxybenzaldehyde (3PBAl) (7) and 3-phenoxybenzyl alcohol (3PBalc) (8) (shown in Scheme 2) were also formed.

비 호환성

ncompatible with oxidizers, chlorates nitrates, peroxides, sulfuric acid, caustics, ammonia, aliphatic amines, alkanolamines, isocyanates, alkylene oxides, epichlorohydrin. Moisture may cause hydrolysis or other forms of decomposition. Emulsifiable concentrate is corrosive

폐기물 처리

Incineration would be an effective disposal procedure where permitted. If an efficient incinerator is not available, the product should be mixed with large amounts of combustible material and contact with the smoke should be avoided. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers

참고 문헌

[1] http://www.toxipedia.org
[2] Y. Xia, Q. Bian, L. Xu, S. Cheng, L. Song, J. Liu, W. Wu, S. Wang and X. Wang, Genotoxic effects on human spermatozoa among pesticide factory workers exposed to fenvalerate, Toxicology, 2004, vol. 203, 49-60
[3] Terry R Roberts, David H Hutson, Philip W Lee, Peter H Nicholls and Jack R Plimmer, Metabolic Pathways of Agrochemicals: Part 2: Insecticides and Fungicides, 1999

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