2'-Iodoacetophenone
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2'-Iodoacetophenone 속성
- 끓는 점
- 139-140°C 12mm
- 밀도
- 1.72 g/mL at 25 °C(lit.)
- 굴절률
- n
20/D 1.618(lit.)
- 인화점
- 218 °F
- 저장 조건
- Keep in dark place,Sealed in dry,Room Temperature
- 물리적 상태
- 액체
- Specific Gravity
- 1.720
- 색상
- 맑은 노란색
- 감도
- Light Sensitive
- BRN
- 2325078
- CAS 데이터베이스
- 2142-70-3(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | C | ||
---|---|---|---|
위험 카페고리 넘버 | 36/38 | ||
안전지침서 | 26-36-24/25 | ||
WGK 독일 | 3 | ||
위험 등급 | IRRITANT | ||
HS 번호 | 29147000 |
2'-Iodoacetophenone C화학적 특성, 용도, 생산
화학적 성질
Clear yellow liquid용도
2′-Iodoacetophenone (2-Iodoacetophenone) may be used in the synthesis of:indene derivatives
di-(o-acetylphenyl)acetylene
indenol derivative
제조 방법
2'-Iodoacetophenone can be synthesized by diazotization of 2-acetylaniline.To a solution of p-TsOH (22.80 g, 120 mmol) in CH3CN (160 mL) was added an aromatic amine (40 mmol). The resulting amine salt suspension was cooled to 0-5°C. A solution of NaNO2 (5.52 g, 80 mmol) in H2O (12 mL) and KI (16.6 g, 100 mmol) in H2O (12 mL) were added sequentially. The reaction mixture was stirred for 10 minutes, then allowed to warm to ambient temperature and stirred until all the amine was consumed. To the reaction mixture were then added H2O (700 mL), NaHCO3 (1M; until pH=9-10) and Na2S2O3 (2M, 80 mL). The reaction mixture was extracted with EtOAc and purified by column chromatography (hexanes:EtOAc, 9:1 v/v) to give 2'-iodoacetophenone:yellow oil in 94% yield.
화학 반응
2'-Iodoacetophenone is a bioactive molecule that reacts with boronic acids to form aryl boronic acid derivatives. This reaction can be carried out in chlorobenzene or dihedral solvents, and it is scalable and applicable to a variety of boronic acids. The product of this reaction is an organocatalyst for the synthesis of bioactive molecules. 2'-Iodoacetophenone also reacts with dipole-containing additives to form dichlorodiphenyldichloroethane, which has been used as a fungicide, insecticide, and herbicide.일반 설명
2′-Iodoacetophenone is a halogenated aromatic ketone.2'-Iodoacetophenone 준비 용품 및 원자재
원자재
준비 용품
2'-Iodoacetophenone 공급 업체
글로벌( 172)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29797 | 60 |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 |
fandachem@gmail.com | China | 9348 | 55 |
career henan chemical co | +86-0371-86658258 |
sales@coreychem.com | China | 29914 | 58 |
Accela ChemBio Inc. | (+1)-858-699-3322 |
info@accelachem.com | United States | 19965 | 58 |
Alchem Pharmtech,Inc. | 8485655694 |
sales@alchempharmtech.com | United States | 63711 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 |
sales@tnjchem.com | China | 34572 | 58 |
Nanjing Fred Technology Co., Ltd. | +86-02584696168 15380713688 |
Austin@fredchem.cn | CHINA | 865 | 58 |
WinWin Chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 |
sales@win-winchemical.com | China | 13854 | 58 |
Wuxi Rejoys chemical Technology Co., Ltd. | 0510-86103381 |
sales@rejoyschem.com | CHINA | 976 | 58 |
Finetech Industry Limited | +86-27-87465837 +8618971612321 |
info@finetechnology-ind.com | China | 9702 | 58 |
2'-Iodoacetophenone 관련 검색:
아세토페논 4'-히드록시아세토페논 p-메틸아세토페논
Chalcone
3-Nitroacetophenone
4-Nitroacetophenone
3-Aminoacetophenone
2-Bromoacetophenone
2-IODOBENZOPHENONE
4'-IODOACETOPHENONE,4-IODOACETOPHENONE,p-Iodoacetophenone
3'-IODOACETOPHENONE
2-bromo-4'-iodoacetophenone
4'-CHLORO-2-IODOBENZOPHENONE
3'-BROMO-2-IODOBENZOPHENONE
4-FLUORO-2'-IODOBENZOPHENONE
3-ETHOXYCARBONYL-2'-IODOBENZOPHENONE
3'-CHLORO-2-IODOBENZOPHENONE
4'-BROMO-2-IODOBENZOPHENONE