클로로브로모메테인

클로로브로모메테인
클로로브로모메테인 구조식 이미지
카스 번호:
74-97-5
한글명:
클로로브로모메테인
동의어(한글):
브로모클로로메탄;클로로브로모메테인
상품명:
Bromochloromethane
동의어(영문):
CH2ClBr;CHLOROBROMOMETHANE;CBM;halon1011;chlorobrom;Halon 1011;halon-1011;BromochL;ai3-15514;MIL-B-4394-B
CBNumber:
CB7402908
분자식:
CH2BrCl
포뮬러 무게:
129.38
MOL 파일:
74-97-5.mol
MSDS 파일:
SDS

클로로브로모메테인 속성

녹는점
−88 °C(lit.)
끓는 점
68 °C(lit.)
밀도
1.991 g/mL at 25 °C(lit.)
증기 밀도
4.5 (vs air)
증기압
117 mm Hg ( 20 °C)
굴절률
n20/D 1.482(lit.)
인화점
11 °C
저장 조건
2-8°C
용해도
Soluble in acetone, alcohol, benzene, ether (Weast, 1986), and many other solvents, particularly chlorinated hydrocarbons.
Specific Gravity
1.991
수용성
9g/L(20℃)
BRN
1730801
Henry's Law Constant
(x 10-3 atm?m3/mol): 1.44 at 25 °C (approximate - calculated from water solubility and vapor pressure)
노출 한도
NIOSH REL: TWA 200 ppm (1,050 mg/m3), IDLH 2,000 ppm; OSHA PEL: TWA 200 ppm; ACGIH TLV: TWA 200 ppm (adopted)
Dielectric constant
7.8(Ambient)
안정성
안정적이지만 빛에 따라 변색될 수 있습니다. 알루미늄, 마그네슘, 아연, 칼슘, 강산화제와 혼합되지 않습니다.
LogP
1.410
CAS 데이터베이스
74-97-5(CAS DataBase Reference)
NIST
Methane, bromochloro-(74-97-5)
EPA
Halon 1011 (74-97-5)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi,N,Xn,T,F
위험 카페고리 넘버 37/38-41-59-36/37/38-20-39/23/24/25-23/24/25-11-36/38
안전지침서 26-39-59-37/39-45-36/37-16-7
유엔번호(UN No.) UN 1887 6.1/PG 3
WGK 독일 2
RTECS 번호 PA5250000
위험 참고 사항 Irritant
위험 등급 6.1(b)
포장분류 III
HS 번호 29034980
유해 물질 데이터 74-97-5(Hazardous Substances Data)
독성 LC50 (inhalation) for mice 15,850 mg/m3/8-h, rats 28,800 ppm/15-min (quoted, RTECS, 1985). Acute oral LD50 for rats 5,000 mg/kg, mice 4,300 mg/kg (quoted, RTECS, 1985).
IDLA 2,000 ppm
기존화학 물질 KE-03638
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H318 눈에 심한 손상을 일으킴 심한 눈 손상 또는 자극성 물질 구분 1 위험 GHS hazard pictograms P280, P305+P351+P338, P310
H332 흡입하면 유해함 급성 독성 물질 흡입 구분 4 경고 GHS hazard pictograms P261, P271, P304+P340, P312
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
H420 대기 상층부의 오존층을 파괴하여 공공의 건강 및 환경에 유해함 오존층에 유해 함 구분 1 경고 GHS hazard pictograms P502
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
1
1 0

클로로브로모메테인 MSDS


Bromochloromethane

클로로브로모메테인 C화학적 특성, 용도, 생산

화학적 성질

white to light yellow crystal powder

물리적 성질

Clear, colorless liquid with a sweet, chloroform-like odor

용도

Bromochloromethane is used primarily as an extinguishing agent due to its oxygen-depleting properties.

정의

ChEBI: A one-carbon compound substituted by a chloro and a bromo group.

일반 설명

A clear colorless liquid with a sweet chloroform-like odor. Denser than water (density 1.991 g / cm3) and insoluble in water. Hence sinks in water. Boiling point 68°C. Vapors may cause illness if inhaled. Nonflammable. When exposed to high temperatures may emit toxic fumes. Used as a fire extinguishing agent.

공기와 물의 반응

Insoluble in water.

반응 프로필

Bromochloromethane is sensitive to light (may discolor). Incompatible with strong bases and strong oxidizing agents. Also incompatible with active metals, calcium, aluminum, magnesium, zinc and their alloys. Attacks some forms of plastics, rubber and coatings. .

위험도

By inhalation.

건강위험

Toxic by ingestion. Vapors may cause dizziness or suffocation. Exposure in an enclosed area may be very harmful. Contact may irritate or burn skin and eyes. Fire may produce irritating and/or toxic gases. Runoff from fire control or dilution water may cause pollution.

화재위험

Some of these materials may burn, but none ignite readily. Most vapors are heavier than air. Air/vapor mixtures may explode when ignited. Container may explode in heat of fire.

Safety Profile

Mildly toxic by ingestion and inhalation. Mutation data reported. This material has a narcotic action of moderate intensity, although of prolonged duration. Animals exposed for several weeks to 1000 pprn had blood bromide levels as high as 350 mgl100 g. Therefore, until further data are available, it should be considered at least as toxic as carbon tetrachloride and more than minimal exposure to its vapors should be avoided. Dangerous; when heated to decomposition it emits highly toxic fumes of Brand Cl-. See also BROMIDES and CHLORINATED HYDROCARBONS, ALIPHATIC.

잠재적 노출

This compound is used in brominated flame retardants; a fire-extinguishing agent; and in organic synthesis

Carcinogenicity

The U.S. EPA classification is D (not classifiable as to human carcinogenicity). Bromochloromethane is structurally similar to dichloromethane (methylene chloride), which is classified B2 (probable human carcinogen). The classification is based on the lack of data regarding the carcinogenicity of bromochloromethane in humans or animals; however, there are data indicative of genotoxic effects and structural relationships to halogenated methanes classified as B2 (probable human carcinogens).

환경귀착

Biological. When bromochloromethane (5 and 10 mg/L) was statically incubated in the dark at 25 °C with yeast extract and settled domestic wastewater inoculum for 7 d, 100% biodegradation with rapid adaptation was observed (Tabak et al., 1981).
Photolytic. The following rate constants were reported for the reaction of bromochloromethane and OH radicals as measured by both flash photolysis resonance fluorescence and discharge flow electron paramagnetic resonance techniques (x 10-13 cm3/molecule?sec): 0.91 at 4 °C, 1.11–1.13 at 25 °C, 1.32–1.34 at 40 °C, 1.55–1.58 at 57 °C, 1.76–1.90 at 76 °C, 2.10–2.26 at 97 °C (Orkin et al., 1997).
Chemical/Physical. Although no products were identified, the estimated hydrolysis half-life in water at 25 °C and pH 7 is 44 yr (Mabey and Mill, 1978). Bromochloromethane reacts with bisulfide ion (HS-), produced by microbial reduction of sulfate, forming 1,3,5-trithiane and dithiomethane. Estimated reaction rate constants at 25 and 35 °C were 7.29 x 10-5 and 2.42 x 10- 4/M?sec, respectively (Roberts et al., 1992).

운송 방법

UN1887 Bromochloromethane, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

비 호환성

Incompatible with strong oxidizers (possible explosion), reducing agents, bases, carbonates, furyl alcohol, chemically active metals, such as calcium; base metals in the presence of moisture, powdered aluminum; zinc, magnesium. Liquid attacks some plastics, rubber, and coatings.

폐기물 처리

Incinerate together with flammable solvent in furnace equipped with afterburner and alkali scrubber.

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