스타이렌-부타디엔 고무

스타이렌-부타디엔 고무
스타이렌-부타디엔 고무 구조식 이미지
카스 번호:
9003-55-8
한글명:
스타이렌-부타디엔 고무
동의어(한글):
스타이렌-부타디엔고무;스타이렌-부타디엔고무(STYRENE-BUTADIENERUBBER);스타이렌/부타디엔코폴리머
상품명:
Styrene Butadiene Rubber
동의어(영문):
sbs;SBR;STYRENE-BUTADIENE RUBBER;STYRENE/BUTADIENE COPOLYMER;dienols;ricon100;styrene-butadienepolymer;styrene-1,3-butadienecopolymer;Polymerized Styrene Butadiene Rubber;Styrene-butadiene rubber,oil-extended
CBNumber:
CB7476376
분자식:
C36H42X2
포뮬러 무게:
474.72
MOL 파일:
9003-55-8.mol
MSDS 파일:
SDS

스타이렌-부타디엔 고무 속성

밀도
1.04 g/mL at 25 °C
굴절률
1.57
용해도
용해도 매개변수가 7.7~9.4 사이인 용매: 용해성
물리적 상태
슬래브/청크
안정성
안정적인. 타기 쉬운. 강한 산화제와 호환되지 않습니다.
LogP
2.700 (est)
IARC
3 (Vol. 19, Sup 7) 1987
EPA
Styrene 1,3-butadiene polymer (9003-55-8)

안전

WGK 독일 3
RTECS 번호 WL6478000
기존화학 물질 KE-13258
KE-32267

스타이렌-부타디엔 고무 C화학적 특성, 용도, 생산

화학적 성질

solid or viscous liquid, depending upon the degree of polymerisation

용도

Molded or extruded into toys, packaging, appliances, communication cassettes, dinnerware and serviceware.

생산 방법

SBR is prepared mainly by emulsion and solution polymerization in a free-radical process with a mercaptan, such as dodecylmercaptan, which is used as a chain-transfer agent to control molecular weight. In the emulsion process, a soapstabilized water emulsion of styrene and butadiene is polymerized in continuous reactors to form SBR elastomer. “Cold” SBR is produced at a temperature of 5–10°C, and “hot” SBR at about 50°C . Solution SBR is typically made in hydrocarbon solution with an n-butyllithium initiator. The major differences between emulsion and solution styrene–butadiene are in the linearity and molecular-weight distribution of the polymer chains. In nonpolar solvents, the tendency is to produce block copolymer, but random copolymers are formed in polar solvents. SBR can be vulcanized similar to natural rubber but generally requires less sulfur and is more accelerated because of its lowunsaturation.

위험도

Questionable carcinogen.

건강위험

Styrene Butadiene Rubber is prepared in large quantities for tire treads and other, similar uses. The properties, molecular weight, and percentage of monomer can all be controlled in the polymerization process. Hazards of the SBR industry have been identified and related mostly to the monomers and additives. Contact dermatitis and leukemia have been associated with solvent and additive use but not with the actual polymer itself (Checkoway et al., 1984; Kilpikari, 1982). Epidemiological studies in the industry have not revealed a significant increase in disease or causes of death (Matanoski and Schwartz, 1987; Meinhardt et al., 1982). The hazards of the butadiene and styrene monomers were discussed previously.

Safety Profile

An eye irritant. Questionable carcinogen. When heated to decomposition it emits acrid smoke and irritating fumes. See also POLYMERS, INSOLUBLE.

스타이렌-부타디엔 고무 준비 용품 및 원자재

원자재

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