사마륨

사마륨
사마륨 구조식 이미지
카스 번호:
7440-19-9
한글명:
사마륨
동의어(한글):
사마륨
상품명:
SAMARIUM
동의어(영문):
Samarium powder;foil;SM000200;SM000210;SM000205;SM007910;SM000230;SAMARIUM;dif.qualities;samarium atom
CBNumber:
CB7493078
분자식:
Sm
포뮬러 무게:
150.36
MOL 파일:
7440-19-9.mol

사마륨 속성

녹는점
1074 °C (lit.)
끓는 점
1794 °C (lit.)
밀도
7.47 g/mL at 25 °C (lit.)
저장 조건
Store below +30°C.
물리적 상태
가루
색상
은회색
Specific Gravity
7.4
비저항
91.4 μΩ-cm, 0°C
수용성
물에 불용성.
감도
Air & Moisture Sensitive
Merck
13,8425
노출 한도
ACGIH: TWA 2 ppm; STEL 4 ppm
OSHA: TWA 2 ppm(5 mg/m3)
NIOSH: IDLH 25 ppm; TWA 2 ppm(5 mg/m3); STEL 4 ppm(10 mg/m3)
CAS 데이터베이스
7440-19-9(CAS DataBase Reference)
EPA
Samarium (7440-19-9)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 F,R,Xn
위험 카페고리 넘버 11-15-33
안전지침서 16-30-33
유엔번호(UN No.) UN 3089 4.1/PG 3
WGK 독일 3
F 고인화성물질 1-10
TSCA Yes
위험 등급 4.2
포장분류 I
HS 번호 28053019
유해 물질 데이터 7440-19-9(Hazardous Substances Data)
기존화학 물질 KE-30854
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H228 인화성 고체 인화성 고체 구분 1
구분 2
위험
경고
GHS hazard pictograms P210, P240,P241, P280, P370+P378
H261 물과 접촉시 인화성가스를 발생시킴 물반응성 물질 및 혼합물 구분 2
구분 3
위험
경고
GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P231+P232 불활성 기체 하에서 취급하고, 습기를 방지하시오.
P240 용기와 수용설비를 접지 및 접합시키시오.
P241 폭발 방지용 장비[전기적/환기/조명/...]을(를) 사용하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P370+P378 화재 시 불을 끄기 위해 (Section 5. 폭발, 화재시 대처방법의 적절한 소화제)을(를) 사용하시오.
NFPA 704
2
2 2
W

사마륨 C화학적 특성, 용도, 생산

화학적 성질

silvery grey powder

물리적 성질

Samarium is a hard, brittle, silver-white metal. When freshly cut, it does not tarnish significantlyunder normal room temperature conditions. Four of its isotopes are radioactive andemit alpha particles (helium nuclei). They are Sm-146, Sm-147, Sm-148, and Sm-149.
Its melting point is 1,074°C, its boiling point is 1,794°C, and its density is 7.52g.cm3.

Isotopes

There are 41 known isotopes of samarium. Seven of these are consideredstable. Sm-144 makes up just 3.07% of the natural occurring samarium, Sm-150 makesup 7.38% of natural samarium found on Earth, Sm-152 constitutes 26.75%, and Sm-154 accounts for 22.75%. All the remaining isotopes are radioactive and have very longhalf-lives; therefore, they are considered “stable.” All three contribute to the natural occurrenceof samarium: Sm-147 = 14.99%, Sm-148 = 11.24%, and Sm-149 = 13.82%.
Samarium is one of the few elements with several stable isotopes that occur naturallyon Earth.

Origin of Name

It is named after the mineral samarskite.

출처

Samarium is the 39th most abundant element in the Earth’s crust and the fifth in abundance(6.5 ppm) of all the rare-earths. In 1879 samarium was first identified in the mineralsamarskite [(Y, Ce U, Fe)3 (Nb, Ta, Ti5)O16]. Today, it is mostly produced by the ion-exchangeprocess from monazite sand. Monazite sand contains almost all the rare-earths, 2.8% of whichis samarium. It is also found in the minerals gadolinite, cerite, and samarskite in South Africa,South America, Australia, and the southeastern United States. It can be recovered as a byproductof the fission process in nuclear reactors.

Characteristics

Samarium is somewhat resistant to oxidation in air but will form a yellow oxide over time. Itignites at the rather low temperature of 150°C. It is an excellent reducing agent, releases hydrogenwhen immersed in water, and has the capacity to absorb neutrons in nuclear reactors.

용도

Samarium is easy to magnetize, but very difficult to demagnetize. This makes it ideal forthe manufacture of permanent magnets (SmCo5) that are part of the hard disks for computers.Samarium is also used as a neutron absorber in nuclear reactors, as well as for lasers andmetallurgical research. It makes up about 1% of the metals in misch metal, an alloy in cigarettelighter flints. It is also one of several rare-earths used in floodlights and carbon-arc lights usedby the motion picture industry. Samarium is used as a catalyst in several industries, includingthe dehydrogenation of ethanol alcohol.

정의

A silvery element of the lanthanoid series of metals. It occurs in association with other lanthanoids. Samarium is used in the metallurgical, glass, and nuclear industries. Symbol: Sm; m.p. 1077°C; b.p. 1791°C; r.d. 7.52 (20°C); p.n. 62; r.a.m. 150.36.

위험도

The salts of samarium are toxic if ingested. These salts react with water, liberating hydrogen,which may explode.

사마륨 준비 용품 및 원자재

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