네롤

네롤
네롤 구조식 이미지
카스 번호:
106-25-2
한글명:
네롤
동의어(한글):
네롤
상품명:
NEROL
동의어(영문):
CIS-GERANIOL;(Z)-3,7-DIMETHYL-2,6-OCTADIEN-1-OL;(3Z)-3,7-Dimethyl-2,6-octadiene-1-ol;2,6-Octadien-1-ol,3,7-dimethyl-,(Z)-;Vernol;NEROLEX;NERYL ALCOHOL;Nerol solution;2,6-OCTADIEN-1-OL, 3,7-DIMETHYL;(Z)-3,7-dimethylocta-2,6-dien-1-ol
CBNumber:
CB7698233
분자식:
C10H18O
포뮬러 무게:
154.25
MOL 파일:
106-25-2.mol
MSDS 파일:
SDS

네롤 속성

녹는점
<-15 °C
끓는 점
103-105 °C/9 mmHg (lit.)
밀도
0.876 g/mL at 25 °C (lit.)
증기압
2.39Pa at 20℃
FEMA
2770 | NEROL
굴절률
n20/D 1.474(lit.)
인화점
226 °F
저장 조건
2-8°C
용해도
무수 에탄올에 용해됨(lit.)
산도 계수 (pKa)
14.45±0.10(Predicted)
물리적 상태
액체
색상
무색~거의 무색 투명
냄새
100.00%에서. 달콤한 천연 네롤리 감귤 목련
?? ??
꽃향기
수용성
1.311g/L(25℃)
Merck
14,6475
JECFA Number
1224
BRN
1722455
LogP
2.76 at 30℃
CAS 데이터베이스
106-25-2(CAS DataBase Reference)
EPA
2,6-Octadien-1-ol, 3,7-dimethyl-, (2Z)- (106-25-2)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 36/37/38
안전지침서 26-36
유엔번호(UN No.) UN1230 - class 3 - PG 2 - Methanol, solution
WGK 독일 2
RTECS 번호 RG5840000
TSCA Yes
HS 번호 29052210
유해 물질 데이터 106-25-2(Hazardous Substances Data)
독성 The acute oral LD50 value in rats was reported as 4.5 g/kg (3.4-5.6 g/kg) (Moreno, 1972). The acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1972).
기존화학 물질 KE-11600
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P272 작업장 밖으로 오염된 의복을 반출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
1
2 0

네롤 C화학적 특성, 용도, 생산

개요

Nerol has a fresh, sweet, rose-like odor and a bitter flavor. Nerol may be synthesized from pinene.

화학적 성질

Nerol occurs in small quantities in many essential oils where it is always accompanied by geraniol; its name originates from its occurrence in neroli oil. Nerol is a colorless liquid with a pleasant rose-like odor, which, unlike that of geraniol, has a fresh green note. Nerol undergoes the same reactions as geraniol but cyclizes more readily in the presence of acids.
Nerol is produced along with geraniol from myrcene in the process described for geraniol. It can be separated from geraniol by fractional distillation.
Nerol is used in perfumery not only for the same purposes as geraniol, for example, in rose compositions, to which it lends a particular freshness, but also in other blossom compositions. In flavor work, it is used for bouquetting citrus flavors. Technical-grade nerol, often in a mixture with geraniol, is used as an intermediate in the production of citronellol and citral.

출처

Reported found in neroli oil (with geraniol) and in the essential oils of lemongrass, Ceylon citronella, ylangylang, champaca, Cayenne Bois de Rose and bergamot; also in lemon, sweet orange and petitgrain bergamot; in clary sage, lavandin, lavender, Mexican linaloe, myrrh, jasmine, Paraguay petitgrain; also reported among the volatile constituents of currant aroma; Helicrysum angustifolium contains up to 30 to 50% nerol. Also reported found in citrus peel oils and juices, apricot, cranberry, blueberry, currant, grapes, papaya, raspberry, blackberry, strawberry, potato, tomato, cinnamon, ginger, mentha oils, mustard, nutmeg, thyme, hop oil, beer, gin, cognac, brandy, grape wines, tea, honey, Arctic bramble, passion fruit, prune, Japanese plum, rose apple, marjoram, mango, tamarind, cardamom, coriander seed and leaf, tarragon, litchi, licorice, buckwheat, laurel, wort, elderberry, cherimoya, myrtle leaf and berry, buchu oil, Bourbon vanilla, lemon balm, clary sage, loganberry, maté, German chamomile oil and mastic gum leaf oil.

용도

Nerol is an isomer of Geraniol (G367000), used in the synthesis of insect repellant. It is also used in the synthesis of Angelicoin A and Herecinone J, which inhibit collagen-induced platelet aggregat ion.

정의

ChEBI: The (2Z)-stereoisomer of 3,7-dimethylocta-2,6-dien-1-ol. It has been isolated from the essential oils from plants like lemon grass.

제조 방법

From pinene.

일반 설명

The antifungal efficacy of nerol (cis-3,7-Dimethyl-2,6-octadien-1-ol), against Aspergillus flavus, was studied.

Safety Profile

Moderately toxic by intramuscular route. Mildly toxic by ingestion. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.

네롤 준비 용품 및 원자재

원자재

준비 용품


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