METHYL (TRIMETHYLSILYL)ACETATE
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METHYL (TRIMETHYLSILYL)ACETATE 속성
- 끓는 점
- 38-39 °C13 mm Hg(lit.)
- 밀도
- 0.891 g/mL at 25 °C(lit.)
- 굴절률
- n
20/D 1.414(lit.)
- 인화점
- 91 °F
- 저장 조건
- Flammables area
- Specific Gravity
- 0.890
- Hydrolytic Sensitivity
- 2: reacts with aqueous acid
- BRN
- 1098961
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | F,Xi | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 11-36/37/38 | ||
| 안전지침서 | 16-26-36 | ||
| 유엔번호(UN No.) | UN 3272 3/PG 3 | ||
| WGK 독일 | 3 | ||
| F 고인화성물질 | 10-21 | ||
| TSCA | No | ||
| 위험 등급 | 3.1 | ||
| 포장분류 | II | ||
| HS 번호 | 29319090 |
METHYL (TRIMETHYLSILYL)ACETATE C화학적 특성, 용도, 생산
화학적 성질
CLEAR COLOURLESS LIQUID용도
Methyl 2-(Trimethylsilyl)acetate is a useful compound in the organic synthesis.일반 설명
Methyl trimethylsilylacetate on reaction with lithium diisopropylamide in THF at -78°C yields methyl lithiotrimethylsilylacetate. It also undergoes Peterson olefination to yield mainly Z-isomers of steroid 17β-side chain methyl acrylates.Purification Methods
Methyl trimethylsilylacetate [2916-76-9] M 146.3, b 65-68o/50mm, d 4 0.89. Dissolve it in Et2O, shaken with 1M HCl, wash with H2O, aqueous saturated NaHCO3, H2O again, and dry it (a precipitate may be formed in the NaHCO3 solution and should be drawn off and discarded). The solvent is distilled off, and the residue is fractionated through a good column. IR (CHCl3) max 1728cm1 . [Fessenden & Fessenden J Org Chem 32 3535 1967, Matsuda et al. J Org Chem 45 237 1980, Beilstein 4 III 1855, 4 IV 3974 for Et ester.]METHYL (TRIMETHYLSILYL)ACETATE 준비 용품 및 원자재
원자재
준비 용품
METHYL (TRIMETHYLSILYL)ACETATE 공급 업체
글로벌( 71)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
info@dakenam.com | China | 15371 | 58 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 |
fandachem@gmail.com | China | 9350 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 |
ivan@atkchemical.com | China | 32480 | 60 |
| Alchem Pharmtech,Inc. | 8485655694 |
sales@alchempharmtech.com | United States | 63711 | 58 |
| career henan chemical co | +86-0371-86658258 15093356674; |
factory@coreychem.com | China | 29826 | 58 |
| Hubei Co-Formula Material Tech Co., Ltd. | +86-27-84459282 |
sales@cfmats.com | CHINA | 882 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 |
sales@tnjchem.com | China | 34572 | 58 |
| WinWin Chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 |
sales@win-winchemical.com | China | 13854 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 |
info@dycnchem.com | CHINA | 52867 | 58 |
| CD Chemical Group Limited | +8615986615575 |
info@codchem.com | China | 20356 | 58 |
METHYL (TRIMETHYLSILYL)ACETATE 관련 검색:
TERT-BUTYL TRIMETHYLSILYLACETATE
(TRIMETHYLSILYL)ACETIC ACID
Trimethylsilyl acetate
ETHYL TRIMETHYLSILYLDIFLUOROACETATE
TERT-BUTYL-2-CHLORO-2-TRIMETHYLSILYLACETATE
ETHYL (DIPHENYLMETHYLSILYL)ACETATE
2,2-DIFLUORO-2-(TRIMETHYLSILYL)ACETIC ACID PROPYL ESTER
METHYL 2-(TRIMETHYLSILYL)PROPIONATE
METHYL TRIMETHYLSILYLDIFLUOROACETATE
(S)-4-((R)-2-BENZYLOXY-TRIDECYL)-3-HEXYL-3-TRIMETHYLSILANYL-OXETAN-2-ONE
METHYL (1-TRIMETHYLSILYL)ACRYLATE
ETHYL 2-BROMO-2-(1,1,1-TRIMETHYLSILYL)ACETATE
METHYL (TRIMETHYLSILYL)ACETATE
Ethyl (trimethylsilyl)acetate