1,2-Dibromopropane

1,2-Dibromopropane 구조식 이미지
카스 번호:
78-75-1
상품명:
1,2-Dibromopropane
동의어(영문):
1,2-Dobromopropane;1,2-Dibromopropane98%;1,2 - Propylene Dibromide;CH2BrCHBrCH3;1.2-DibroMopro;1,2-Dibrompropan;(RS)-Dibrompropan;PROPYLENE BROMIDE;1,2-DIBROMOPROPANE;1,2-dibromo-propan
CBNumber:
CB7718142
분자식:
C3H6Br2
포뮬러 무게:
201.89
MOL 파일:
78-75-1.mol
MSDS 파일:
SDS

1,2-Dibromopropane 속성

녹는점
-55 °C
끓는 점
140-142 °C(lit.)
밀도
1.937 g/mL at 25 °C(lit.)
굴절률
n20/D 1.519(lit.)
인화점
35 °C
저장 조건
Flammables area
용해도
유기용매: 혼화성
물리적 상태
투명한 액체
색상
Colorless to Light yellow to Light orange
수용성
약간 용해됨
Merck
14,7853
BRN
1718884
Dielectric constant
4.2999999999999998
안정성
안정적인. 가연성. 강산화제, 강염기, 마그네슘과 호환되지 않습니다.
CAS 데이터베이스
78-75-1(CAS DataBase Reference)
NIST
Propane, 1,2-dibromo-(78-75-1)
EPA
1,2-Dibromopropane (78-75-1)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn
위험 카페고리 넘버 10-20/22-36/37/38-20/21/22-40
안전지침서 23-24/25-36/37/39-26-16-45-27
유엔번호(UN No.) UN 1993 3/PG 3
WGK 독일 3
RTECS 번호 TX8574000
TSCA Yes
위험 등급 3
포장분류 III
HS 번호 29033036
유해 물질 데이터 78-75-1(Hazardous Substances Data)
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H226 인화성 액체 및 증기 인화성 액체 구분 3 경고
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H411 장기적 영향에 의해 수생생물에 유독함 수생 환경유해성 물질 - 만성 구분 2
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P273 환경으로 배출하지 마시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
2
2 0

1,2-Dibromopropane MSDS


Propylene dibromide

1,2-Dibromopropane C화학적 특성, 용도, 생산

화학적 성질

1,2-Dibromopropane is considered non-flammable and non-explosive liquid.

용도

1,2-Dibromopropane is used in organic synthesis and solvent. It was used to study the effect of reductant concentration, reductant contact time and suspension pH on reductive dechlorination of carbon tetrachloride by soil manipulated with Fe(II) and HS-. It was used as internal standard during the determination of nitrogenous disinfection byproduct trichloronitromethane by gas chromatography mass spectrometry.

제조 방법

1,2-Dibromopropane is synthesized from bromopropane by bromination.
First mix bromopropane and iron powder, heat to 40-50°C, slowly add bromine, and continue to reflux for 2h after adding. Then, the iron slag was filtered off, and the filtrate was washed several times with water, once with 5% sodium carbonate solution, and then with 5% sodium thiosulfate solution to remove free bromine. Dry with anhydrous calcium chloride. Fractional distillation, collecting 139-142 ℃ fraction is the finished product of 1,2-dibromopropane.

주요 응용

Photodissociation dynamics of 1,2-dibromopropane at 234 and 265 nm has been investigated by using velocity map ion imaging method. 1,2-Dibromopropane was used to study the effect of reductant concentration, reductant contact time and suspension pH on reductive dechlorination of carbon tetrachloride by soil manipulated with Fe(II) andHS-. It was used as internal standard during the determination of nitrogenous disinfection byproduct trichloronitromethane by gas chromatography mass spectrometry.

일반 설명

1,2-dibromopropane is a colorless liquid. Prepared from propyl bromide and Br in the presence of AlCl3 or AlBr3. (NTP, 1992)

공기와 물의 반응

Insoluble in water.

반응 프로필

Halogenated aliphatic compounds, such as 1,2-Dibromopropane, are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Materials in this group may be incompatible with strong oxidizing and reducing agents. Also, they may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. 1,2-Dibromopropane is considered nonflammable.

화재위험

1,2-Dibromopropane is considered non-flammable.

1,2-Dibromopropane 준비 용품 및 원자재

원자재

준비 용품


1,2-Dibromopropane 공급 업체

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