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M-페닐렌다이아민

M-페닐렌다이아민
M-페닐렌다이아민 구조식 이미지
카스 번호:
108-45-2
한글명:
M-페닐렌다이아민
동의어(한글):
1,3-벤젠다이아민;M-페닐렌다이아민;m-페닐렌디아민;m-페닐렌다이아민및그염류;1,3-다이아미노벤젠;1,3-다이아미노페닐렌;1,3-벤젠디아민;1,3-페닐렌다이아민;3-아미노아닐린;m-벤젠다이아민;M-아미노아닐린;벤젠-1,3-다이아민;페닐렌-1,3-다이아민
상품명:
m-Phenylenediamine
동의어(영문):
MPDA;ci76025;apco2330;APCO 2330;c.i.76025;1.3-Phenyl;C.I. 76025;developerc;developerm;Developer C
CBNumber:
CB7852752
분자식:
C6H8N2
포뮬러 무게:
108.14
MOL 파일:
108-45-2.mol

M-페닐렌다이아민 속성

녹는점
64-66 °C
끓는 점
282-284 °C
밀도
1,139 g/cm3
증기 밀도
3.7 (vs air)
증기압
0.62 mm Hg ( 100 °C)
굴절률
1.6339
인화점
>230 °F
저장 조건
Store below +30°C.
용해도
350g/l
물리적 상태
pellets
산도 계수 (pKa)
5.11, 2.50(at 20℃)
색상
Yellow to light tan or brown gray
수소이온지수(pH)
8 (100g/l, H2O, 20℃)
수용성
350 g/L (25 ºC)
감도
Air Sensitive
Merck
14,7283
BRN
471357
InChIKey
WZCQRUWWHSTZEM-UHFFFAOYSA-N
CAS 데이터베이스
108-45-2(CAS DataBase Reference)
IARC
3 (Vol. 16, Sup 7) 1987
NIST
1,3-Benzenediamine(108-45-2)
EPA
1,3-Phenylenediamine (108-45-2)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T,N
위험 카페고리 넘버 23/24/25-36-43-50/53-68-40
안전지침서 28-36/37-45-60-61-28A
유엔번호(UN No.) UN 1673 6.1/PG 3
WGK 독일 2
RTECS 번호 SS7700000
F 고인화성물질 8-10-23
자연 발화 온도 560 °C
TSCA Yes
위험 등급 6.1
포장분류 III
HS 번호 29215119
유해 물질 데이터 108-45-2(Hazardous Substances Data)
독성 LD50 in rats (mg/kg): 650 orally; 283 i.p. (Burnett)
기존화학 물질 KE-02175
유해화학물질 필터링 97-1-334
함량 및 규제정보 물질구분: 유독물질; 혼합물(제품)함량정보: 페닐렌디아민과 그 염류 및 이를 25% 이상 함유한 혼합물
그림문자(GHS):
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H301 삼키면 유독함 급성 독성 물질 - 경구 구분 3 위험 P264, P270, P301+P310, P321, P330,P405, P501
H311 피부와 접촉하면 유독함 급성 독성 물질 - 경피 구분 3 위험 P280, P302+P352, P312, P322, P361,P363, P405, P501
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 P264, P280, P305+P351+P338,P337+P313P
H331 흡입하면 유독함 급성 독성 물질 흡입 구분 3 위험 P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H341 유전적인 결함을 일으킬 것으로 의심됨 (노출되어도 생식세포 유전독성을 일으키지 않는다는 결정적인 증거가 있는 노출경로가 있다면 노출경로 기재) 생식세포 변이원성 물질 구분 2 경고 P201,P202, P281, P308+P313, P405,P501
H400 수생생물에 매우 유독함 수생 환경유해성 물질 - 급성 구분 1 경고 P273, P391, P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 P273, P391, P501
예방조치문구:
P201 사용 전 취급 설명서를 확보하시오.
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P311 의료기관(의사)의 진찰을 받으시오.
P301+P310 삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P405 밀봉하여 저장하시오.
P403+P233 용기는 환기가 잘 되는 곳에 단단히 밀폐하여 저장하시오.
NFPA 704
1
3 1

M-페닐렌다이아민 MSDS


1,3-Diaminobenzene

M-페닐렌다이아민 C화학적 특성, 용도, 생산

화학적 성질

Grey crystal granule

화학적 성질

m-Phenylenediamine is a colorless to white crystalline substance that turns red upon exposure to air

용도

1,3-Phenylenediamine is used in the foaming-type hair dye composition.

용도

The appearance of the high purity of the m-phenylenediamine is snow white flake solid used as a synthetic electronic grade polyimide material and epoxy resin curing agent.

용도

m-Phenylenediamine is used in the foaming-type hair dye composition. It is used as a synthetic electronic grade polyimide material and epoxy resin curing agent. It is used also block polymers, textile fibers, urethanes, petroleum additives, rubber chemicals, in corrosion inhibitors, in photography, as reagent for gold & bromine.

Synthesis Reference(s)

Journal of the American Chemical Society, 102, p. 6182, 1980 DOI: 10.1021/ja00539a054
The Journal of Organic Chemistry, 37, p. 930, 1972 DOI: 10.1021/jo00972a002

일반 설명

Colorless or white colored needles that turn red or purple in air. Melting point 64-66 C. Density 1.14 g / cm3. Flash point 280 F. May irritate skin and eyes. Toxic by skin absorption, inhalation or ingestion. Used in aramid fiber manufacture, as a polymer additive, dye manufacturing, as a laboratory reagent, and in photography.

공기와 물의 반응

Soluble in water [Merck].

반응 프로필

m-Phenylenediamine an aromatic amine, neutralizes acids, acid chlorides, acid anhydrides and chloroformates in exothermic reactions to form salts. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Incompatible with oxidizing agents .

화재위험

m-Phenylenediamine is combustible. Dust may form explosive mixtures in air

Safety Profile

Suspected carcinogen with experimental tumorigenic and teratogenic data. Poison by ingestion, intravenous, subcutaneous, and intraperitoneal routes. Mildly toxic by skin contact. Mutation data reported. Combustible when exposed to heat or flame. A hair dye ingredtent. When heated to decomposition it emits toxic fumes of NOx. See also other phenylenediamine entries and AMINES.

잠재적 노출

Used in making various dyes; as a curing agent for epoxy resin; rubber, textile fibers; urethanes, corrosion inhibitors; adhesives; in photographic and analytical procedures and processes.

Carcinogenicity

"Occupational exposure to m-PDA may occur through inhalation and dermal contact with this compound at workplace where m-PDA is produced or used. The general population may be exposed to m-PDA via dermal contact with consumer products containing this compound."An IARC Working Group concluded, on the basis of lack of human data and inadequate animal data, that m-PDA was not classifiable (Group 3) as to its carcinogenicity to humans.

신진 대사 경로

By the perfused rat liver, 1,3-diaminobenzene (MPD) is metabolized to three identified N-acetylated derivatives N-acetyl-1,3-diaminobenzene, N,N'- diacetyl-1,3-diaminobenzene, and N,N'-diacetyl-2,4- diaminophenol which are identical to the metabolites excreted in rat urine.

운송 방법

UN1673 Phenylenediamines (o-, m-, p-), Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Purification Methods

Purify the diamine by distillation under a vacuum followed by recrystallisation from EtOH (rhombs) and if necessary redistillation. It should be protected from light; otherwise it darkens rapidly. [Neilson et al. J Chem Soc 371 1962, IR: Katritzky & Jones J Chem Soc 3674, 2058 1959, UV: Forbes & Leckie Can J Chem 36 1371 1958.] The hydrochloride has m 277-278o, and the bis-4-chlorobenzenesulfonyl derivative has m 220-221o from H2O (214-215o, from MeOH/H2O) [Runge & Pfeiffer Chem Ber 90 1737 1957]. The acetate has m 191o. [Beilstein 13 IV 79.]

비 호환성

Dust may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, acid chlorides; acid anhydrides; chloroformates. Heat and light contribute to instability. Keep away from metals.

폐기물 처리

Controlled incineration whereby oxides of nitrogen are removed from the effluent gas by scrubber, catalytic or thermal device.

M-페닐렌다이아민 준비 용품 및 원자재

원자재

준비 용품


M-페닐렌다이아민 공급 업체

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ATK CHEMICAL COMPANY LIMITED
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career henan chemical co
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