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메틸 n-아밀케톤

메틸 n-아밀케톤
메틸 n-아밀케톤 구조식 이미지
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메틸 n-아밀케톤
2-헵탄온;메틸n-아밀케톤;2-헵타논;메틸n-아밀케톤;n-아밀 메틸 케톤;메틸 펜틸 케톤
Ick;MAK;hICK;LCK2;fj04c02;KIAA0936;ketonec-7;FEMA 2545;heptan-2-;kinase ICK
포뮬러 무게:
MOL 파일:

메틸 n-아밀케톤 속성

-35 °C (lit.)
끓는 점
149-150 °C (lit.)
0.82 g/mL at 25 °C (lit.)
증기 밀도
3.94 (vs air)
2.14 mm Hg ( 20 °C)
n20/D 1.408(lit.)
2544 | 2-HEPTANONE
106 °F
저장 조건
Store below +30°C.
water: soluble4.21 g/L at 20°C
물리적 상태
Clear colorless
Odor Threshold
4.3 g/L (20 ºC)
JECFA Number
Henry's Law Constant
3.59 at 37 °C (static headspace-GC, Bylaite et al., 2004)
노출 한도
TLV-TWA 235 mg/m3 (50 ppm) (ACGIH), 465 mg/m3 (100 ppm) (NIOSH). .
Stable. Flammable. Incompatible with strong oxidizing agents, strong reducing agents, strong bases.
CAS 데이터베이스
110-43-0(CAS DataBase Reference)
2-Heptanone (110-43-0)
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn
위험 카페고리 넘버 22-38-40-48/20/22-20/22-10
안전지침서 36-24/25
유엔번호(UN No.) UN 2810 6.1/PG 3
WGK 독일 2
RTECS 번호 MJ5250000
자연 발화 온도 739 °F
위험 등급 3
포장분류 III
HS 번호 29141990
유해 물질 데이터 110-43-0(Hazardous Substances Data)
독성 LD50 orally in Rabbit: 1670 mg/kg LD50 dermal Rabbit 10332 mg/kg
기존화학 물질 KE-18303
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H226 인화성 액체 및 증기 인화성 액체 구분 3 경고
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 P264, P270, P301+P312, P330, P501
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 P264, P280, P302+P352, P321,P332+P313, P362
H320 눈에 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2B 경고 P264, P305+P351+P338,P337+P313
H332 흡입하면 유해함 급성 독성 물질 흡입 구분 4 경고 P261, P271, P304+P340, P312
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고
H336 졸음 또는 현기증을 일으킬 수 있음 특정표적장기 독성 물질(1회 노출);마취작용 구분 3 경고 P261, P271, P304+P340, P312,P403+P233, P405, P501
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P233 용기를 단단히 밀폐하시오. 용기는 환기가 잘 되는 곳에 단단히 밀폐하여 보관하시오.
P240 용기와 수용설비를 접지 및 접합시키시오.
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P270 이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P271 옥외 또는 환기가 잘 되는 곳에서만 취급하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P304+P340 흡입하면 신선한 공기가 있는 곳으로 옮기고 호흡하기 쉬운 자세로 안정을 취하시오.
P370+P378 화재 시 불을 끄기 위해 (Section 5. 폭발, 화재시 대처방법의 적절한 소화제)을(를) 사용하시오.
P405 밀봉하여 저장하시오.
P403+P233 용기는 환기가 잘 되는 곳에 단단히 밀폐하여 저장하시오.
P501 ...에 내용물 / 용기를 폐기 하시오.
NFPA 704
1 0

메틸 n-아밀케톤 MSDS

Methyl amyl ketone

메틸 n-아밀케톤 C화학적 특성, 용도, 생산


2-Heptanone has a characteristic banana, slightly spicy odor2-Heptanone may be prepared by oxidation of methyl n-amyl carbinol; also from n-amyl propionic acid or from ethyl butyl acetat.

화학적 성질

2-Heptanone has a fruity, spicy, cinnamon, banana, slightly spicy odor.

화학적 성질

colourless liquid

화학적 성질

Methyl amyl ketone is a clear colorless liquid with a mild, banana-like odor.

물리적 성질

Colorless liquid with a banana-like odor. Can be detected at a concentration of 140 μg/kg (Buttery et al., 1969a). Cometto-Mu?iz et al. (2000) reported nasal pungency threshold concentrations ranging from approximately 195 to 935 ppm. An odor threshold concentration of 6.8 ppbv was reported by Nagata and Takeuchi (1990).


Reported found in clove essential oil, Ceylon cinnamon and rancid coconut oil; also identifed in Ruta Montana Also reported found in banana, lingonberry, loganberry, black currant, guava, grapes, papaya, peach, pear, raspberry, other berries, strawberry jam, asparagus, roasted onion, leek, baked potato, mushroom, clove bud, ginger, blue, cheddar and Swiss cheeses, milk, cream, butter, fsh, meats, hop oil, beer, brandy, rum, malt whiskey, grape wines, cocoa, coffee, tea, peanuts, pecans, walnut, oats, soybeans, coconut oil, olive, passion fruit, mango, fgs, rice, sweet corn, corn tortillas, malt, caviar, shrimp, oysters, crab, crayfsh and mate


Organic solvent


2-Heptanone is used as an industrial solvent; a solvent for synthetic resin finishes; an inert reaction medium; a flavor ingredient in foods; a fragrance ingredient in creams, lotions, perfumes, soaps, and detergents.


Solvent for nitrocellulose lacquers, synthetic flavoring, perfumery.


Methyl amyl ketone is used as a flavoringagent and as a solvent in lacquers andsynthetic resins.


ChEBI: A dialkyl ketone with methyl and pentyl as the alkyl groups.

제조 방법

By oxidation of methyl n-amyl carbinol; also from n-amyl propionic acid or from ethyl butyl acetate.

Aroma threshold values

Detection: 1 ppb to 1.33 ppm; recognition: 2.66 to 3.73 ppm; aroma characteristics at 1.0%: cheesy ketonic, slightly green waxy, banana fruity.

Taste threshold values

Taste characteristics at 20 ppm: cheesy, fruity, coconut, waxy green, creamy, fungal with buttery and brown fruity nuances.

Synthesis Reference(s)

Canadian Journal of Chemistry, 58, p. 2271, 1980 DOI: 10.1139/v80-365
Tetrahedron Letters, 35, p. 8835, 1994 DOI: 10.1016/S0040-4039(00)78511-X
Journal of the American Chemical Society, 102, p. 1047, 1980 DOI: 10.1021/ja00523a023

일반 설명

A clear colorless liquid. Flash point 126°F. Less dense than water and only slightly soluble in water. Hence floats on water. Vapors heavier than air. Density 6.8 lb / gal. Used as a synthetic flavoring and in perfumes.

공기와 물의 반응

Flammable. Slightly soluble in water.

반응 프로필

2-Heptanone reacts exothermically with many acids and bases to produce flammable gases (e.g., H2). The heat may be sufficient to start a fire in the unreacted portion. Reacts with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas and heat. Incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides. Incompatible with many oxidizing agents including nitric acid, nitric acid/hydrogen peroxide mixture, and perchloric acid. May form peroxides [USCG, 1999].


Moderate fire risk. Toxic by inhalation, skin and eye irritant, narcotic in high concentration.


Inhalation can cause headache, fatigue, nausea, vomiting, dizziness, stupor, drowsiness, disturbed vision, and unconsciousness. Skin contact can cause moderate irritation, defatting, and dermatitis. Ingestion may cause irritation of lips and mouth, gastro-intestinal irritation, nausea, diarrhea, drowsiness, loss of consciousness, weak and rapid pulse, cold-pale complexion.


Exposure to methyl amyl ketone causedirritation of mucous membranes, mild tomoderate congestion of the lungs, and narcosis in test animals. A 4-hour exposure to a4000-ppm concentration in air was lethal torats; 1500–2000 ppm produced lung irritation and narcosis. The concentration at whichit produces similar symptoms in humans isnot known.
The oral toxicity of this compound is low.Its irritant action on skin should be low tovery low.
LD50 value, oral (mice): 730 mg/kg.


Combustible liquid, flash point (closed cup) 39.9°C (102°F), (open cup) 48.9°C (12°F); vapor density 3.9 (air = 1) vapor pressure 2.6 torr at 20°C (68°F); autoignition temperature 393°C (740°F); fire-extinguishing agent: “alcohol” foam; a water spray may be used to cool below its flash point.
Methyl amyl ketone forms an explosive mixture with air in the range 1.1% [at 66°C (150.8°F)] to 7.9% [at 121°C (249.8°F)] by volume. It can react explosively with strong acids, alkalies, and oxidizing agents.

Safety Profile

Moderately toxic by ingestion. Mildly toxic by inhalation and skin contact. A skin irritant. A flammable liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and fumes. See also KETONES.


Identified as one of 140 volatile constituents in used soybean oils collected from a processing plant that fried various beef, chicken, and veal products (Takeoka et al., 1996). Also identified as a volatile constituent released by fresh coffee beans (Coffea canephora variety Robusta and Coffea arabica) at different stages of ripeness (Mathieu et al., 1998).


Biological. Heukelekian and Rand (1955) reported a 10-d BOD value of 0.50 g/g which is 17.8% of the ThOD value of 2.81 g/g.
Chemical/Physical. Atkinson et al. (2000) studied the kinetic and products of the gas-phase reaction of 2-heptanone with OH radicals in purified air at 25 °C and 740 mmHg. A relative rate constant of 1.17 x 10-11 cm3/molecule·sec was calculated for this reaction. Reaction products identified by GC, FTIR, and atmospheric pressure ionization tandem mass spectroscopy were (with respective molar yields): formaldehyde, 0.38; acetaldehyde, λ0.05; propanal, λ0.05; butanal, 0.07; pentanal, 0.09; and molecular weight 175 organic nitrates.
2-Heptanone will not hydrolyze because it does not contain a hydrolyzable functional group. Burns in air releasing carbon monoxide and carbon dioxide.

운송 방법

UN1110 n-Amyl Methyl ketone, Hazard Class: 3; Labels: 3-Flammable liquid.

Toxicity evaluation

2-Heptanone is metabolized in the liver and causes toxicity by oxidative and free radical mechanisms. It is known to potentiate both nephrotoxic and hepatotoxic effects of halogenated hydrocarbons.

폐기물 처리

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

메틸 n-아밀케톤 준비 용품 및 원자재


준비 용품

메틸 n-아밀케톤 공급 업체

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Henan Tianfu Chemical Co.,Ltd.
0371-55170693 CHINA 22607 55
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Chongqing Chemdad Co., Ltd
+86-13650506873 CHINA 37282 58
Alchem Pharmtech,Inc.
8485655694 United States 63726 58

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