글루타르산

글루타르산
글루타르산 구조식 이미지
카스 번호:
110-94-1
한글명:
글루타르산
동의어(한글):
글루타르산;글루타릭애씨드
상품명:
Glutaric acid
동의어(영문):
PENTANEDIOIC ACID;glutaric;1,5-PENTANEDIOIC ACID;1,5-PENTADIOIC ACID;1,3-PROPANEDICARBOXYLIC ACID;Glutarsure;Glutarsaure;utaric acid;lutaric acid;GLUTARIC ACID
CBNumber:
CB7852828
분자식:
C5H8O4
포뮬러 무게:
132.11
MOL 파일:
110-94-1.mol
MSDS 파일:
SDS

글루타르산 속성

녹는점
95-98 °C (lit.)
끓는 점
200 °C/20 mmHg (lit.)
밀도
1,429 g/cm3
증기압
0.022 hPa (18.5 °C)
굴절률
nD106 1.41878
인화점
200°C/20mm
저장 조건
Store below +30°C.
용해도
물: 용해성 5mg/mL, 투명하거나 약간 흐릿함, 무색 내지 희미한 노란색
산도 계수 (pKa)
4.31(at 25℃)
물리적 상태
결정성 분말
색상
오렌지 레드
색상
오렌지색
수소이온지수(pH)
3.7(1 mM solution);3.17(10 mM solution);2.66(100 mM solution)
수용성
430g/L(20℃)
Merck
14,4473
BRN
1209725
안정성
안정적인. 염기, 산화제, 환원제와 호환되지 않습니다.
InChIKey
JFCQEDHGNNZCLN-UHFFFAOYSA-N
LogP
-0.26 at 25℃
CAS 데이터베이스
110-94-1(CAS DataBase Reference)
NIST
Pentanedioic acid(110-94-1)
EPA
Pentanedioic acid (110-94-1)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 36-36/37/38
안전지침서 26-37/39-36-39
WGK 독일 1
RTECS 번호 MA3740000
TSCA Yes
HS 번호 29171990
유해 물질 데이터 110-94-1(Hazardous Substances Data)
기존화학 물질 KE-27970
그림문자(GHS): GHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
예방조치문구:
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P363 다시 사용전 오염된 의류는 세척하시오.
NFPA 704
1
2 0

글루타르산 MSDS


1,5-Pentanedioic acid

글루타르산 C화학적 특성, 용도, 생산

화학적 성질

white or off-white crystals, usually containing 1mol crystal water. Soluble in water, alcohol, ether and chloroform, slightly soluble in petroleum ether.

출처

Glutaric acid occurs in washings from fleece and, together with malonic acid, in the juice of unripened sugar beet.

용도

Glutaric acid is used as the raw material for organic synthesis, pharmaceutical intermediate and synthetic resin. It serves as a precursor in the production of polyester polyols, polyamides, ester plasticizers and corrosion inhibitors. It is useful to decrease polymer elasticity and in the synthesis surfactants and metal finishing compounds. It acts as an intermediate during the catabolism of lysine in mammals.

제조 방법

glutaric acid is produced as a by-product of the production process of adipic acid (about 2% of the output of an adipic acid plant is glutaric); Glutaric acid can be produced through various chemical routes, for example, from cyclopentane by oxidation with molecular oxygen and cobalt (III) catalysts or by ozonolysis; and from cyclopentanol–cyclopentanone by oxidation with oxygen and Co(CH3CO2)2, with potassium peroxide in benzene, or with N2O4 or nitric acid. Together with succinic acid, glutaric acid is formed as a by-product during oxidation of cyclohexanol–cyclohexanone in the adipic acid production process.

주요 응용

The applications of glutaric acid, e.g., as an intermediate, are limited. Its use as a starting material in the manufacture of maleic acid has no commercial importance. it does not usually reach the market because it is converted into dibasic esters and sold as environmentally friendly solvents.

정의

ChEBI: glutaric acid is an alpha,omega-dicarboxylic acid that is a linear five-carbon dicarboxylic acid. It has a role as a human metabolite and a Daphnia magna metabolite. It is an alpha,omega-dicarboxylic acid and a dicarboxylic fatty acid. It is a conjugate acid of a glutarate(1-) and a glutarate.

일반 설명

Glutaric acid appears as colorless crystals or white solid. (NTP, 1992)

공기와 물의 반응

Water soluble.

화재위험

Flash point data for 1,5-Pentanedioic acid are not available; however, 1,5-Pentanedioic acid is probably combustible.

Purification Methods

Crystallise the acid from *benzene, CHCl3, distilled water or *benzene containing 10% (w/w) of diethyl ether. Dry it under vacuum. [Beilstein 2 IV 1934.]

글루타르산 준비 용품 및 원자재

원자재

준비 용품


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