1,2,4,5-사염화벤젠
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1,2,4,5-사염화벤젠 속성
- 녹는점
- 139 °C
- 끓는 점
- 240-246 °C(lit.)
- 밀도
- 1.858
- 증기압
- 5 at 25 °C (extrapolated, Mackay et al., 1982)
- 굴절률
- 1.5348 (estimate)
- 인화점
- >230 °F
- 저장 조건
- 0-6°C
- 용해도
- 0.0003g/L
- 물리적 상태
- 결정질 고체
- 색상
- 라이트 핑크부터 그레이까지
- 수용성
- 불용성. 21°C에서 <0.1g/100mL
- BRN
- 1618315
- Henry's Law Constant
- 0.10 at 20 °C (gas stripping-GC, Oliver, 1985)
- 안정성
- 안정적인. 타기 쉬운. 강한 산화제와 호환되지 않습니다. 알칼리성 메탄올 용액과 폭발적으로 반응함.
- CAS 데이터베이스
- 95-94-3(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | Xn,T,F,N | ||
---|---|---|---|
위험 카페고리 넘버 | 22-36/37/38-23/24/25-11-36-20/21/22-51/53 | ||
안전지침서 | 26-36-45-27-16-36/37-61 | ||
유엔번호(UN No.) | UN 3077 9/PG 3 | ||
WGK 독일 | 3 | ||
RTECS 번호 | DB9450000 | ||
TSCA | Yes | ||
위험 등급 | 9 | ||
HS 번호 | 29036990 | ||
유해 물질 데이터 | 95-94-3(Hazardous Substances Data) | ||
독성 | Acute oral LD50 for rats 1,500 mg/kg, mice 1,035 mg/kg (quoted, RTECS, 1985). |
1,2,4,5-사염화벤젠 C화학적 특성, 용도, 생산
화학적 성질
white solid용도
1,2,4,5-Tetrachlorobenzene was used to study the environmental behavior of hexachlorobutadiene (HCBD).정의
ChEBI: A tetrachlorobenzene carrying chloro groups at positions 1, 2, 4 and 5.환경귀착
Biological. A mixed culture of soil bacteria or a Pseudomonas sp. transformed 1,2,4,5- tetrachlorobenzene to 2,3,5,6-tetrachlorophenol (Ballschiter and Scholz, 1980). After incubation in sewage sludge for 32 d under anaerobic conditions, 1,2,4,5-tetrachlorobenzene did not biodegrade (Kirk et al., 1989).In an enrichment culture derived from a contaminated site in Bayou d’Inde, LA, 1,2,4,5- tetrachlorobenzene underwent reductive dechlorination to 1,2,4-trichlorobenzene. The maximum dechlorination rate, based on the recommended Michaelis-Menten model, was 5.5 nM/d (Pavlostathis and Prytula, 2000).
Photolytic. Irradiation (λ ≥285 nm) of 1,2,4,5-tetrachlorobenzene (1.1–1.2 mM/L) in an acetonitrile-water mixture containing acetone (0.553 mM) as a sensitizer gave the following products (% yield): 1,2,4-trichlorobenzene (25.3), 1,3-dichlorobenzene (8.1), 1,4-dichlorobenzene (3.6), 2,2′,3,4′,5,5′,6-heptachlorobiphenyl (4.19), four hexachlorobiphenyls (6.78), four pentachlorobiphenyls (2.33), one tetrachlorobiphenyl (0.32), 2,4,5-trichloroacetophenone, and (2,4,5- trichlorophenyl)acetonitrile (Choudhry and Hutzinger, 1984). Without acetone, the identified photolysis products (% yield) included 1,2,4-trichlorobenzene (27.7), 1,3-dichlorobenzene (0.3), 1,4-dichlorobenzene (8.5), pentachlorobenzene (trace), 1,2,3,4-tetrachlorobenzene (0.45), 1,2,3,5- tetrachlorobenzene (1.11), 2,2′,3,4′,5,5′,6-heptahlorobiphenyl (1.24), three hexachlorobiphenyls (1.19), and four pentachlorobiphenyls (0.56) (Choudhry and Hutzinger, 1984). The sunlight irradiation of 1,2,4,5-tetrachlorobenzene (20 g) in a 100-mL borosilicate glass-stoppered Erlenmeyer flask for 28 d yielded 26 ppm heptachlorobiphenyl (Uyeta et al., 1976).
Chemical/Physical. Based on an assumed base-mediated 1% disappearance after 16 d at 85 °C and pH 9.70 (pH 11.26 at °C), the hydrolysis half-life was estimated to be >900 yr (Ellington et al., 1988).
Purification Methods
Crystallise it from EtOH, ether, *benzene, *benzene/EtOH or carbon disulfide. [Beilstein 5 IV 668.]1,2,4,5-사염화벤젠 준비 용품 및 원자재
원자재
준비 용품
1,2,4,5-사염화벤젠 공급 업체
글로벌( 156)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 |
info@fdachem.com | China | 7786 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29797 | 60 |
Speranza Chemical Co., Ltd. | +86-86-075521030354 +8618688942810 |
sophieliu@speranzachem.com | China | 723 | 55 |
Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22968 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 47465 | 58 |
career henan chemical co | +86-0371-86658258 15093356674; |
factory@coreychem.com | China | 29826 | 58 |
Shaanxi Dideu Medichem Co. Ltd | +86-029-81148696 +8615536356810 |
1047@dideu.com | China | 3459 | 58 |
Richest Group Ltd | 18017061086 |
oled@richest-group.com | CHINA | 5601 | 58 |
Neostar United (Changzhou) Industrial Co., Ltd. | +86-519-519-85557386 |
marketing1@neostarunited.com | China | 8349 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 |
sales@tnjchem.com | China | 34572 | 58 |