노르말부틸이소시아네이트

노르말부틸이소시아네이트
노르말부틸이소시아네이트 구조식 이미지
카스 번호:
111-36-4
한글명:
노르말부틸이소시아네이트
동의어(한글):
N-부틸이소시아네이트;N-뷰틸이소시아네이트;노르말부칠이소시아네이트;노르말부틸이소시아네이트;N-뷰틸이소시아네이트;N-뷰틸 아이소사이아네이트
상품명:
Butyl isocyanate
동의어(영문):
N-BUTYL ISOCYANATE;1-Isocyanatobutane;BIC;ISOCYANIC ACID BUTYL ESTER;n-bic;n-C4H9NCO;Butylisocyanat;Butyl isocyate;BUTYL ISOCYANATE;ISOCYANATOBUTANE
CBNumber:
CB8153607
분자식:
C5H9NO
포뮬러 무게:
99.13
MOL 파일:
111-36-4.mol
MSDS 파일:
SDS

노르말부틸이소시아네이트 속성

녹는점
85.5℃
끓는 점
115 °C(lit.)
밀도
0.88 g/mL at 25 °C(lit.)
증기 밀도
3 (vs air)
증기압
10.6 mm Hg ( 20 °C)
굴절률
n20/D 1.406(lit.)
인화점
64 °F
저장 조건
2-8°C
물리적 상태
액체
색상
무색의
감도
Moisture Sensitive
Merck
13,1574
BRN
773917
노출 한도
No exposure limit is set for this compound. On the basis of its low inhalation toxicity, a TLV-TWA value of 8 mg/m3 (2 ppm) can be safely ascribed.
InChIKey
HNHVTXYLRVGMHD-UHFFFAOYSA-N
CAS 데이터베이스
111-36-4(CAS DataBase Reference)
NIST
Butane, 1-isocyanato-(111-36-4)
EPA
Butyl isocyanate (111-36-4)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 F,T+
위험 카페고리 넘버 11-21/22-26-34-37-42/43
안전지침서 23-26-28-36/37/39-45
유엔번호(UN No.) UN 2485 6.1/PG 1
WGK 독일 1
RTECS 번호 NQ8250000
F 고인화성물질 10-19-21
TSCA Yes
위험 등급 6.1(a)
포장분류 I
HS 번호 29291090
유해 물질 데이터 111-36-4(Hazardous Substances Data)
독성 LC50 (4hr) in male, female rats (mg/m3): 60, 55 by inhalation (Pauluhn, Eben)
기존화학 물질 KE-21464
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H225 고인화성 액체 및 증기 인화성 액체 구분 2 위험 GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H330 흡입하면 치명적임 급성 독성 물질 흡입 구분 1, 2 위험 GHS hazard pictograms P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H334 흡입 시 알레르기성 반응, 천식 또는 호흡 곤란 등을 일으킬 수 있음 호흡기 과민성 물질 구분 1 위험 GHS hazard pictograms P261, P285, P304+P341, P342+P311,P501
H412 장기적 영향에 의해 수생생물에 유해함 수생 환경유해성 물질 - 만성 구분 3 P273, P501
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
3
3 2
W

노르말부틸이소시아네이트 C화학적 특성, 용도, 생산

화학적 성질

Colorless to faintly yellow liquid

용도

n-Butyl isocyanate is used as an acylatingagent in the Friedel–Crafts reaction to produce amide.

정의

ChEBI: An isocyanate having a butyl group attached to the nitrogen.

일반 설명

A clear, colorless liquid with a pungent odor. Flash point 68°F. Very toxic by ingestion, and may also be toxic by skin absorption and inhalation. Vapors heavier than air. Less dense than water and insoluble in water. Produces toxic oxides of nitrogen during combustion.

공기와 물의 반응

Highly flammable. Extremely slow decomposition by water. Less dense than water and insoluble in water.

반응 프로필

Isocyanates and thioisocyanates are incompatible with many classes of compounds, reacting exothermically to release toxic gases. Reactions with amines, aldehydes, alcohols, alkali metals, ketones, mercaptans, strong oxidizers, hydrides, phenols, and peroxides can cause vigorous releases of heat. Acids and bases initiate polymerization reactions in these materials. Some isocyanates react with water to form amines and liberate carbon dioxide. Base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. Such reactions in the absence of solvents often occur with explosive violence [Wischmeyer 1969].

위험도

Strong irritant to eyes and skin.

건강위험

n-Butyl isocyanate exhibits low inhalationtoxicity and relatively higher oral toxicity.This is in contrast to the aromatic isocyanates. The toxic effects are nausea, dyspnea, insomnia, coughing, and chest pain.Such symptoms, however, are much lessmarked than those of methyl isocyanate.
LC50 value, inhalation (mice): 680 mg/m3
LD50 value, oral (mice): 150 mg/kg
There is no report of any carcinogenic orteratogenic study of this compound.

화재위험

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

Safety Profile

A poison by ingestion and intravenous routes. Mddly toxic by inhalation. A powerful irritant to eyes, skin, and mucous membranes. A flammable liquid. See also CYANATES and NITROGEN MONOXIDE.

잠재적 노출

N-Butyl isocyanate is used as a reagent in organic synthesis; used as intermediates in production of pharmaceuticals, carbamate and urea insecticides, and fungicides. It is also used in the production of sulfonylurea antidiabetic drugs

운송 방법

UN2485 n-Butyl isocyanate, Hazard Class: 6.1; Labels: 6.1—Poison Inhalation Hazard, 3—Flammable liquid. Hazard, Inhalation Hazard Zone B. PGI.

비 호환성

Vapor may form explosive mixture with air. Isocyanates are highly flammable and reactive with many compounds, even with themselves. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Reaction with moist air, water or alcohols may form amines and insoluble polyureas and react exothermically, releasing toxic, corrosive or flammable gases, including carbon dioxide; and, at the same time, may generate a violent release of heat increasing the concentration of fumes in the air. Incompatible with amines, aldehydes, alkali metals, ammonia, carboxylic acids, caprolactum, alkaline materials, glycols, ketones, mercaptans, hydrides, organotin catalysts, phenols, strong acids, strong bases, strong reducing agents such as hydrides, urethanes, ureas. Elevated temperatures or contact with acids, bases, tertiary amines, and acylchlorides may cause explosive polymerization. Contact with metals may evolve flammable hydrogen gas. Attacks some plastics, rubber and coatings. May accumulate static electrical charges, and may cause ignition of its vapors

폐기물 처리

Dispose of contents and container to an approved waste disposal plant. Use a licensed professional waste disposal service to dispose of this material. Caution: this chemical is highly flammable with a low flash point (,20C). Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

노르말부틸이소시아네이트 준비 용품 및 원자재

원자재

준비 용품


노르말부틸이소시아네이트 공급 업체

글로벌( 212)공급 업체
공급자 전화 이메일 국가 제품 수 이점
Xiamen AmoyChem Co., Ltd
+86-592-6051114 +8618959220845
sales@amoychem.com China 6387 58
SIMAGCHEM CORP
+86-13806087780
sale@simagchem.com China 17367 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21691 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555 +8617317452075
jack.li@time-chemicals.com China 1807 55
career henan chemical co
+86-0371-86658258
sales@coreychem.com China 29914 58
SHANDONG ZHI SHANG CHEMICAL CO.LTD
+86 18953170293
sales@sdzschem.com China 2931 58
Hubei Jusheng Technology Co.,Ltd.
18871490254
linda@hubeijusheng.com CHINA 28180 58
Jinan Finer Chemical Co., Ltd
+86-531-88989536 +86-15508631887
sales@finerchem.com China 2967 58
Hubei xin bonus chemical co. LTD
86-13657291602
linda@hubeijusheng.com CHINA 22968 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873
sales@chemdad.com China 39916 58

노르말부틸이소시아네이트 관련 검색:

Copyright 2019 © ChemicalBook. All rights reserved