L(+)-아라비노스

L(+)-아라비노스
L(+)-아라비노스 구조식 이미지
카스 번호:
5328-37-0
한글명:
L(+)-아라비노스
동의어(한글):
L(+)-아라비노스
상품명:
L-Arabinose
동의어(영문):
Amidosulfonic acid;X-GAL (SOLID POWDER;L-ARA;FEMA 3255;pectinose;L- pentose;L-Arabinose;PECTIN SUGAR;L(+)Arabinose;L(+)-Arbinose
CBNumber:
CB8181541
분자식:
C5H10O5
포뮬러 무게:
150.13
MOL 파일:
5328-37-0.mol
MSDS 파일:
SDS

L(+)-아라비노스 속성

녹는점
160-163 °C(lit.)
알파
104 º (C=6, IN WATER 23 ºC)
끓는 점
415.5±38.0 °C(Predicted)
밀도
1.508±0.06 g/cm3(Predicted)
증기압
0Pa at 20℃
FEMA
3255 | L-ARABINOSE
굴절률
104 ° (C=10, H2O)
저장 조건
room temp
용해도
H2O: 1 M at 20 °C, 투명, 무색
산도 계수 (pKa)
12.46±0.20(Predicted)
물리적 상태
고체
물리적 상태
단단한 모양
색상
백색 결정체
냄새
냄새 없는
수소이온지수(pH)
6.5-7.0 (100g/l, H2O, 20℃)
optical activity
[α]20/D +104.0±2.0°, 24 hr, c = 10% in H2O
수용성
거의 투명함
최대 파장(λmax)
λ: 260 nm Amax: ≤0.05
λ: 280 nm Amax: ≤0.04
Merck
14,761
BRN
1723085
안정성
안정적인. 강한 산화제와 호환되지 않습니다.
InChIKey
PYMYPHUHKUWMLA-VAYJURFESA-N
LogP
-2.8 at 20℃
CAS 데이터베이스
5328-37-0(CAS DataBase Reference)
EPA
L-Arabinose (5328-37-0)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
WGK 독일 3
F 고인화성물질 3-10
HS 번호 2940 00 00
기존화학 물질 2015-3-7163
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P271 옥외 또는 환기가 잘 되는 곳에서만 취급하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
NFPA 704
0
0 0

L(+)-아라비노스 C화학적 특성, 용도, 생산

개요

L-Arabinose is considered a rare sugar that can be found naturally within the structures of most fruits and vegetables. Due to its low caloric sweetening effects, arabinose is commonly used in nutritional supplements and prescription drugs. In addition to its sweetening effects, when reacted with amino acid blends, using the Maillard Reaction, arabinose is able to contribute to the production of savory and meaty flavors used within the food and flavor industry.
L-Arabinose is commonly used in the Flavor Industry to produce meaty or cooked/roasted flavors.

화학적 성질

L-Arabinose is a white crystalline powder, It is a rare type of C5-sugar that naturally occurs in the hemicelluloses structure of most fruits and vegetables. Its name is derived from gum Arabic, another well-known food ingredient. Humans have always consumed L-Arabinose both pure as well as part of the hemicelluloses structure. The highest concentrations of L-Arabinose in food as monosaccharide can be found in instant coffee, wine and sake.

출처

For biosynthetic reasons, most saccharides are almost always more abundant in nature as the "D"-form, or structurally analogous to D-glyceraldehyde. However, L-arabinose is in fact more common than D-arabinose in nature and is found in nature as a component of biopolymers such as hemicellulose and pectin. L-Arabinose is widely distributed in nature including Acacia and Larix species as a complex polysaccharide.

용도

The L-arabinose operon, also known as the araBAD operon, has been the subject of much biomolecular research. The operon directs the catabolism of arabinose in E. coli, and it is dynamically activated in the presence of arabinose and the absence of glucose.
In synthetic biology, arabinose is often used as a one-way or reversible switch for protein expression under the Pbad promoter in E. coli. This on-switch can be negated by the presence of glucose or reversed off by the addition of glucose in the culture medium which is a form of catabolite repression. L-Arabinose is an arabinose isomer widely found in nature, while D-arabinose is less common. L-Arabinose is a constituent of many biopolymers that make up plant cell walls.
This monosaccharide is often used in cell culture media, serving as a bacterial carbon source, and can be used to distinguish between bacteria based on their fermentation abilities.
L-Arabinose, in the absence of glucose, induces transcription of the ara operon in E. coli that encodes L-arabinose catabolizing enzymes. It does this by binding to the AraC protein and activating the PBAD promoter. The PBAD promoter is used in plasmid vectors as a switch for protein expression that can be turned on by L-arabinose or turned off by addition of glucose.

제조 방법

By partial hydrolysis of mesquite gum.

정의

l-enantiomers occur naturally. lArabinose is common in vegetable gums, especially arabic.

주요 응용

L-Arabinose is used as a substrate to identify, differentiate and characterize pentose sugar isomerase(s). L-Arabinose is used in the bioproduction of L-ribose.
L-(+)-Arabinose is a pentose sugar that occurs naturally in corn fiber gum and acacia gum.
L-(+)-Arabinose is used as a key starting material in the total synthesis of (+)-ambruticin, zaragozic acid A, (?)-radicamine B and (+)-herbarumin I.

benefits

L-Arabinose can play an important role in the management of blood glucose and insulin levels related to sucrose intake. The addition of L-Arabinose to a sugar containing diet has the following direct benefits: 1) up to 60% reduction of the glucose peak level related to sucrose consumption, 2) up to 60% suppression of the insulin peak level related to sucrose consumption, and 3) a sustained release of glucose to the body over a longer period of time. A low glycemic diet may have benefits like reduction of heart disease, lowering of blood cholesterol, management of body weight and composition, and prevention of type 2 diabetes. A low insulinic diet may lead to lower fat storage and prevention of pre-diabetes incidence. Sustained glucose release over a longer period of time has advantages for athletes and other people that value a responsible and healthy diet.

생물학적 활성

L-Arabinose is the naturally occurring isomer and is a constituent of plant polysaccharides. Most bacteria contain an inducible arabinose operon that codes for a series of enzymes and transporters that allows L-arabinose to be used as the sole carbon source in microbial culture.

L(+)-아라비노스 준비 용품 및 원자재

원자재

준비 용품


L(+)-아라비노스 공급 업체

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