마그네슘 티오황산염

마그네슘 티오황산염
마그네슘 티오황산염 구조식 이미지
카스 번호:
10124-53-5
한글명:
마그네슘 티오황산염
동의어(한글):
마그네슘티오황산염;마그네슘티오황산염(MAGNESIUMTHIOSULFATE)
상품명:
Magnesium thiosulfate hexahydrate
동의어(영문):
magnosulf;Einecs 233-340-5;MAGNESIUM THIOSULFATE;MAGNESIUM HYPOSULFITE;MAGNESIUM THIOSULPHATE;thiosulfuricacid,magnesiumsalt;Magnesium thiosulfate 6-hydrate;Magnesium thiosulfate hexahydrate;Generation of magnesium sulfate sulfur;thiosulfuricacid(h2s2o3),magnesiumsalt(1:1)
CBNumber:
CB8200741
분자식:
H4MgO3S2
포뮬러 무게:
140.45
MOL 파일:
10124-53-5.mol
MSDS 파일:
SDS

마그네슘 티오황산염 속성

녹는점
1700°C
밀도
1.818
수용성
g/100g 용액 H2O: 30.69(0°C), 34.51(28°C); 고체상, MgS2O3 · 6H2O [KRU93]; 불용성 알코올 [MER06]
Merck
14,5694
CAS 데이터베이스
10124-53-5(CAS DataBase Reference)
EPA
Thiosulfuric acid (H2S2O3), magnesium salt (1:1) (10124-53-5)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 36/37/38
안전지침서 26-36
WGK 독일 3
RTECS 번호 XN6550000
독성 mouse,LD50,subcutaneous,850mg/kg (850mg/kg),Arzneimittel-Forschung. Drug Research. Vol. 5, Pg. 376, 1955.
기존화학 물질 KE-22758
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
예방조치문구:
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P321 (…) 처치를 하시오.
P332+P313 피부 자극이 생기면 의학적인 조치· 조언을 구하시오.
P362 오염된 의복을 벗고 세척 후에 재사용하기

마그네슘 티오황산염 C화학적 특성, 용도, 생산

개요

Magnesium thiosulfate has the molecular formula of MgS2O3 and the molecular weight of 136.4352 g/mol. It is also known as “hyposulfite”. It can be prepared by the reaction of sodium thiosulfate upon the chloride in water:
MgCl2+Na2S2O3? MgS2O3+2NaCl
Since magnesium thiosulfate is soluble in water (50 g/100 ml at 20°C), the solution must be evaporated at a low temperature to crystallize the product (salt-out temperature ~15°F (-9.4°C). A hexahydrate, MgS2O3· 6H2O, is the result.
These are colorless crystals that lose water at 170°C to form the trihydrate. Further heating to 420°C then forms the anhydrate. Further heating to 600°C will cause the production of magnesium sulfate, sulfur and oxides of sulfur:
2MgS2O3+2O2+heat? 2MgSO4+S+SO2 Magnesium thiosulfate is considered to have a low toxicity to humans. It has been used to remove ozone from either a water stream, such as a drinking water or wastewater stream being treated with ozone, or scrubbing ozone from a gaseous stream by contacting the gaseous stream with solid magnesium thiosulfate. It has also been used to remove chlorine gas from a water stream by contacting the stream with magnesium thiosulfate solution. In yet another aspect, a method of scrubbing chlorine from a gaseous stream comprises contacting the gas stream with solid magnesium thiosulfate.
Magnesium thiosulfate is not commonly referenced in scientific literature. The few articles that prevail discuss technically specific physical properties of the end product itself. Synthetic methods are described in some Japanese patents and there is mention of MgTS in a short German description in Handbuch der Anorganischen Chemie, vol. 11, 1984. Both refer to adding sulfur to magnesium sulfite to produce magnesium thiosulfate. Neither reference describes the pH nor physical consistency of the “sulfite” intermediate, although the German article does note the “color change” observed as SO2 is purged into MgO: the slurry becomes yellow.

화학적 성질

colorless or white crystal(s) [MER06]

마그네슘 티오황산염 준비 용품 및 원자재

원자재

준비 용품


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