페놀 수지

페놀 수지
페놀 수지 구조식 이미지
카스 번호:
9003-35-4
한글명:
페놀 수지
동의어(한글):
페놀수지;페놀수지(PHENOLICRESIN)
상품명:
PHENOL-FORMALDEHYDE RESIN
동의어(영문):
Phenolic resin;Phenolic resins;Novolac;P-F-R-2;Phenolic resin 264;phenol-formaldehyde;phenol,polymerwithformaldehyde;RESOLE;-formaL;Phenolpac
CBNumber:
CB8274689
분자식:
C7H6O2
포뮬러 무게:
122.12134
MOL 파일:
9003-35-4.mol
MSDS 파일:
SDS

페놀 수지 속성

녹는점
94 °C
끓는 점
229.3℃[at 101 325 Pa]
밀도
1.10 g/cm3
증기압
3.18Pa at 25℃
저장 조건
Sealed in dry,Room Temperature
수용성
1.557mg/L at 25℃
Dielectric constant
4.5(Ambient)
안정성
안정적인. 강한 산화제와 호환되지 않습니다.
LogP
3.564 at 25℃
EPA
Formaldehyde phenol polymer (9003-35-4)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
기존화학 물질 KE-28224
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P272 작업장 밖으로 오염된 의복을 반출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P321 (…) 처치를 하시오.
P333+P313 피부자극성 또는 홍반이 나타나면 의학적인 조치·조언를 구하시오.
P363 다시 사용전 오염된 의류는 세척하시오.
P501 ...에 내용물 / 용기를 폐기 하시오.

페놀 수지 C화학적 특성, 용도, 생산

화학적 성질

The phenolic resins most widely used are low molecular weight butylated resols, which contain phenolic hydroxyl groups and etherified and unetherified methylol groups. The epoxy resins used have a molecular weight of 3000-4000 and therefore contain secondary hydroxyl groups.

용도

Phenol-formaldehyde resin is used in binders, adhesives, laminates, impregnation products, surface coatings, casting sand, etc.

제조 방법

Phenol-formaldehyde resin is prepared as follows:
C6H5OH+H2C=O ---> [-C6H2(OH)CH2-]n
One-Stage Resins. The ratio of formaldehyde to phenol is high enough to allow the thermosetting process to take place without the addition of other sources of cross-links.
Two-Stage Resins. The ratio of formaldehyde to phenol is low enough to prevent the thermosetting reaction from occurring during manufacture of the resin. At this point the resin is termed novolac resin. Subsequently, hexamethylenetetramine is incorporated into the material to act as a source of chemical cross-links during the molding operation (and conversion to the thermoset or cured state).

공업 용도

Phenol-formaldehyde resin is a synthetic resin, commonly known as phenolic, made by the reaction of phenol and formaldehyde, and employed as a molding material for the making of mechanical and electrical parts. The resins are also used for laminating, coatings, and casting resins.
Phenolic resins are used most extensively as thermosetting plastic materials, as there are only a few uses as thermoplastics. The polymer is composed of carbon, hydrogen, oxygen, and sometimes nitrogen. Its molecular weight varies from a very low value during its early state of formation to almost infinity in its final state of cure. The chemical configuration, in the thermoset state, is usually represented by a threedimensional network in which the phenolic nuclei are linked by methylene groups. The completely cross-linked network requires three methylene groups to two phenolic groups. A lesser degree of cross-linking is attainable either by varying the proportions of the ingredients or by blocking some of the reactive positions of the phenolic nucleus by other groups, such as methyl, butyl, etc. Reactivity can be enhanced by increasing the hydroxyl groups on the phenolic nuclei, for example, by the use of resorcinol.
The outstanding characteristics of phenolics are good electrical properties, very rigid set, good tensile strength, excellent heat resistance, good rigidity at elevated temperature, good aging properties; also, good resistance to water, organic solvents, weak bases, and weak acids. All these characteristics are coupled with relatively low cost.

페놀 수지 준비 용품 및 원자재

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